Abstract: A negative electrode including a negative electrode active material layer including a negative electrode active material including a negative electrode active material particle. The negative electrode active material particle includes a silicon compound particle including a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle includes crystalline Li2SiO3 in at least part of the silicon compound particle. Among a peak intensity A derived from Li2SiO3, a peak intensity B derived from Si, a peak intensity C derived from Li2Si2O5, and a peak intensity D derived from SiO2 which are obtained from a 29Si-MAS-NMR spectrum of the silicon compound particle, the peak intensity A is the highest intensity, and the peak intensity A and the peak intensity C satisfy a relationship of the following formula 1: Formula 1: 3C<A.

Abstract: The present invention relates to hollow silica particles, which each includes a shell layer containing silica and a space inside the shell layer, in which the hollow silica particles have a peak intensity derived from SiOH at a wavenumber of around 3,746 cm?1 of 0.60 or less by infrared spectroscopy, a relative permittivity at 1 GHz of from 1.3 to 5.0 and a dielectric loss tangent at 1 GHz of from 0.0001 to 0.05.

Abstract: A negative electrode active material comprising: particles of negative electrode active material, wherein the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5?x?1.6), and wherein the particles of silicon compound have, as chemical shift values obtained from a 29Si-MAS-NMR spectrum, an intensity A of a peak derived from amorphous silicon obtained in ?40 to ?60 ppm, an intensity B of a peak derived from silicon dioxide obtained in the vicinity of ?110 ppm, and an intensity C of a peak derived from Si obtained in the vicinity of ?83 ppm, which satisfy the following formula 1 and formula 2. B?1.

Abstract: A negative electrode active material comprising: particles of negative electrode active material, wherein the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5?x?1.6), and wherein the particles of silicon compound have, as chemical shift values obtained from a 29Si-MAS-NMR spectrum, an intensity A of a peak derived from amorphous silicon obtained in ?40 to ?60 ppm, an intensity B of a peak derived from silicon dioxide obtained in the vicinity of ?110 ppm, and an intensity C of a peak derived from Si obtained in the vicinity of ?83 ppm, which satisfy the following formula 1 and formula 2. B?1.

Abstract: A negative electrode active material includes: particles of negative electrode active material, the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5?x?1.6); the particles of silicon compound contain at least one kind or more of Li2SiO3 and Li4SiO4; the particles of negative electrode active material contain Li2CO3 and LiOH on a surface thereof; and a content of the Li2CO3 is 0.01% by mass or more and 5.00% by mass or less relative to a mass of the particles of negative electrode active material and a content of the LiOH is 0.01% by mass or more and 5.00% by mass or less relative to the mass of the particles of negative electrode active material. Thus a negative electrode active material is capable of improving initial charge/discharge characteristics and the cycle characteristics when used as a negative electrode active material of the secondary battery.

Abstract: A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing a silicon compound (SiOx: 0.5?x?1.6) that contains Li, includes: making a silicon compound into which the lithium has been inserted contact with a solution B containing a polycyclic aromatic compound or a derivative thereof or both thereof (here, the solution B contains one or more kinds selected from an ether-based solvent, a ketone-based solvent, an ester-based solvent, an alcohol-based solvent, and an amine-based solvent as the solvent); and making the silicon compound contact with a solution C (here, the solution C contains one or more kinds selected from an alcohol-based solvent, a carboxylic acid-based solvent, and water as the solvent). Thereby, a production method of a negative electrode active material for non-aqueous electrolyte secondary batteries is capable of increasing a battery capacity and improving the cycle characteristics.

Abstract: A negative electrode active material including a negative electrode active material particle. The negative electrode active material particle includes a silicon compound particle including a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle includes crystalline Li2SiO3 in at least part of the silicon compound particle. Among a peak intensity A derived from Li2SiO3, a peak intensity B derived from Si, a peak intensity C derived from Li2Si2O5, and a peak intensity D derived from SiO2 which are obtained from a 29Si-MAS-NMR spectrum of the silicon compound particle, the peak intensity A is the highest intensity, and the peak intensity A and the peak intensity C satisfy a relationship of the following formula 1.

