Abstract: In a sliding structure for an internal combustion, a cylinder has recesses in a stroke center region. Piston rings have inclined surfaces on an outer circumferential surface, and a lubricating oil flows between the inner wall surface and the outer circumferential surface that relatively move via the inclined surfaces. At any RPM equal to or greater than at idle, a center friction coefficient at the stroke center region through which the piston rings pass at the highest speed is less than a center friction coefficient when no recesses are formed in the stroke center region. Contrarily, at the RPM, an outside friction coefficient when the piston rings pass through a region outside the stroke center region is less than an outside friction coefficient when the recesses are formed in the outside region. As a result, further improved low fuel efficiency is achieved for the dimple liner technique.

Abstract: In a sliding structure for an internal combustion, a cylinder has recesses in a stroke center region. Piston rings have inclined surfaces on an outer circumferential surface, and a lubricating oil flows between the inner wall surface and the outer circumferential surface that relatively move via the inclined surfaces. At any RPM equal to or greater than at idle, a center friction coefficient at the stroke center region through which the piston rings pass at the highest speed is less than a center friction coefficient when no recesses are formed in the stroke center region. Contrarily, at the RPM, an outside friction coefficient when the piston rings pass through a region outside the stroke center region is less than an outside friction coefficient when the recesses are formed in the outside region. As a result, further improved low fuel efficiency is achieved for the dimple liner technique.

Abstract: A production method for a composite of fine particles (A) and carbon particles (B), including the steps of: mixing fine particles (A) formed of a substance comprising at least one kind of Si, Sn, Al, Ge and In; and molten pitch, to obtain a mixture (1); pulverizing the mixture (1) to obtain a pulverized product (2a); dry-mixing the pulverized product (2a) and carbon particles (B) to obtain a mixture (3a); and firing the mixture (3a), followed by pulverization; or including the steps of: adding carbon particles (B) to the mixture (1), followed by dry mixing and pulverizing, to obtain a pulverized product (2b); and firing the pulverized product (2b), followed by pulverization.

Abstract: A negative electrode material for a lithium ion battery containing a composite material, the composite material including silicon-containing particles, graphitic carbon material particles, and a carbonaceous carbon material, in which the composite material has a ratio (A/B) of an area (A) of a peak near 100 eV derived from metal Si to an area (B) of a peak near 103 eV derived from silicon oxide, as measured by XPS, of not less than 0.10 and not more than 2.30. Also disclosed is a paste including the negative electrode material, as well as a negative electrode for a lithium ion battery including a formed body of the paste and a lithium ion battery including the negative electrode.

Abstract: The present invention relates to a negative electrode material for a lithium ion battery, made of a composite material comprising silicon-containing particles, artificial graphite particles and a carbon coating layer, wherein the silicon-containing particles are silicon particles having a SiOx layer (0<x?2) on a particle surface, have an oxygen content ratio of 1 mass % or more and 18 mass % or less, and mainly comprise particles having a primary particle diameter of 200 nm or less; and the artificial graphite particles have a scale-like shape. By using the negative electrode material, a lithium ion battery having a high capacitance and excellent charge-discharge cycle characteristics can be produced.

Abstract: A negative electrode material for lithium ion batteries is obtained by a method which includes: mixing carbon particles (B) such as graphite particles, particles (A), such as Si particles, containing an element capable of occluding and releasing lithium ions, a carbon precursor such as sucrose, a carboxylic acid compound such as acetic acid, and a liquid medium such as water or isopropyl alcohol to prepare a slurry; drying and solidifying the slurry; and heat-treating the resulting solidified material to carbonize the carbon precursor. A lithium ion battery is obtained using this negative electrode material.

Abstract: A negative electrode material for a lithium ion battery containing a composite material, the composite material including silicon-containing particles, graphitic carbon material particles, and a carbonaceous carbon material, in which the composite material has a ratio (A/B) of an area (A) of a peak near 100 eV derived from metal Si to an area (B) of a peak near 103 eV derived from silicon oxide, as measured by XPS, of not less than 0.10 and not more than 2.30. Also disclosed is a paste including the negative electrode material, as well as a negative electrode for a lithium ion battery including a formed body of the paste and a lithium ion battery including the negative electrode.

