Patents by Inventor Hiroki Kawada

Hiroki Kawada has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11713963
    Abstract: Line-edge roughness or line width roughness is evaluated while preventing influence of noise caused by a device or an environment. Therefore, an averaged signal profile 405 in which a moving average of S pixels (S is an integer greater than 1) is taken in a Y direction is obtained from a signal profile showing a secondary electron signal amount distribution in an X direction with respect to a predetermined Y coordinate obtained from a top-down image, an edge position 406 of a line pattern is extracted based on the averaged signal profile, and a noise floor height is calculated based on a first power spectral density 407 of LER data or LWR data based on the extracted edge position and a second power spectral density 409 of a rectangular window function corresponding to the moving average of the S pixels.
    Type: Grant
    Filed: May 29, 2019
    Date of Patent: August 1, 2023
    Assignee: HITACHI HIGH-TECH CORPORATION
    Inventors: Atsuko Shintani, Takahiro Kawasaki, Kazuhisa Hasumi, Masami Ikota, Hiroki Kawada
  • Patent number: 11607667
    Abstract: Provided is a water-absorbing agent that causes no or little fluctuation of feed rate when fed with use of a feeder. A water-absorbing agent containing a water-absorbing resin as a main component, the water-absorbing agent satisfying the following (a) and (b): (a) K-index is 70 or more; and (b) Moisture absorption blocking ratio, after 30 minutes of standing at a temperature of 25° C. and a relative humidity of 80% RH, is 70 weight % or less, the K-index being defined by the following equation: K-index=100?(?438+3.6×angle of repose+3.5×angle of difference+7.9×compressibility rate+290×bulk density (EDANA method)).
    Type: Grant
    Filed: November 14, 2018
    Date of Patent: March 21, 2023
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Hiroki Kawada, Taku Iwamura, Koji Tachi, Makiko Masuda, Yasuhisa Nakashima, Kazushi Torii, Yukihiro Kasano
  • Publication number: 20220034653
    Abstract: Line-edge roughness or line width roughness is evaluated while preventing influence of noise caused by a device or an environment. Therefore, an averaged signal profile 405 in which a moving average of S pixels (S is an integer greater than 1) is taken in a Y direction is obtained from a signal profile showing a secondary electron signal amount distribution in an X direction with respect to a predetermined Y coordinate obtained from a top-down image, an edge position 406 of a line pattern is extracted based on the averaged signal profile, and a noise floor height is calculated based on a first power spectral density 407 of LER data or LWR data based on the extracted edge position and a second power spectral density 409 of a rectangular window function corresponding to the moving average of the S pixels.
    Type: Application
    Filed: May 29, 2019
    Publication date: February 3, 2022
    Inventors: Atsuko Shintani, Takahiro Kawasaki, Kazuhisa Hasumi, Masami Ikota, Hiroki Kawada
  • Patent number: 10961358
    Abstract: To provide a water-absorbing resin composition having both a high centrifuge retention capacity (CRC) and a sufficient urine resistance and a method for producing such a water-absorbing resin composition, an aspect of the present invention is a water-absorbing resin composition having the following properties: (1) A centrifuge retention capacity (CRC) being not less than 35 g/g; (2) A post-degradation-test one-hour eluted soluble component being not more than 19% by mass; (3) An absorbency against pressure 0.7 psi (AAP0.7) being not less than 10 g/g; and (4) A content of a water-absorbing resin in dust being not more than 300 ppm with respect to a total mass of the water-absorbing resin composition.
    Type: Grant
    Filed: September 29, 2017
    Date of Patent: March 30, 2021
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Taku Iwamura, Yasuhisa Nakajima, Kazushi Torii, Taku Fujimoto, Hiroki Kawada
  • Publication number: 20200398253
    Abstract: Provided is a water-absorbing agent that causes no or little fluctuation of feed rate when fed with use of a feeder. A water-absorbing agent containing a water-absorbing resin as a main component, the water-absorbing agent satisfying the following (a) and (b): (a) K-index is 70 or more; and (b) Moisture absorption blocking ratio, after 30 minutes of standing at a temperature of 25° C. and a relative humidity of 80% RH, is 70 weight % or less, the K-index being defined by the following equation: K-index=100?(?438+3.6×angle of repose+3.5×angle of difference+7.9×compressibility rate+290×bulk density (EDANA method)).
