Patents by Inventor Hidehiko Nishioka

Hidehiko Nishioka has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6287530
    Abstract: An additive for synthetic resins is provided which comprises particles of a petaloid hydroxyapatite represented by a chemical formula Ca10(PO4)6(OH)2, having the specified particle diameter, degree of dispersion: and specific surface area, and a synthetic resin composition blended with the additive is also provided. By the use of the additive of the present invention, a film satisfying anti-blocking property, transparency and anti-scratch property can be obtained.
    Type: Grant
    Filed: June 25, 1999
    Date of Patent: September 11, 2001
    Assignee: Maruo Calcium Company Ltd.
    Inventors: Mitsunobu Aoyama, Shigeo Takiyama, Hidehiko Nishioka, Shiro Minayoshi
  • Patent number: 6033780
    Abstract: The fine particles of peraloid porous hydroxyapatite are provided, which have an atomic ratio of Ca/P in a range of 1.62-1.72 and the chemical formula Ca.sub.5 (PO.sub.4).sub.3 (OH). The particles are comprised of micropores having a petaloid porous structure not only on the surface but also in the inside of the particles, and have the specific particle diameter of the specific particle size, micropore diameter of the specific particle size, the specific surface of the specific range, static and pressurized percentage of voids of the specific range. The particles have superior dispersibility and are useful in the fields such as carriers for pharmaceuticals and so on, adsorbents, absorbents, sustained-release materials, filtering agents, biological materials, fillers for plastics, and anti-blocking agents for films and so on.
    Type: Grant
    Filed: January 5, 1998
    Date of Patent: March 7, 2000
    Assignee: Maruo Calcium Company Limited
    Inventors: Hidehiko Nishioka, Shigeo Takiyama, Minoru Hanazaki
  • Patent number: 5976687
    Abstract: An additive for synthetic resins is provided. The additive comprises particles surface-coated with a petaloid porous hydroxyapatite having a chemical formula Ca.sub.5 (PO.sub.4).sub.3 (OH) and the petaloid porous hydroxyapatite is not less than 5% by weight of the particles. The additive can be added to any kinds of synthetic resins. If the additive is used in a polyethylene film, blocking of the film is not only prevented, but good transparency and good anti-scratch ability are imparted, and if the additive is used in a polyester, a film having good slipperiness, anti-abrasion and less coarse protrusions can be provided.
    Type: Grant
    Filed: June 11, 1998
    Date of Patent: November 2, 1999
    Assignee: Maruo Calcium Company, Ltd.
    Inventors: Hidehiko Nishioka, Minoru Hanazaki, Shiro Minayoshi, Shigeo Takiyama, Mitsunobu Aoyama
  • Patent number: 5844022
    Abstract: An additive for synthetic resins is provided. The additive comprises particles surface-coated with a petaloid porous hydroxyapatite having a chemical formula Ca.sub.5 (PO.sub.4 ).sub.3 (OH) and the petaloid porous hydroxyapatite is not less than 5% by weight of the particles. The additive can be added to any kinds of synthetic resins. If the additive is used in a polyethylene film, blocking of the film is not only prevented, but good transparency and good anti-scratch ability are imparted, and if the additive is used in a polyester, a film having good slipperiness, anti-abrasion and less coarse protrusions can be provided.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: December 1, 1998
    Assignee: Maruo Calcium Company Limited
    Inventors: Hidehiko Nishioka, Minoru Hanazaki, Shiro Minayoshi, Shigeo Takiyama, Mitsunobu Aoyama
  • Patent number: 5494651
    Abstract: A monodisperse spherical, ellipsoidal or plate-like vaterite calcium carbonate almost free from secondary aggregation is disclosed. The vaterite type calcium carbonate is prepared by the steps of adding 5-20 times mol equivalent of water with respect to unslaked lime to a methanol suspension of 0.5-12 weight % of unslaked lime and/or slaked lime (in case of slaked, conversion is to be made into unslaked lime of the same mol) to prepare of a mixture of methanol, unslaked lime and/or slaked lime and water, letting carbon dioxide gas through said mixture, adjusting the temperature in the carbonation reaction system to not less than 30.degree. C. before arrival of conductivity within carbonation reaction system at the maximal point on conductivity variation curve in the carbonation reaction system and adjusting the time from start of carbonation reaction to the point where the conductivity is 100 .mu.S/cm to be less than 1,000 minutes.
    Type: Grant
    Filed: October 19, 1993
    Date of Patent: February 27, 1996
    Assignee: Maruo Calcium Company Limited
    Inventors: Shiro Minayoshi, Naofumi Saito, Minoru Hanazaki, Hidehiko Nishioka, Sakae Kuroda, Masako Takahashi, Seiya Shimizu, Norimasa Maida
  • Patent number: 5275651
    Abstract: A monodisperse spherical, ellipsoidal or plate-like vaterite calcium carbonate almost free from secondary aggregation is disclosed. The vaterite type calcium carbonate is prepared by the steps of adding 5-20 times mol equivalent of water with respect to unslaked lime to a methanol suspension of 0.5-12 weight % of unslaked lime and/or slaked lime (in case of slaked, conversion is to be made into unslaked lime of the same mol) to prepare of a mixture of methanol, unslaked lime and/or slaked lime and water, letting carbon dioxide gas through said mixture, adjusting the temperature in the carbonation reaction systemto not less than 30.degree. C. before arrival of conductivity within carbonation reaction system at the maximal point on conductivity variation curve in the carbonation reaction system and adjusting the time from start of carbonation reaction to the point where the conductivity is 100.mu. S/cm to be less than 1,000 minutes.
    Type: Grant
    Filed: May 28, 1991
    Date of Patent: January 4, 1994
    Assignee: Maruo Calcium Company Limited
    Inventors: Shiro Minayoshi, Naofumi Saito, Minoru Hanazaki, Hidehiko Nishioka, Sakae Kuroda, Masako Takahashi, Seiya Shimizu, Norimasa Maida