Abstract: The present invention relates to a negative electrode material for a lithium ion battery, made of a composite material comprising silicon-containing particles, artificial graphite particles and a carbon coating layer, wherein the silicon-containing particles are silicon particles having a SiOx layer (0<x?2) on a particle surface, have an oxygen content ratio of 1 mass % or more and 18 mass % or less, and mainly comprise particles having a primary particle diameter of 200 nm or less; and the artificial graphite particles have a scale-like shape. By using the negative electrode material, a lithium ion battery having a high capacitance and excellent charge-discharge cycle characteristics can be produced.

Abstract: A production method for a composite of fine particles (A) and carbon particles (B), including the steps of: mixing fine particles (A) formed of a substance comprising at least one kind of Si, Sn, Al, Ge and In; and molten pitch, to obtain a mixture (1); pulverizing the mixture (1) to obtain a pulverized product (2a); dry-mixing the pulverized product (2a) and carbon particles (B) to obtain a mixture (3a); and firing the mixture (3a), followed by pulverization; or including the steps of: adding carbon particles (B) to the mixture (1), followed by dry mixing and pulverizing, to obtain a pulverized product (2b); and firing the pulverized product (2b), followed by pulverization.

Abstract: A negative electrode material for a lithium ion battery, in which a fine particle (A) containing an element selected from Si, Sn, Ge and In and a carbon particle (B) obtained by heat-treating a petroleum-based coke and/or a coal-based coke at a temperature of 2,500° C. or more are connected through a chemical bond such as urethane bond, urea bond, siloxane bond and ester bond. Also disclosed are a negative electrode sheet obtained by coating a current collector with a paste containing the negative electrode material, a binder and a solvent, and then drying and pressure-forming the paste; and a lithium ion battery incorporating the negative electrode sheet.

Abstract: A negative electrode material for use in a lithium-ion battery is obtained by a method comprising subjecting a carbon particle (B) comprising a graphite material or the like to surface treatment with an oxidizing agent and then removing a residue of the oxidizing agent, modifying the carbon particle (B) from which the residue of the oxidizing agent has been removed with a silane coupling agent, modifying a particle (A) comprising an element capable of occluding and releasing a lithium ion, such as a Si particle, with a silane coupling agent, linking the modified carbon particle (B) and the modified particle (A) via a chemical bond, and coating a composite particle comprising the particle (A) and the carbon particle (B) linked to the particle (A) via a chemical bond with carbon.

Abstract: A negative electrode material for lithium ion batteries is obtained by a method which includes: mixing carbon particles (B) such as graphite particles, particles (A), such as Si particles, containing an element capable of occluding and releasing lithium ions, a carbon precursor such as sucrose, a carboxylic acid compound such as acetic acid, and a liquid medium such as water or isopropyl alcohol to prepare a slurry; drying and solidifying the slurry; and heat-treating the resulting solidified material to carbonize the carbon precursor. A lithium ion battery is obtained using this negative electrode material.

Abstract: A negative electrode material for a lithium ion battery, in which a fine particle (A) containing an element selected from Si, Sn, Ge and In and a carbon particle (B) obtained by heat-treating a petroleum-based coke and/or a coal-based coke at a temperature of 2,500° C. or more are connected through a chemical bond such as urethane bond, urea bond, siloxane bond and ester bond. Also disclosed are a negative electrode sheet obtained by coating a current collector with a paste containing the negative electrode material, a binder and a solvent, and then drying and pressure-forming the paste; and a lithium ion battery incorporating the negative electrode sheet.

Abstract: A piston ring reduces reciprocating friction between a piston and an inner wall surface of a cylinder, while maintaining reduction effect of the reciprocating friction. The piston ring is mounted in a ring groove of the piston, and slides against the inner wall surface of a cylinder liner or a cylinder. The piston ring includes: plural fine recessed portions formed in a barrel width region on an outer peripheral sliding surface of the piston ring; and a non-recessed portion area where no recessed portions are formed in the barrel width region. The non-recessed portion area is configured to have an area percentage within a range from 20-85% in the barrel width region where an area percentage of the barrel width region before the recessed portions are formed is defined to be 100%. The non-recessed portion area exists through an entire cross section in an axial direction of the barrel width.

