Patents by Inventor Hidekuni Oda

Hidekuni Oda has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6153807
    Abstract: A copolymer of ethylene and an alpha-olefin having an ethylene content of from 30 to 90 mole %, a number average molecular weight of from 300 to 30,000 and a molecular weight distribution defined by a Q value (the ratio of the weight average molecular weight to the number average molecular weight of not more than 3 and a Z value (the ratio of the maximum value of the molecular weight to the minimum value of the molecular weight when the molecular weight is measured by gel permeation chromatography) of from 15 to 200. The said copolymer can be produced by a process comprising copolymerizing ethylene with an alpha-olefin in the liquid phase in the presence of a polymerization catalyst composed of a combination of a soluble vanadium compound and an organoaluminum compound in the co-presence of hydrogen, characterized in that(a) the copolymerization is carried out in a continuous manner,(b) the concentration of the vanadium compound in the polymerization system is maintained at 0.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: November 28, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hidekuni Oda, Tatuo Kinoshita, Akiyoshi Shimizu
  • Patent number: 5955639
    Abstract: A copolymer of ethylene and an alpha-olefin having an ethylene content of from 30 to 90 mole %, a number average molecular weight of from 300 to 30,000 and a molecular weight distribution defined by a Q value (the ratio of the weight average molecular weight to the number average molecular weight) of not more than 3 and a Z value (the ratio of the maximum value of the molecular weight to the minimum value of the molecular weight when the molecular weight is measured by gel permeation chromatography) of from 15 to 200. The said copolymer can be produced by a process comprising copolymerizing ethylene with an alpha-olefin in the liquid phase in the presence of a polymerization catalyst composed of a combination of a soluble vanadium compound and an organoaluminum compound in the co-presence of hydrogen, characterized in that(a) the copolymerization is carried out in a continuous manner,(b) the concentration of the vanadium compound in the polymerization system is maintained at 0.
    Type: Grant
    Filed: July 29, 1993
    Date of Patent: September 21, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hidekuni Oda, Tatuo Kinoshita, Akiyoshi Shimizu
  • Patent number: 5767331
    Abstract: A copolymer of ethylene and an alpha-olefin having an ethylene content of from 30 to 90 mole %, a number average molecular weight of from 300 to 30,000 and a molecular weight distribution defined by a Q value (the ratio of the weight average molecular weight to the number average molecular weight) of not more than 3 and a Z value (the ratio of the maximum value of the molecular weight to the minimum value of the molecular weight when the molecular weight is measured by gel permeation chromatography) of from 15 to 200. The said copolymer can be produced by a process comprising copolymerizing ethylene with an alpha-olefin in the liquid phase in the presence of a polymerization catalyst composed of a combination of a soluble vanadium compound and an organoaluminum compound in the co-presence of hydrogen, characterized in that(a) the copolymerization is carried out in a continuous manner,(b) the concentration of the vanadium compound in the polymerization system is maintained at 0.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: June 16, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidekuni Oda, Tatuo Kinoshita, Akiyoshi Shimizu
  • Patent number: 5658998
    Abstract: A random copolymer characterized in that (A) the copolymer comprises polymerized units from ethylene and polymerized units from at least one cycloolefin, (B) the mole ratio of the polymerized units from the cycloolefin to the polymerized units from ethylene is from 3:97 to 60:40, (C) the cycloolefin is incorporated in the polymer chain without ring opening, (D) the copolymer has an intrinsic viscosity of 0.01 to 20 dl/g, (E) the copolymer has a molecular weight distribution (Mw/Mn) of not more than 4, and (F) the copolymer has a crystallinity of 0 to 10%. The random copolymer may be grafted by (a) alpha, beta-unsaturated carboxylic acids and/or their derivatives, (b) styrenes, (c) organic silicon compounds having an olefinically unsaturated bond and a hydrolyzable group, or (d) unsaturated epoxy monomers.