Abstract: A negative electrode including a negative electrode active material layer including a negative electrode active material including a negative electrode active material particle. The negative electrode active material particle includes a silicon compound particle including a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle includes crystalline Li2SiO3 in at least part of the silicon compound particle.

Abstract: A negative electrode active material includes: particles of negative electrode active material, the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5?x?1.6); the particles of silicon compound contain at least one kind or more of Li2SiO3 and Li4SiO4; the particles of negative electrode active material contain Li2CO3 and LiOH on a surface thereof; and a content of the Li2CO3 is 0.01% by mass or more and 5.00% by mass or less relative to a mass of the particles of negative electrode active material and a content of the LiOH is 0.01% by mass or more and 5.00% by mass or less relative to the mass of the particles of negative electrode active material. Thus a negative electrode active material is capable of improving initial charge/discharge characteristics and the cycle characteristics when used as a negative electrode active material of the secondary battery.

Abstract: A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries containing particles of lithium-containing silicon compound includes: preparing particles of silicon compound containing a silicon compound (SiOx: 0.5?x?1.6); obtaining particles of lithium-containing silicon compound by making the particle of silicon compound contact with a solution A that contains lithium and has an ether-based solvent as a solvent; and heating the particles of the lithium-containing silicon compound. A production method of a negative electrode active material for non-aqueous electrolyte secondary batteries is capable of increasing battery capacity of the negative electrode active material and capable of improving the first time efficiency and cycle characteristics.

Abstract: A negative electrode active material includes a negative electrode active material particle. The negative electrode active material particle includes a silicon compound particle including a silicon compound (SiOx: 0.5?x?1.6). The silicon compound particle includes crystalline Li2Si2O5 in at least part of the silicon compound particle. Among peak intensities A derived from Li2SiO3, B derived from Si, a peak intensity C derived from Li2Si2O5, and D derived from SiO2 which are obtained from a 29Si-MAS-NMR spectrum of the silicon compound particle, the peak intensity C is the highest intensity, and the peak intensity A and the peak intensity C satisfy a relationship of the formula A<C/3. Thus, a negative electrode active material stabilizes a slurry prepared when a negative electrode of a secondary battery is prepared, and improves initial charge and discharge and cycle characteristics when used as a negative electrode active material for a secondary battery.

Abstract: A negative electrode active material including a negative electrode active material particle, wherein the negative electrode active material particle includes a silicon compound particle comprising a silicon compound (SiOx: 0.5?x?1.6), the silicon compound particle includes crystalline Li2SiO3 and Li2Si2O5 in at least part of the silicon compound particle, among a peak intensity A derived from Li2SiO3, a peak intensity B derived from Si, a peak intensity C derived from Li2Si2O5, and a peak intensity D derived from SiO2 which are obtained from a 29Si-MAS-NMR spectrum of the silicon compound particle, the peak intensity A or the peak intensity C is the highest intensity, and the peak intensity A and the peak intensity C satisfy a relationship of the following formula 1,formula 1: C/3?A?3C.

Abstract: The present disclosure relates to a negative electrode active material including: particles of negative electrode active material, wherein the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx: 0.55?x?1.6), and the particles of silicon compound includes at least one or more kinds of Li2SiO3 and Li4SiO4; the particles of silicon compound contain nickel; and, a mass of the nickel to a mass of the particles of negative electrode active material is 2 mass ppm or more and 100 mass ppm or less. Thus, when used as the negative electrode active material of a secondary battery, a negative electrode active material capable of improving the initial charge/discharge characteristics and cycle characteristics is provided.

