Patents by Inventor Hidekazu Awano

Hidekazu Awano has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11961997
    Abstract: A negative electrode active material for a non-aqueous electrolyte secondary battery, containing negative electrode active material particles, including silicon compound particles each containing a silicon compound (SiOx: 0.5?x?1.6) and at least one or more of Li2SiO3 and Li2Si2O5, the material includes a phosphate, the negative electrode active material particles each have a surface containing lithium element, and a ratio mp/ml satisfies 0.02?mp/ml?3, where ml represents a molar quantity of the lithium element and contained per unit mass of the particles, and mp represents a molar quantity of phosphorus element contained per unit mass of the particles. Thereby, a negative electrode active material is capable of stabilizing an aqueous negative electrode slurry prepared in producing a negative electrode of a secondary battery, and capable of improving initial charge-discharge characteristics when the negative electrode active material is used for a secondary battery.
    Type: Grant
    Filed: September 25, 2019
    Date of Patent: April 16, 2024
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takumi Matsuno, Hidekazu Awano, Takakazu Hirose, Kohta Takahashi, Yusuke Osawa
  • Patent number: 11901545
    Abstract: Methods for producing a negative electrode active material particle which includes a silicon compound particle containing a silicon compound that contains oxygen. The methods including preparing a silicon compound particle containing a silicon compound that contains oxygen; inserting Li into the silicon compound particle; and heating, while stirring, the Li-inserted silicon compound particle in a furnace to produce a negative electrode active material particle, wherein at least part of Si constituting the silicon compound particle is present in at least one state selected from oxide of Si2+ to Si3+ containing no Li, and compound containing Li and Si2+ to Si3+.
    Type: Grant
    Filed: February 2, 2022
    Date of Patent: February 13, 2024
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takakazu Hirose, Takumi Matsuno, Reiko Sakai, Kohta Takahashi, Hidekazu Awano
  • Publication number: 20220158166
    Abstract: Methods for producing a negative electrode active material particle which includes a silicon compound particle containing a silicon compound that contains oxygen. The methods including preparing a silicon compound particle containing a silicon compound that contains oxygen; inserting Li into the silicon compound particle; and heating, while stirring, the Li-inserted silicon compound particle in a furnace to produce a negative electrode active material particle, wherein at least part of Si constituting the silicon compound particle is present in at least one state selected from oxide of Si2+ to Si3+ containing no Li, and compound containing Li and Si2+ to Si3+.
    Type: Application
    Filed: February 2, 2022
    Publication date: May 19, 2022
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takakazu HIROSE, Takumi MATSUNO, Reiko SAKAI, Kohta TAKAHASHI, Hidekazu AWANO
  • Patent number: 11316147
    Abstract: A negative electrode active material includes: particles of negative electrode active material, the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5?x?1.6); the particles of silicon compound contain at least one kind or more of Li2SiO3 and Li4SiO4; the particles of negative electrode active material contain Li2CO3 and LiOH on a surface thereof; and a content of the Li2CO3 is 0.01% by mass or more and 5.00% by mass or less relative to a mass of the particles of negative electrode active material and a content of the LiOH is 0.01% by mass or more and 5.00% by mass or less relative to the mass of the particles of negative electrode active material. Thus a negative electrode active material is capable of improving initial charge/discharge characteristics and the cycle characteristics when used as a negative electrode active material of the secondary battery.
    Type: Grant
    Filed: January 27, 2017
    Date of Patent: April 26, 2022
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Hidekazu Awano, Takumi Matsuno, Hiromichi Kamo, Takakazu Hirose, Masahiro Furuya
  • Patent number: 11283060
    Abstract: A negative electrode active material contains a negative electrode active material particle which includes a silicon compound particle containing a silicon compound that contains oxygen. The silicon compound particle contains a Li compound, and at least part of Si constituting the silicon compound particle is present in at least one state selected from oxide of Si2+ to Si3+ containing no Li, and compound containing Li and Si2+ to Si3+. A negative electrode active material is capable of increasing battery capacity and improving cycle characteristics and initial charge-discharge characteristics when the negative electrode active material is used for a secondary battery. A mixed negative electrode active material contains the negative electrode active material. A method produces a negative electrode active material particle which enables production of the negative electrode active material particle to be contained in the negative electrode active material as described above.