Abstract: A cylinder realizing reduced reciprocation friction between a piston ring and a bore surface of the cylinder in a region where the piston ring slides. The cylinder in which a piston slides on a bore surface of the cylinder. A plurality of recesses is formed in a stroke center region in the bore surface of the cylinder. The stroke center region is a region between an under face position of a ring groove for a bottom piston ring at a top dead center of the piston and a top face position of a ring groove for a top piston ring at a bottom dead center of the piston. The total of areas of all of the recesses is in the range of 1% to 80% when an area of the stroke center region is 100%, and the recesses are not formed in a region other than the stroke center region of the bore surface of the cylinder.

Abstract: A cylinder realizing reduced reciprocation friction between a piston ring and a bore surface of the cylinder in a region where the piston ring slides. The cylinder in which a piston slides on a bore surface of the cylinder. A plurality of recesses is formed in a stroke center region in the bore surface of the cylinder. The stroke center region is a region between an under face position of a ring groove for a bottom piston ring at a top dead center of the piston and a top face position of a ring groove for a top piston ring at a bottom dead center of the piston. The total of areas of all of the recesses is in the range of 1% to 80% when an area of the stroke center region is 100%, and the recesses are not formed in a region other than the stroke center region of the bore surface of the cylinder.

Abstract: A synthesis experiment automation system is provided with a robot, which transports synthesis reaction containers from a reaction container rack to a dispensing/separation position of a dispensing and separation device, and transports the synthesis reaction containers to a predetermined position in a temperature regulator unit of a reaction device, where a reaction is carried out under previously set experiment conditions; and with a computer, which controls the actions of the robot and the operations of the dispensing and separation device and the reaction device in accordance with a plurality of previously set experiment conditions. Accordingly, the synthesis experiment automation system is capable of simultaneously performing a plurality of different experiments as complex as those usually performed by researchers, and, moreover, has a large number of possible experiment operations, and can easily be improved and/or extended.

Abstract: A 3-[(E)-1-propenyl]cephem compound represented by formula (I): ##STR1## wherein R represents hydrogen, a protective group for an amino group, or the group shown by formula (II): ##STR2## in which R.sup.3 is a protective group for an amino group, R.sup.4 is a protective group for a hydroxyl group, and W is --CH.dbd. or --N.dbd.; R.sup.2 represents a protective group for a carboxyl group; and X represents hydrogen or chlorine. The compound is useful as an intermediate for producing cephem antibiotics and is prepared by isomerizing the corresponding 3-[(Z)-1-propenyl]cephem compound in an inert organic solvent in the presence of an aromatic thiol. The compound of formula (I) wherein X is chlorine can be converted into a 3-[(E)-3-ammonio-1-propenyl]cephem derivative through the reaction with a tertiary amine.

Abstract: A 3-?(E)-1-propenyl!cephem compound represented by formula (I): ##STR1## wherein R represents hydrogen, a protective group for an amino group, or the group shown by formula (II): ##STR2## in which R.sup.3 is a protective group for an amino group, R.sup.4 is a protective group for a hydroxyl group, and W is --CH.dbd. or --N.dbd.; R.sup.2 represents a protective group for a carboxyl group; and X represents hydrogen or chlorine. The compound is useful as an intermediate for producing cephem antibiotics and is prepared by isomerizing the corresponding 3-?(Z)-1-propenyl!cephem compound in an inert organic solvent in the presence of an aromatic thiol. The compound of formula (I) wherein X is chlorine can be converted into a 3-?(E)-3-ammonio-1-propenyl!cephem derivative through the reaction with a tertiary amine.

Abstract: The present invention concerns a process for producing crystals of 3-amino-2-hydroxyacetophenone salt having a high bulk density and improved flow properties, by treating 3-amino-2-hydroxyacetophenone of formula (1) ##STR1## or hydrogen halide salt thereof with sulfuric acid, in a solvent.