Abstract: A surface-treated metal material includes a metal sheet, a plating layer formed on the metal sheet and containing aluminum, magnesium, and zinc, and a composite coating formed on a surface of the plating layer, the composite coating including an organic silicon compound, one or two of a zirconium compound and a titanium compound, a phosphoric acid compound, a fluorine compound, and a vanadium compound, wherein, when a surface of the composite coating is analyzed at a spot size of ?30 ?m using micro-fluorescent X-rays, a maximum value of V/Zn, which is a mass ratio of a V content to a Zn content, is 0.010 to 0.100.

Abstract: This surface-treated steel sheet includes: a steel sheet; a Zn-based plating layer formed on the steel sheet; and a coating formed on the Zn-based plating layer, in which a Si concentration, a P concentration, a F concentration, a V concentration, a Zr concentration, a Zn concentration, and an Al concentration of the coating are, by mass %, Si: 10.00% to 25.00%, P: 0.01% to 5.00%, F: 0.01% to 2.00%, V: 0.01% to 4.00%, Zr: 0.01% to 3.00%, Zn: 0% to 3.00%, and Al: 0% to 3.00%, in a narrow spectrum of 5i2p obtained by performing XP S analysis on a surface of the coating, a ratio of an integrated intensity of a peak having a local, maximum value, at 103.37±0.25 eV to an integrated intensity of a peak having a local maximum value at 102.26±0.25 eV is 0.04 or more and 0.25 or less.

Abstract: A surface-treated metal sheet includes a steel sheet, a coating layer containing zinc formed on the steel sheet and a conversion coating formed on the coating layer, wherein the conversion coating contains an organosilicon compound, a phosphate compound and a fluorine compound, and when the surface roughness in a rectangular area with a side of 1 ?m on the surface of the conversion coating is represented by an arithmetic mean height of the scale limited surface Sa, a maximum height of the scale limited surface Sz, and a root mean square height of the scale limited surface Sq, one or more conditions of an arithmetic mean height of the scale limited surface Sa being 0.1 to 10 nm, a maximum height of the scale limited surface Sz being 1 to 1,000 nm, and a root mean square height of the scale limited surface Sq being 0.1 to 100 nm are satisfied.

Abstract: A surface-treated metal material includes a metal sheet, a plating layer formed on the metal sheet and containing aluminum, magnesium, and zinc, and a composite coating formed on a surface of the plating layer, the composite coating including an organic silicon compound, one or two of a zirconium compound and a titanium compound, a phosphoric acid compound, a fluorine compound, and a vanadium compound, wherein, when a surface of the composite coating is analyzed at a spot size of ?30 ?m using micro-fluorescent X-rays, a maximum value of V/Zn, which is a mass ratio of a V content to a Zn content, is 0.010 to 0.100.

Abstract: The object of the invention is to provide a surface-treated steel sheet having a coating having fine adhesiveness to an adhesive on the surface and having excellent corrosion resistance, and a production method thereof. Provided is a surface-treated steel sheet including: a steel sheet; a plated layer containing zinc on the steel sheet; and a coating on the plated layer, wherein the coating contains an acrylic resin, zirconium, vanadium, phosphorus and cobalt, and the acrylic resin has an area ratio of 80 to 100 area % in an area from a surface to a thickness of one-fifth of a film thickness of the coating, and an area ratio of 5 to 50 area % in an area including areas from the film thickness center of the coating to a thickness of one-tenth of the film thickness toward the surface side and toward the plated layer side.

Abstract: A surface-treated steel sheet for fuel tanks, including a Zn—Ni alloy plating layer on one surface or both surfaces of a steel sheet; and a trivalent chromate covering layer or a chromate-free covering layer on the Zn—Ni alloy plating layer, wherein, in a surface outermost layer of the trivalent chromate covering layer or the chromate-free covering layer, concavities, of which a depth from an arithmetic average height of a cross-sectional curve of the surface outermost layer is more than or equal to 0.1 ?m, exist in a proportion of 50 to 1000 concavities/mm2 and at an area ratio of 20 to 80% to a surface area of the steel sheet.

Abstract: The object of the invention is to provide a surface-treated steel sheet having a coating having fine adhesiveness to an adhesive on the surface and having excellent corrosion resistance, and a production method thereof. Provided is a surface-treated steel sheet including: a steel sheet; a plated layer containing zinc on the steel sheet; and a coating on the plated layer, wherein the coating contains an acrylic resin, zirconium, vanadium, phosphorus and cobalt, and the acrylic resin has an area ratio of 80 to 100 area % in an area from a surface to a thickness of one-fifth of a film thickness of the coating, and an area ratio of 5 to 50 area % in an area including areas from the film thickness center of the coating to a thickness of one-tenth of the film thickness toward the surface side and toward the plated layer side.

Abstract: A surface-treated steel sheet for fuel tanks, including: a Zn—Ni alloy plating layer on one surface or both surfaces of a steel sheet; and a trivalent chromate covering layer or a chromate-free covering layer on the Zn—Ni alloy plating layer. The steel sheet consists of, in mass %, C: 0.0005 to 0.0050%, Si: 0.01 to 1.00%, Mn: 0.70 to 2.00%, P: less than or equal to 0.060%, S: less than or equal to 0.010%, Al: 0.01 to 0.30%, N: 0.001 to 0.010%, Ti: 0.010 to 0.050%, Nb: 0.010 to 0.040%, B: 0.0005 to 0.0030%, and the balance: Fe and unavoidable impurities. In a surface outermost layer of the trivalent chromate covering layer or the chromate-free covering layer, concavities, of which a depth from an arithmetic average height of a cross-sectional curve of the surface outermost layer is more than or equal to 0.1 ?m, exist in a proportion of 50 to 1000 concavities/mm2 and at an area ratio of 20 to 80% to a surface area of the steel sheet.