    Type: Grant
    Filed: May 18, 2018
    Date of Patent: March 22, 2022
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takakazu Hirose, Takumi Matsuno, Reiko Sakai, Kohta Takahashi, Hidekazu Awano
  • Publication number: 20210376311
    Abstract: A negative electrode active material for a non-aqueous electrolyte secondary battery, containing negative electrode active material particles, including silicon compound particles each containing a silicon compound (SiOx: 0.5?x?1.6) and at least one or more of Li2SiO3 and Li2Si2O5, the material includes a phosphate, the negative electrode active material particles each have a surface containing lithium element, and a ratio mp/ml satisfies 0.02?mp/ml?3, where ml represents a molar quantity of the lithium element and contained per unit mass of the particles, and mp represents a molar quantity of phosphorus element contained per unit mass of the particles. Thereby, a negative electrode active material is capable of stabilizing an aqueous negative electrode slurry prepared in producing a negative electrode of a secondary battery, and capable of improving initial charge-discharge characteristics when the negative electrode active material is used for a secondary battery.
    Type: Application
    Filed: September 25, 2019
    Publication date: December 2, 2021
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takumi MATSUNO, Hidekazu AWANO, Takakazu HIROSE, Kohta TAKAHASHI, Yusuke OSAWA
  • Publication number: 20210193990
    Abstract: A negative electrode active material includes: particles of negative electrode active material, the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5?x?1.6); the particles of silicon compound contain at least one kind or more of Li2SiO3 and Li4SiO4; the particles of negative electrode active material contain Li2CO3 and LiOH on a surface thereof; and a content of the Li2CO3 is 0.01% by mass or more and 5.00% by mass or less relative to a mass of the particles of negative electrode active material and a content of the LiOH is 0.01% by mass or more and 5.00% by mass or less relative to the mass of the particles of negative electrode active material. Thus a negative electrode active material is capable of improving initial charge/discharge characteristics and the cycle characteristics when used as a negative electrode active material of the secondary battery.
    Type: Application
    Filed: January 27, 2017
    Publication date: June 24, 2021
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hidekazu AWANO, Takumi MATSUNO, Hiromichi KAMO, Takakazu HIROSE, Masahiro FURUYA
  • Patent number: 10991971
    Abstract: The present disclosure relates to a negative electrode active material including: particles of negative electrode active material, wherein the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx: 0.55?x?1.6), and the particles of silicon compound includes at least one or more kinds of Li2SiO3 and Li4SiO4; the particles of silicon compound contain nickel; and, a mass of the nickel to a mass of the particles of negative electrode active material is 2 mass ppm or more and 100 mass ppm or less. Thus, when used as the negative electrode active material of a secondary battery, a negative electrode active material capable of improving the initial charge/discharge characteristics and cycle characteristics is provided.
    Type: Grant
    Filed: October 24, 2016
    Date of Patent: April 27, 2021
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takumi Matsuno, Takakazu Hirose, Hiromichi Kamo, Masahiro Furuya, Hidekazu Awano
  • Patent number: 10868303
    Abstract: A negative electrode active material contains particle of the negative electrode active material, wherein the particle of the negative electrode active material contains particle of a silicon compound which contains a silicon compound (SiOx: 0.5?x?1.6), the particle of the silicon compound contains lithium, and the particle of the negative electrode active material has a total content rate of a polyphenylene compound component and a polycyclic aromatic component measured by TPD-MS of 1 ppm by mass or more and 4,000 ppm by mass or less. As a result, a negative electrode active material is capable of improving cycle characteristics and initial charge/discharge characteristics when it is used as a negative electrode active material of a lithium ion secondary battery.
    Type: Grant
    Filed: February 14, 2017
    Date of Patent: December 15, 2020
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Hiromichi Kamo, Masahiro Furuya, Hidekazu Awano, Takakazu Hirose, Takumi Matsuno, Katsunori Nishiura, Nan Fang
  • Patent number: 10559822
    Abstract: A negative electrode active material, wherein the negative electrode active material is a negative electrode active material including negative electrode active material particles; the negative electrode active material particles include silicon compound particles including a silicon compound (SiOx: 0.5?x?1.6); the silicon compound particles include at least any one kind or more kinds of Li2SiO3 and Li4SiO4; the negative electrode active material particles have a loose bulk density BD of 0.5 g/cm3 or more and 0.9 g/cm3 or less, a tapped bulk density TD of 0.7 g/cm3 or more and 1.2 g/cm3 or less, and a compression degree of 25% or less, the compression degree being defined by (TD?BD)/TD. Therefore, the negative electrode active material which is capable of improving the initial charge and discharge characteristics as well as the cycle characteristics upon using it as the negative electrode active material of a secondary battery is provided.
    Type: Grant
    Filed: October 27, 2016
    Date of Patent: February 11, 2020
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takumi Matsuno, Takakazu Hirose, Hiromichi Kamo, Masahiro Furuya, Hidekazu Awano
  • Publication number: 20200028152
    Abstract: A negative electrode active material contains a negative electrode active material particle which includes a silicon compound particle containing a silicon compound that contains oxygen. The silicon compound particle contains a Li compound, and at least part of Si constituting the silicon compound particle is present in at least one state selected from oxide of Si2+ to Si3+ containing no Li, and compound containing Li and Si2+ to Si3+. A negative electrode active material is capable of increasing battery capacity and improving cycle characteristics and initial charge-discharge characteristics when the negative electrode active material is used for a secondary battery. A mixed negative electrode active material contains the negative electrode active material. A method produces a negative electrode active material particle which enables production of the negative electrode active material particle to be contained in the negative electrode active material as described above.