    Type: Grant
    Filed: March 17, 1995
    Date of Patent: August 19, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Syuji Minami, Hirokazu Kajiura, Hidekuni Oda
  • Patent number: 5654386
    Abstract: A random copolymer characterized in that (A) the copolymer comprises polymerized units from ethylene and polymerized units from at least one cycloolefin, (B) the mole ratio of the polymerized units from the cycloolefin to the polymerized units from ethylene is from 3:97 to 60:40, (C) the cycloolefin is incorporated in the polymer chain without ring opening, (D) the copolymer has an intrinsic viscosity of 0.01 to 20 dl/g, (E) the copolymer has a molecular weight distribution (Mw/Mn) of not more than 4, and (F) the copolymer has a crystallinity of 0 to 10%. The random copolymer may be grafted by (a) alpha, beta-unsaturated carboxylic acids and/or their derivatives, (b) styrenes, (c) organic silicon compounds having an olefinically unsaturated bond and a hydrolyzable group, or (d) unsaturated epoxy monomers.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 5, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Syuji Minami, Hirokazu Kajiura, Hidekuni Oda
  • Patent number: 5179171
    Abstract: A random copolymer characterized in that (A) the copolymer comprises polymerized units from ethylene and polymerized units from at least one cycloolefin, (B) the mole ratio of the polymerized units from the cycloolefin to the polymerized units from ethylene is from 3:97 to 60:40, (C) the cycloolefin is incorporated in the polymer chain without ring opening, (D) the copolymer has an intrinsic viscosity of 0.01 to 20 dl/g, (E) the copolymer has a molecular weight distribution (Mw/Mn) of not more than 4, and (F) the copolymer has a crystallinity of 0 to 10%. The random copolymer may be grafted by (a) alpha, beta-unsaturated carboxylic acids and/or their derivatives, (b) styrenes, (c) organic silicon compounds having an olefinically unsaturated bond and a hydrolyzable group, or (d) unsaturated epoxy monomers.
    Type: Grant
    Filed: February 10, 1992
    Date of Patent: January 12, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Syuji Minami, Hirokazu Kajiura, Hidekuni Oda, Hideaki Yamaguchi
  • Patent number: 4614778
    Abstract: A random copolymer comprising ethylene, a 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene and optionally an alpha-olefin having at least three carbon atoms or cycloolefin. The mole ratio of polymerized units from the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene to polymerized units from ethylene is from 3:97 to 95:5 and the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene is incorporated in the polymer chain as polymerized units without ring-opening.The copolymer is prepared by copolymerizing ethylene with the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene in a hydrocarbon medium in the presence of a catalyst formed from a vanadium compound and an organoaluminum compound which are soluble in the hydrocarbon medium.The copolymer has excellent transparency and a well balanced combination of heat resistance, heat aging resistance, chemical and solvent resistance, dielectric properties and mechanical properties such as rigidity.
    Type: Grant
    Filed: January 29, 1985
    Date of Patent: September 30, 1986
    Inventors: Hirokazu Kajiura, Hidekuni Oda, Syuji Minami
  • Patent number: 4588794
    Abstract: A rubbery copolymer of ethylene, 1-butene and a polyene, characterized by having (A) an ethylene/1-butene mole ratio of from 86/14 to 95/5, (B) an iodine value of from 2 to 40, (C) an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.8 to 4 dl/g, and (D) a weight average molecular weight/number average molecular weight ratio (Mw/Mn) of less than 3; and a process for the production thereof.
    Type: Grant
    Filed: August 28, 1984
    Date of Patent: May 13, 1986
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidekuni Oda, Kazuhiko Murata, Hirokazu Kajiura, Akira Matsuda
  • Patent number: 4510303
    Abstract: An ethylene-alpha-olefin-polyene random copolymer rubber comprising ethylene, an alpha-olefin having 3 to 10 carbon atoms and a polyene, wherein (A) a molar ratio of ethylene/alpha-olefin is 55/45 to 95/5, (B) the polyene is a mixture of 5-ethylidene-2-norbornene (ENB) and 5-vinyl-2-norbornene (VNB) in a molar ratio of ENB/VNB of 1/1 to 20/1, (C) an iodine value of the copolymer rubber is 2 to 40, (D) an intrinsic viscosity [.eta.] of the copolymer rubber is 1.0 to 6.0 dl/g measured in decalin at 135.degree. C., and (E) g.sub..eta. * defined by a ratio of the intrinsic viscosity [.eta.] to an intrinsic viscosity [.eta.]l of a linear ethylene-propylene random copolymer having an ethylene content of 70 mole % and the same weight-average molecular weight determined by a light-scattering method as that of the copolymer rubber is 0.2 to 0.9. Also a process for preparing this random copolymer rubber and vulcanizate derived from the same are also disclosed.