    Type: Application
    Filed: November 14, 2018
    Publication date: December 24, 2020
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Hiroki KAWADA, Taku IWAMURA, Koji TACHI, Makiko MASUDA, Yasuhisa NAKASHIMA, Kazushi TORII, Yukihiro KASANO
  • Patent number: 10816333
    Abstract: A pattern measurement method and device realize high-precision measurement of a pattern in a depth direction. The method includes forming an inclined plane in a sample region having a deep hole, a deep groove, or a three-dimensional structure, setting the field of view of a scanning electron microscope to include a boundary between the inclined plane and the sample surface, acquiring an image based on a detection signal, specifying a first position which is the boundary between the inclined plane and a non-inclined plane and a second position which is the position of a desired deep hole or deep groove positioned in the inclined plane, and calculating the height-direction dimension of a pattern constituting the circuit element having the deep hole, deep groove, or three-dimensional structure based on a dimension in the sample surface direction between the first position and the second position and the angle of the inclined plane.
    Type: Grant
    Filed: July 28, 2016
    Date of Patent: October 27, 2020
    Assignee: Hitachi High-Tech Corporation
    Inventor: Hiroki Kawada
  • Patent number: 10665424
    Abstract: A pattern measuring method and a pattern measuring apparatus that efficiently prevent a measurement error inherent to a device that performs beam scanning in a specific direction such as a scanning electron microscope are provided. The invention is directed to a pattern measuring method and a pattern measuring apparatus in which a first curve with respect to an edge of one side and a second curve with respect to an edge of the other side are obtained by calculating a first power spectral density with respect to the edge of one side of a pattern and a second power spectral density with respect to the edge of the other side of the pattern based upon a signal that is obtained when a charged particle beam is scanned in a direction intersecting the edge of the pattern; a difference value between the first curve and the second curve is calculated; and one of the first curve and the second curve is corrected by using the difference value.
    Type: Grant
    Filed: July 26, 2018
    Date of Patent: May 26, 2020
    Assignee: Hitachi High-Tech Corporation
    Inventors: Hiroki Kawada, Takahiro Kawasaki, Junichi Kakuta
  • Patent number: 10562006
    Abstract: The purpose of the present invention is to provide a particulate water absorbing agent having both a high water absorption multiplying factor and a high water absorption rate and a method for manufacturing the same. The present invention is a particulate water absorbing agent for which CRC is 30 to 50 g/g, wherein the weight average particulate diameter (D50) is 200-600 ?m, and the DRC index given by the following formula is a specific value (for example, 43, 30, or 20) or less: DRC index=(49?DRC5min [g/g])/(D50 [?m]/1000).
    Type: Grant
    Filed: March 28, 2017
    Date of Patent: February 18, 2020
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Mariko Tamaki, Daisuke Takagi, Yuichiro Horimoto, Taishi Kobayashi, Taku Fujimoto, Takahiro Kitano, Taku Iwamura, Hiroki Kawada, Hiroyuki Goto, Yasuhisa Nakajima, Hiroyuki Ikeuchi
  • Publication number: 20190338082
    Abstract: To provide a water-absorbing resin composition having both a high centrifuge retention capacity (CRC) and a sufficient urine resistance and a method for producing such a water-absorbing resin composition, an aspect of the present invention is a water-absorbing resin composition having the following properties: (1) A centrifuge retention capacity (CRC) being not less than 35 g/g; (2) A post-degradation-test one-hour eluted soluble component being not more than 19% by mass; (3) An absorbency against pressure 0.7 psi (AAP0.7) being not less than 10 g/g; and (4) A content of a water-absorbing resin in dust being not more than 300 ppm with respect to a total mass of the water-absorbing resin composition.
    Type: Application
    Filed: September 29, 2017
    Publication date: November 7, 2019
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Taku IWAMURA, Yasuhisa NAKAJIMA, Kazushi TORII, Taku FUJIMOTO, Hiroki KAWADA
  • Patent number: 10438771
    Abstract: Provided is a measurement device including: an irradiation optical system which emits a primary charged quantum beam to a sample for scanning; a detector which detects secondary charged particles generated from the sample; and a signal processing unit which processes an output signal from the secondary charged particle detector which has detected the secondary charged particles, in which the signal processing unit includes a measurement unit which measures widths of a first pattern group calibrated with a well-known first dimension and a second pattern group calibrated with a well-known second dimension, and an operation unit which defines a relationship between the well-known dimensions of the first and second pattern groups and length measurement values of the first and second pattern groups as a function.