    Type: Application
    Filed: May 18, 2018
    Publication date: January 23, 2020
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takakazu HIROSE, Takumi MATSUNO, Reiko SAKAI, Kohta TAKAHASHI, Hidekazu AWANO
  • Publication number: 20190058189
    Abstract: A negative electrode active material, wherein the negative electrode active material is a negative electrode active material including negative electrode active material particles; the negative electrode active material particles include silicon compound particles including a silicon compound (SiOx: 0.5?x?1.6); the silicon compound particles include at least any one kind or more kinds of Li2SiO3 and Li4SiO4; the negative electrode active material particles have a loose bulk density BD of 0.5 g/cm3 or more and 0.9 g/cm3 or less, a tapped bulk density TD of 0.7 g/cm3 or more and 1.2 g/cm3 or less, and a compression degree of 25% or less, the compression degree being defined by (TD?BD)/TD. Therefore, the negative electrode active material which is capable of improving the initial charge and discharge characteristics as well as the cycle characteristics upon using it as the negative electrode active material of a secondary battery is provided.
    Type: Application
    Filed: October 27, 2016
    Publication date: February 21, 2019
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takumi MATSUNO, Takakazu HIROSE, Hiromichi KAMO, Masahiro FURUYA, Hidekazu AWANO
  • Publication number: 20190051897
    Abstract: A negative electrode active material contains particle of the negative electrode active material, wherein the particle of the negative electrode active material contains particle of a silicon compound which contains a silicon compound (SiOx: 0.5?x?1.6), the particle of the silicon compound contains lithium, and the particle of the negative electrode active material has a total content rate of a polyphenylene compound component and a polycyclic aromatic component measured by TPD-MS of 1 ppm by mass or more and 4,000 ppm by mass or less. As a result, a negative electrode active material is capable of improving cycle characteristics and initial charge/discharge characteristics when it is used as a negative electrode active material of a lithium ion secondary battery.
    Type: Application
    Filed: February 14, 2017
    Publication date: February 14, 2019
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Hiromichi KAMO, Masahiro FURUYA, Hidekazu AWANO, Takakazu HIROSE, Takumi MATSUNO, Katsunori NISHIURA, Nan FANG
  • Publication number: 20190006661
    Abstract: Negative electrode active material, wherein the negative electrode active material comprises a negative electrode active material particle; the negative electrode active material particle comprises silicon compound particle comprising a silicon compound (SiOx: 0.5?x?1.6); the silicon compound particle comprises at least any one or more of Li2SiO3 and Li4SiO4; the negative electrode active material comprises 2% by mass or less of silicon dioxide particle and comprises a silicon dioxide-carbon composite secondary particle comprising a plurality of the silicon dioxide particles and carbon; and the composite secondary particle includes a lithium compound in at least part of a portion other than a silicon dioxide or a silicon compound (SiOx: 0.5?x?1.6) in the composite secondary particle.
    Type: Application
    Filed: December 16, 2016
    Publication date: January 3, 2019
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takumi MATSUNO, Takakazu HIROSE, Hiromichi KAMO, Masahiro FURUYA, Hidekazu AWANO
  • Publication number: 20180287193
    Abstract: The present disclosure relates to a negative electrode active material including: particles of negative electrode active material, wherein the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx: 0.55?x?1.6), and the particles of silicon compound includes at least one or more kinds of Li2SiO3 and Li4SiO4; the particles of silicon compound contain nickel; and, a mass of the nickel to a mass of the particles of negative electrode active material is 2 mass ppm or more and 100 mass ppm or less. Thus, when used as the negative electrode active material of a secondary battery, a negative electrode active material capable of improving the initial charge/discharge characteristics and cycle characteristics is provided.
    Type: Application
    Filed: October 24, 2016
    Publication date: October 4, 2018
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takumi MATSUNO, Takakazu HIROSE, Hiromichi KAMO, Masahiro FURUYA, Hidekazu AWANO
  • Publication number: 20170352914
    Abstract: A lithium-cobalt-based composite oxide used for a positive electrode active material of an electrochemical device, wherein the lithium-cobalt-based composite oxide has elutable fluoride ions, the elutable fluoride ions being eluted to an eluate when the lithium-cobalt-based composite oxide is dispersed to ultrapure water, in a mass ratio of 500 ppm or more and 15000 ppm or less in comparison with the lithium-cobalt-based composite oxide, and the lithium-cobalt-based composite oxide has a composition shown by the following general formula (1): Li1-xCo1-zMzO2-aFa (?0.1?x<1, 0?z<1, 0?a<2) . . . (1) (wherein, M represents one or more kinds of metal element selected from the group of Mn, Ni, Fe, V, Cr, Al, Nb, Ti, Cu, and Zn).