Abstract: A surface-treated steel sheet includes a steel sheet; and a plating layer which is formed on one surface or both surfaces of the steel sheet and which includes zinc and one of the group consisting of vanadium and zirconium, wherein the plating layer includes dendrite-shaped crystals including metallic zinc, and intercrystal filling regions which fill spaces between the dendrite-shaped crystals and show amorphous diffraction patterns when electron beam diffraction is carried out, wherein when the plating layer includes the vanadium, the intercrystal filling regions include a hydrated vanadium oxide or a vanadium hydroxide, and, wherein when the plating layer includes zirconium, the intercrystal filling regions include a hydrated zirconium oxide or a zirconium hydroxide.

Abstract: A metal material of the present invention is composed of an underlying metal and a phosphate compound-based film which is disposed on the surface of the underlying metal and has a surface part, in which the surface part of the phosphate compound-based film contains Zr.

Abstract: A composite coated metal sheet comprising a coated film having a low environmental impact prepared free from hexavalent chromium, and having good corrosion resistance equivalent to that provided by chromate treatment and excellent adhesiveness between the coated film and a resin layer formed on the coated film. Also, a treatment agent and a method of manufacturing the composite coated metal sheet with the treatment agent is described. The composite coated metal sheet comprises a coated film formed on a surface of a plated metal sheet or metal sheet, the coated film contains an oxide and/or a hydroxide of metal other than chromium, and an organic component comprising modified and/or unmodified functional group(s).

Abstract: A metal material of the present invention is composed of an underlying metal and a phosphate compound-based film which is disposed on the surface of the underlying metal and has a surface part, in which the surface part of the phosphate compound-based film contains Zr.

Abstract: A method for production of a metal oxide and/or metal hydroxide coated metal material comprises immersing a metal material or electrolyzing a conductive material in an aqueous treatment solution at pH 2-7 containing metal ion and fluorine ion in a 4-fold or more molar ratio with respect to the metal ion, and/or containing a complex ion comprising at least a metal and fluorine in a 4-fold or more molar ratio with respect to the metal, to form on the surface of the metal material a metal oxide and/or metal hydroxide coating containing the metal ion and/or the metal, as well as a metal oxide and/or metal hydroxide coated metal material having a metal oxide and/or metal hydroxide coating produced by the method.

Abstract: The present invention provides a precoated metal sheet excellent in the coating material adhesion and having little affect on environment. The precoated metal sheet of the invention is a precoated metal sheet comprising a metal or plated metal sheet having stacked on the surface thereof at least a coat layer and an organic resin layer, the metal or plated metal sheet mainly comprising zinc and aluminum and the coat layer mainly comprising one or both of a metal oxide and a metal hydroxide each using a metal species exclusive of chromium.

Abstract: To provide a chemical conversion-treated metal sheet excellent in the corrosion resistance and coating adhesion, free from elution of chromium oxide and small in the environmental load, there is provided a chemical conversion-treated metal sheet comprising a metal sheet having on at least one surface thereof an inorganic film, wherein the inorganic film is a film comprising as a main component one or both of a metal oxide and a metal hydroxide exclusive of Cr and the film contains F.

Abstract: A composite coated metal sheet comprising a coated film having a low environmental impact prepared free from hexavalent chromium, and having good corrosion resistance equivalent to that provided by chromate treatment and excellent adhesiveness between the coated film and a resin layer formed on the coated film. Also, a treatment agent and a method of manufacturing the composite coated metal sheet with the treatment agent is described. The composite coated metal sheet comprises a coated film formed on a surface of a plated metal sheet or metal sheet, the coated film contains an oxide and/or a hydroxide of metal other than chromium, and an organic component comprising modified and/or unmodified functional group(s).

Abstract: There is provided a substrate material, for an HDD suspension, which has excellent adhesion between a stainless steel foil and an insulating resin layer and maintains high etching performance by preventing metal components in the stainless steel from diffusing into the insulating resin layer. The substrate material for an HDD suspension of the invention is a material obtained by shaping a stainless steel foil, wherein, on the surface of the stainless steel foil and on at least one side thereof, there are laminated, at least, a covering layer made chiefly of either one or both of a metal oxide and a metal hydroxide with chromium excluded as the metal species, and an insulating resin layer.

Abstract: The present invention provides a precoated metal sheet excellent in the coating material adhesion and having little affect on environment. The precoated metal sheet of the invention is a precoated metal sheet comprising a metal or plated metal sheet having stacked on the surface thereof at least a coat layer and an organic resin layer, the metal or plated metal sheet mainly comprising zinc and aluminum and the coat layer mainly comprising one or both of a metal oxide and a metal hydroxide each using a metal species exclusive of chromium.

Abstract: The present invention provides a chromate-free coated metal sheet excellent in corrosion resistance and coating material adhesion and having little affect on environment. The precoated metal sheet of the invention is a coated metal sheet comprising a metal sheet having on at least one surface thereof a film mainly comprising one or both of a metal oxide and a metal hydroxide each using a metal species exclusive of chromium, the precoated metal sheet having one or both of cracks in the film and pits on the underlying sheet and having an organic coat layer on the film.

Abstract: To provide a chemical conversion-treated metal sheet excellent in the corrosion resistance and coating adhesion, free from elution of chromium oxide and small in the environmental load, there is provided a chemical conversion-treated metal sheet comprising a metal sheet having on at least one surface thereof an inorganic film, wherein the inorganic film is a film comprising as a main component one or both of a metal oxide and a metal hydroxide exclusive of Cr and the film contains F.