    Type: Grant
    Filed: May 6, 1983
    Date of Patent: April 9, 1985
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidekuni Oda, Syuji Minami, Hiroshi Inoue, Akira Matsuda, Yohzoh Yamamoto
  • Patent number: 4259468
    Abstract: A rubbery copolymer of ethylene, an .alpha.-olefin having 3 to 10 carbon atoms and a polyene, characterized by having (A) an ethylene/.alpha.-olefin mole ratio of from 50/50 to 95/5, (B) an iodine value of from 5 to 50, (C) an intrinsic viscosity [.eta.], measured in decaline at 135.degree. C., of from 1.0 to 6.0 dl/g, (D) a weight average molecular weight/number average molecular weight ratio (Mw/Mn) of from 3 to 15, and (E) an iodine value index .alpha..sub.1 for the lower molecular weight components and an iodine value index .alpha..sub.2 for the higher molecular weight components, said .alpha..sub.1 and .alpha..sub.2 falling within the ranges -30.ltoreq..alpha..sub.1 .ltoreq.0 and 0<.alpha..sub.2 .ltoreq.30. Said copolymer can be obtained by copolymerizing ethylene, the .alpha.-olefin having 3 to 10 carbon atoms and polyene at a temperature of from about 40.degree. C. to about 100.degree. C. in the presence of a catalyst composed of (a) a vanadium compound of the formula VO(OR).sub.n X.sub.
    Type: Grant
    Filed: August 7, 1979
    Date of Patent: March 31, 1981
    Assignee: Mitsui Petrochemical Industries Ltd.
    Inventors: Hirokazu Kajiura, Kazuhiko Murata, Hidekuni Oda, Tatsuo Yasutake
  • Patent number: 4252909
    Abstract: A free expandable rubbery composition comprising an ethylene/.alpha.-olefin copolymer or terpolymer, a blowing agent and a crosslinking agent, said ethylene/.alpha.-olefin co- or terpolymer simultaneously meeting the following requirements (A), (B) and (C):(A) it contains 55 to 73 mole % of an ethylene unit,(B) it has an (EB.times.TS) value of at least 7,000 wherein EB represents the break elongation (%) of the co- or terpolymer and TS is the maximum tensile strength (kg/cm.sup.2) of the co- or terpolymer, and(C) it has a Mooney viscosity, ML.sub.1+4 at 121.degree. C., of 65 to 120.This composition can be used for the production of a crosslinked and foamed rubbery article by the free expansion method.
    Type: Grant
    Filed: March 6, 1979
    Date of Patent: February 24, 1981
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kiyoshi Honma, Hidekuni Oda
  • Patent number: 4168361
    Abstract: A random copolymer consisting essentially of 40 to 90 mole% of propylene and 60 to 10 mole% of 1-butene, and having (A) a boiling n-heptane-insoluble content of not more than 5% by weight based on the weight of the copolymer, (B) a boiling methyl acetate-soluble content of not more than 2% by weight based on the weight of the copolymer, (C) a melting point, determined by differential thermal analysis, of 40 to 140.degree. C., (D) an intrinsic viscosity, determined in decalin at 135.degree. C., of 0.5 to 6 dl/g, (E) an elongation at break, measured by JIS K6301, of at least 300%, (F) a tensile strength at break, measured by JIS K6301, of at least 50 kg/cm.sup.2, and (G) a haze, measured by JIS K6714, of not more than 40%.
    Type: Grant
    Filed: December 19, 1977
    Date of Patent: September 18, 1979
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidekuni Oda, Yozo Yamamoto, Hirokazu Kajiura, Syuji Minami, Takao Ohno