Abstract: Tourmaline fine powders are mixed with glass powders having melting point between 500.degree. C. and the transition temperature of tourmaline, and the grains are formed from the mixture and sintered at a temperature below melting point of the glass. Tourmaline powders are stacked in the glass matrix in the tourmaline composite grains prepared above. When water passes through a case including many such grains, the water contacts with the grains and is converted to activated water by the grains. By using the activated water, a structure such as a moving vehicle or an outer wall of a building can be washed efficiently without a detergent. Further, the grains can be used in an apparatus for recycling wash water.

Abstract: Tourmaline fine powders are mixed with glass powders having melting point between 500.degree. C. and the transition temperature of tourmaline, and the grains are formed from the mixture and sintered at a temperature below melting point of the glass. Tourmaline powders are stacked in the glass matrix in the tourmaline composite grains prepared above. When water passes through a case including many such grains, the water contacts with the grains and is converted to activated water by the grains. By using the activated water, a structure such as a moving vehicle or an outer wall of a building can be washed efficiently without a detergent. Further, the grains can be used in an apparatus for recycling wash water.