Abstract: A negative electrode active material contains particle of the negative electrode active material, wherein the particle of the negative electrode active material contains particle of a silicon compound which contains a silicon compound (SiOx: 0.5?x?1.6), the particle of the silicon compound contains lithium, and the particle of the negative electrode active material has a total content rate of a polyphenylene compound component and a polycyclic aromatic component measured by TPD-MS of 1 ppm by mass or more and 4,000 ppm by mass or less. As a result, a negative electrode active material is capable of improving cycle characteristics and initial charge/discharge characteristics when it is used as a negative electrode active material of a lithium ion secondary battery.

Abstract: A negative electrode active material which is a negative electrode active material containing particles of a negative electrode active material, wherein the particles of the negative electrode active material contain particles of a silicon compound which contain a silicon compound (SiOx: 0.5?x?1.6), the particles of the negative electrode active material contain lithium, and the particles of the negative electrode active material have a peak in the range of 2?=31.8±0.5° measured by X-ray diffraction spectrum using K? line of Cu. According to this constitution, it is provided a negative electrode active material capable of improving cycle characteristics and initial charge and discharge characteristics when it is used as a negative electrode active material of a lithium ion secondary battery.

Abstract: A negative electrode active material for a non-aqueous electrolyte secondary battery, wherein the negative electrode active material includes negative electrode active material particles, the negative electrode active material particles include a silicon compound particle which includes a silicon compound including oxygen, the silicon compound particle includes a Li compound, and the silicon compound particle is adhered with a phosphate salt in an outermost surface layer thereof. With this, the negative electrode active material which is high in the capacity and the stability to aqueous slurry as well as excellent in the cycle characteristic and the first efficiency can be provided.

Abstract: A negative electrode active material contains particles of negative electrode active material, wherein the particles of negative electrode active material contain a silicon compound represented by SiOx (0.5?x?1.6), and when the particles of negative electrode active material are measured by an atom probe method, and an Si 75% equivalent concentration surface obtained by the atom probe method is defined to be a boundary surface of a silicon grain, an average diameter of the silicon grains at a center portion of the particle in the particles of negative electrode active material is in the range of 0.25 nm to 5 nm. According to this constitution, when it is used as the negative electrode active material of a secondary battery, a negative electrode active material is capable of increasing battery capacity and improving cycle characteristics.

Abstract: A method for producing a negative electrode active material containing particles of negative electrode active material containing particles of silicon compound. The method includes preparing a container in which silicon has been contained; melting the silicon contained in the container to form a silicon melt; generating a mixed gas in which a silicon gas and a silicon oxide gas are mixed by introducing a raw material which generates a silicon oxide gas into the silicon melt; producing particles of silicon compound containing a silicon compound (SiOx: 0.5x<1.0) by solidifying and depositing the mixed gas on an adsorption plate, and inserting lithium into the particles of silicon compound.

Abstract: A negative electrode active material for non-aqueous electrolyte secondary batteries which has particles of negative electrode active material, the particles of negative electrode active material containing a silicon compound (SiOx: 0.5?x?1.6) that contains a Li compound, including a carbon coating on at least a part of a surface of the silicon compound and a salt coating containing one or more kinds of a metal silicate containing a metal element other than a lithium element and a metal salt containing a metal element other than the lithium element on a part of a surface of the silicon compound or a surface of the carbon coating or both of these. Thus, the negative electrode active material for non-aqueous electrolyte secondary batteries having high stability to an aqueous slurry, high capacity and excellent cycle characteristics and initial efficiency may be provided.

Abstract: The present invention relates to a negative electrode material for nonaqueous electrolyte secondary batteries, which is composed of a silicon composite body that has a structure wherein microcrystals or fine particles of silicon are dispersed in a substance having a composition different from that of the microcrystals or fine particles, said silicon composite body having a crystallite size of the microcrystals or fine particles of 8.0 nm or less as calculated using Scherrer's equation on the basis of the half width of the diffraction peak belonging to Si(220) in an X-ray diffraction. The present invention is able to provide a negative electrode material for nonaqueous electrolyte secondary batteries, which has excellent coulombic efficiency, and a nonaqueous electrolyte secondary battery.