    Type: Grant
    Filed: September 22, 2016
    Date of Patent: October 8, 2019
    Assignee: Hitachi High-Technologies Corporation
    Inventors: Michio Hatano, Yoshinori Nakayama, Masaru Matsuzaki, Hiroki Kawada, Yoshinori Momonoi, Zhigang Wang
  • Patent number: 10393509
    Abstract: A pattern height measurement device capable of high-precision measurement of the dimensions of a fine pattern, and a charged particle beam device are provided. The pattern height measurement device includes a calculation device that determines dimensions of a sample, in the height direction, based on first reflected light information obtained by dispersing light reflected from a sample. The calculation device determines second reflected light information based on a formula for the relationship between the value for the dimension in the sample surface direction of a pattern formed upon the sample, obtained by irradiation of a charged particle beam on the sample, the value for the dimension in the height direction of the sample, and reflected light information; compares a second reflected light intensity and the first reflected light information; and outputs the value for the dimension in the height direction of the sample in the second reflected light information.
    Type: Grant
    Filed: July 30, 2014
    Date of Patent: August 27, 2019
    Assignee: Hitachi High-Technologies Corporation
    Inventors: Hiroki Kawada, Katsuhiro Sasada, Takenori Hirose, Shou Takami
  • Publication number: 20190170509
    Abstract: The purpose of the present invention is to provide a pattern measurement method and a pattern measurement device, whereby high-precision measurement of a pattern in a depth direction thereof is realized.
    Type: Application
    Filed: July 28, 2016
    Publication date: June 6, 2019
    Inventor: Hiroki KAWADA
  • Publication number: 20190111411
    Abstract: The purpose of the present invention is to provide a particulate water absorbing agent having both a high water absorption multiplying factor and a high water absorption rate and a method for manufacturing the same. The present invention is a particulate water absorbing agent for which CRC is 30 to 50 g/g, wherein the weight average particulate diameter (D50) is 200-600 ?m, and the DRC index given by the following formula is a specific value (for example, 43, 30, or 20) or less: DRC index=(49?DRC5min [g/g])/(D50 [?m]/1000).
    Type: Application
    Filed: March 28, 2017
    Publication date: April 18, 2019
    Inventors: Kazushi TORII, Mariko TAMAKI, Daisuke TAKAGI, Yuichiro HORIMOTO, Taishi KOBAYASHI, Taku FUJIMOTO, Takahiro KITANO, Taku IWAMURA, Hiroki KAWADA, Hiroyuki GOTO, Yasuhisa NAKAJIMA, Hiroyuki IKEUCHI
  • Publication number: 20190066973
    Abstract: A pattern measuring method and a pattern measuring apparatus that efficiently prevent a measurement error inherent to a device that performs beam scanning in a specific direction such as a scanning electron microscope are provided. The invention is directed to a pattern measuring method and a pattern measuring apparatus in which a first curve with respect to an edge of one side and a second curve with respect to an edge of the other side are obtained by calculating a first power spectral density with respect to the edge of one side of a pattern and a second power spectral density with respect to the edge of the other side of the pattern based upon a signal that is obtained when a charged particle beam is scanned in a direction intersecting the edge of the pattern; a difference value between the first curve and the second curve is calculated; and one of the first curve and the second curve is corrected by using the difference value.
    Type: Application
    Filed: July 26, 2018
    Publication date: February 28, 2019
    Inventors: Hiroki KAWADA, Takahiro KAWASAKI, Junichi KAKUTA
  • Patent number: 10184790
    Abstract: The presently disclosed subject matter provides a pattern measurement method and device for achieving highly accurate measurement in the depth direction of a pattern. The method involves a focused ion beam irradiated to form an inclined surface in a sample area; a field of view of a SEM set to include the boundary between the inclined surface and a sample surface; and an image of the field of view obtained on the basis of a detection signal. Such an acquired image is used to specify a first position, the boundary between inclined surface and non-inclined surface, and a second position, the position of a desired deep hole or deep groove positioned within the inclined surface. The pattern dimension in a height direction is determined on the basis of the distance in the sample surface direction between the first position and second position and the angle of the inclined surface.
    Type: Grant
    Filed: May 11, 2015
    Date of Patent: January 22, 2019
    Assignee: HITACHI HIGH-TECHNOLOGIES CORPORATION
    Inventors: Hiroki Kawada, Hideo Sakai, Katsuhiro Sasada
  • Patent number: 10101150
    Abstract: The objective of the present invention is to provide a height measurement device capable of highly accurate measurement in the depth direction of a structure on a sample. To achieve this objective, proposed are a charged particle beam device and a height measurement device that is provided with a calculation device for determining the size of a structure on a sample on the basis of a detection signal obtained by irradiating the sample with a charged particle beam, wherein the calculation device calculates the distance from a first charged particle beam irradiation mark formed at a first height on the sample and a second charged particle beam irradiation mark formed at a second height on the sample and on the basis of this distance and the charged particle beam irradiation angle when the first charged particle beam irradiation mark and second charged particle beam irradiation mark were formed, calculates the distance between the first height and the second height.