    Type: Application
    Filed: November 24, 2015
    Publication date: December 7, 2017
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Hidekazu AWANO, Hiromichi KAMO, Takakazu HIROSE, Hiroki YOSHIKAWA
  • Publication number: 20170331116
    Abstract: The present invention is a lithium-phosphorus-based composite oxide/carbon composite used for a positive electrode active material of an electrochemical device, including lithium-phosphorus-based composite oxide with the surface being coated with carbon, wherein the lithium-phosphorus-based composite oxide/carbon composite has elutable fluoride ions, which are eluted to an elute from the composite dispersed to ultrapure water, in a mass ratio of 500 ppm or more and 15000 ppm or less in comparison with the lithium-phosphorus-based composite oxide/carbon composite, and the lithium-phosphorus-based composite oxide has a composition of the following general formula (1): Li1-xFe1-zMzPO4-aFa(?0.1?x<1,0?z?1,0?a?4)??(1) (wherein, M represents one or more kinds of metal element selected from the group of Mn, Ni, Co, V, Cr, Al, Nb, Ti, Cu, and Zn).
    Type: Application
    Filed: November 13, 2015
    Publication date: November 16, 2017
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Hidekazu AWANO, Hiromichi KAMO, Takakazu HIROSE, Hiroki YOSHIKAWA
  • Publication number: 20120319034
    Abstract: A lithium secondary battery active material in which lithium titanate that can supply excellent rapid charge and discharge characteristics to a lithium secondary battery when used as a negative electrode active material of the lithium secondary battery is used, and a lithium secondary battery that is manufactured using the lithium secondary battery active material and is excellent in terms of, particularly, rapid charge and discharge characteristics. The lithium secondary battery active material of the invention is composed of lithium titanate which has a spinel structure, has a content of sulfate radicals of 100 ppm to 2500 ppm in terms of sulfur atoms and a content of chlorine of 1500 ppm or less, and is expressed by a general formula LixTiyO12 (however, in the formula, the atomic ratio of Li/Ti is 0.70 to 0.90, x satisfies 3.0?x?5.0, and y satisfies 4.0?y?6.0).
    Type: Application
    Filed: November 25, 2010
    Publication date: December 20, 2012
    Applicant: Nippon Chemical Industrial Co., Ltd.
    Inventors: Hidekazu Awano, Katsuyuki Negishi
  • Publication number: 20120175552
    Abstract: There is provided a positive electrode active material for lithium secondary batteries which suppresses gelation when kneaded with a binder resin in producing a positive electrode material and provides excellent coating properties. The positive electrode active material for lithium secondary batteries comprises a lithium composite oxide represented by the following general formula (1) and a Ca atom contained in the lithium composite oxide. When the positive electrode active material is analyzed by X-ray diffraction using Cu—K? radiation as a radiation source, the intensity ratio (b/a) of (b) the diffraction peak at 2?=18.7±0.2° to (a) the diffraction peak at 2?=37.4±0.2° derived from CaO is from 10 to 150. LixNi1-y-zCoyMezO2 (1) In the formula, Me represents a metal element having an atomic number of 11 or more other than Co and Ni; and x, y, and z are represented by the formulae 0.98?x?1.20, 0<y?0.5, and 0<z?0.5, respectively, provided that y+z<1.
    Type: Application
    Filed: March 21, 2012
    Publication date: July 12, 2012
    Applicant: NIPPON CHEMICAL INDUSTRIAL CO., LTD.
    Inventors: Minoru Fukuchi, Hidekazu Awano, Yuuki Anbe
  • Patent number: 8137844
    Abstract: A method for manufacturing a cathode active material for a lithium rechargeable battery, including: selecting a first metal compound from a group consisting of a halide, a phosphate, a hydrogen phosphate and a sulfate of Mg or Al; selecting a second metal compound from a group consisting of an oxide, a hydroxide and a carbonate of Mg or Al; combining the first metal compound and the second metal compound to obtain a metal compound, the metal compound containing either Mg or Al atoms; mixing a lithium compound, a transition metal compound and the metal compound to obtain a mixture; and sintering the mixture.
    Type: Grant
    Filed: November 16, 2007
    Date of Patent: March 20, 2012
    Assignee: Nippon Chemical Industrial Co., Ltd.
    Inventors: Hidekazu Awano, Minoru Fukuchi, Yuuki Anbe