    Type: Grant
    Filed: December 10, 2014
    Date of Patent: October 16, 2018
    Assignee: Hitachi High-Technologies Corporation
    Inventors: Hiroki Kawada, Muneyuki Fukuda, Yoshinori Momonoi, Shou Takami
  • Patent number: 10002743
    Abstract: For scanning electron beams and measuring overlay misalignment between an upper layer pattern and a lower layer pattern with high precision, electron beams are scanned over a region including a first pattern and a second pattern of a sample, the sample having the lower layer pattern (the first pattern) and the upper layer pattern (the second pattern) formed in a step after a step of forming the first pattern. The electron beams are scanned such that scan directions and scan sequences of the electron beams become axial symmetrical or point-symmetrical in a plurality of pattern position measurement regions defined within the scan region for the electron beams, thereby reducing measurement errors resulting from the asymmetry of electric charge.
    Type: Grant
    Filed: April 21, 2015
    Date of Patent: June 19, 2018
    Assignee: Hitachi High-Technologies Corporation
    Inventors: Shoji Hotta, Hiroki Kawada, Osamu Inoue
  • Patent number: 9934940
    Abstract: There is provided a control device for controlling a charged particle beam apparatus, wherein the beam apparatus comprises a workpiece stage having at least two turning axes which are not parallel to each other and an irradiation unit, and the control device comprises an angle calculation unit that based on a direction of a first processing in which a processed surface having a normal line not parallel to any of the turning axes is generated in the workpiece by the irradiation unit and a direction of a second processing to be processed by the irradiation unit from a direction different from the direction of the first processing with respect to the processed surface to be generated by the first processing, calculates turning angles about the turning axes that changes the direction of the stage from the direction of the first processing to the direction of the second processing.
    Type: Grant
    Filed: March 24, 2017
    Date of Patent: April 3, 2018
    Assignee: Hitachi High-Tech Science Corporation
    Inventors: Satoshi Tomimatsu, Tsuyoshi Oonishi, Hiroki Kawada, Hideo Sakai
  • Publication number: 20170343340
    Abstract: The objective of the present invention is to provide a height measurement device capable of highly accurate measurement in the depth direction of a structure on a sample. To achieve this objective, proposed are a charged particle beam device and a height measurement device that is provided with a calculation device for determining the size of a structure on a sample on the basis of a detection signal obtained by irradiating the sample with a charged particle beam, wherein the calculation device calculates the distance from a first charged particle beam irradiation mark formed at a first height on the sample and a second charged particle beam irradiation mark formed at a second height on the sample and on the basis of this distance and the charged particle beam irradiation angle when the first charged particle beam irradiation mark and second charged particle beam irradiation mark were formed, calculates the distance between the first height and the second height.
    Type: Application
    Filed: December 10, 2014
    Publication date: November 30, 2017
    Applicant: Hitachi High-Tecnologies Corporation
    Inventors: Hiroki KAWADA, Muneyuki FUKUDA, Yoshinori MOMONOI, Shou TAKAMI
  • Patent number: 9830524
    Abstract: In the present invention, at the time of measuring, using a CD-SEM, a length of a resist that shrinks when irradiated with an electron beam, in order to highly accurately estimate a shape and dimensions of the resist before shrink, a shrink database with respect to various patterns is previously prepared, said shrink database containing cross-sectional shape data obtained prior to electron beam irradiation, a cross-sectional shape data group and a CD-SEM image data group, which are obtained under various electron beam irradiation conditions, and models based on such data and data groups, and a CD-SEM image of a resist pattern to be measured is obtained (S102), then, the CD-SEM image and data in the shrink database are compared with each other (S103), and the shape and dimensions of the pattern before the shrink are estimated and outputted (S104).
    Type: Grant
    Filed: May 24, 2012
    Date of Patent: November 28, 2017
    Assignee: HITACHI HIGH-TECHNOLOGIES CORPORATION
    Inventors: Tomoko Sekiguchi, Takeyoshi Ohashi, Junichi Tanaka, Zhaohui Cheng, Ruriko Tsuneta, Hiroki Kawada, Seiko Hitomi