Patents by Inventor Hiromitsu Nagashima
Hiromitsu Nagashima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20160376437Abstract: An aromatic polycarbonate resin composition is obtained by removing a solvent from a resin solution that is obtained by dissolving an aromatic polycarbonate resin-A that has a viscosity-average molecular weight of 3,000-25,000 and an aromatic polycarbonate resin-B that has a viscosity-average molecular weight of 50,000-90,000 into the solvent. The aromatic polycarbonate resin-A is contained in an amount of 99-50% by mass and the aromatic polycarbonate resin-B is contained in an amount of 1-50% by mass relative to the total mass of the aromatic polycarbonate resin-A and the aromatic polycarbonate resin-B; a plate-like molded article having thickness of 3.0 mm and molded from the aromatic polycarbonate resin composition has a haze value of 2% or less; and the number of unmelted polycarbonate pieces having a length of 100 ?m or more and present within a region of 5 cm×3 cm in the plate-like molded article is 10 or less.Type: ApplicationFiled: September 9, 2016Publication date: December 29, 2016Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Shoko SUZUKI, Jun TAJIMA, Hiromitsu NAGASHIMA
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Publication number: 20150299461Abstract: An aromatic polycarbonate resin composition is obtained by removing a solvent from a resin solution that is obtained by dissolving an aromatic polycarbonate resin-A that has a viscosity-average molecular weight of 3,000-25,000 and an aromatic polycarbonate resin-B that has a viscosity-average molecular weight of 50,000-90,000 into the solvent. The aromatic polycarbonate resin-A is contained in an amount of 99-50% by mass and the aromatic polycarbonate resin-B is contained in an amount of 1-50% by mass relative to the total mass of the aromatic polycarbonate resin-A and the aromatic polycarbonate resin-B; a plate-like molded article having thickness of 3.0 mm and molded from the aromatic polycarbonate resin composition has a haze value of 2% or less; and the number of unmelted polycarbonate pieces having a length of 100 ?m or more and present within a region of 5 cm×3 cm in the plate-like molded article is 10 or less.Type: ApplicationFiled: November 26, 2013Publication date: October 22, 2015Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Shoko SUZUKI, Jun TAJIMA, Hiromitsu NAGASHIMA
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Patent number: 8927633Abstract: An aromatic polycarbonate resin composition includes per 100 mass parts of an aromatic polycarbonate resin (A) having an aromatic polycarbonate resin (a1) and an aromatic polycarbonate resin (a2) in a ratio when a total quantity of aromatic polycarbonate resins (a1) and (a2) is denoted as 100 mass percent, (a1):(a2)=99 mass percent to 50 mass percent:1 mass percent to 50 mass percent; 0.01 to 10 mass parts of microparticles (B) selected from the group consisting of polyorganosilsesquioxane microparticles and (meth)acrylic resin microparticles; and 0.005 mass part to 0.1 mass part of a flame retardant (C) in the form of organic sulfonic acid metal salt; wherein a molten resin quantity Q value flowing out of an orifice 1 mm in diameter×10 mm in length at a temperature of 280° C. at a load of 1.57×107 Pa.Type: GrantFiled: August 31, 2012Date of Patent: January 6, 2015Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Jun Tajima, Yutaka Nishibayashi, Hiromitsu Nagashima
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Publication number: 20140221541Abstract: An aromatic polycarbonate resin composition includes per 100 mass parts of an aromatic polycarbonate resin (A) having an aromatic polycarbonate resin (a1) and an aromatic polycarbonate resin (a2) in a ratio when a total quantity of aromatic polycarbonate resins (a1) and (a2) is denoted as 100 mass percent, (a1):(a2)=99 mass percent to 50 mass percent:1 mass percent to 50 mass percent; 0.01 to 10 mass parts of microparticles (B) selected from the group consisting of polyorganosilsesquioxane microparticles and (meth)acrylic resin microparticles; and 0.005 mass part to 0.1 mass part of a flame retardant (C) in the form of organic sulfonic acid metal salt; wherein a molten resin quantity Q value flowing out of an orifice 1 mm in diameter×10 mm in length at a temperature of 280° C. at a load of 1.57×107 Pa.Type: ApplicationFiled: August 31, 2012Publication date: August 7, 2014Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Jun Tajima, Yutaka Nishibayashi, Hiromitsu Nagashima
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Publication number: 20140155548Abstract: To provide an aromatic polycarbonate resin composition which has an impact resistance improved by blending of an impact strength improver and which also has an excellent transparency and a good surface hardness. The aromatic polycarbonate resin composition includes, with respect to 100 parts by mass of a resin component containing 55 to 85 percent by mass of an aromatic polycarbonate resin (A) having a mass average molecular weight of 15,000 to 40,000 and 15 to 45 percent by mass of a (meth)acrylate copolymer (B) which has a mass average molecular weight of 5,000 to 30,000 and which is composed of an aromatic (meth)acrylate unit (b1) and a methyl (meth)acrylate unit (b2) at a mass ratio (b1/b2) of 5 to 50/50 to 95, 1 to 20 parts by mass of an impact strength improver (C). A refractive index nab of the resin component at a wavelength of 589 nm and a refractive index nc of the impact strength improver (C) at a wavelength of 589 nm satisfy the following formula i). ?0.01?nab?nc?+0.Type: ApplicationFiled: June 25, 2012Publication date: June 5, 2014Applicant: Mitsubishi Engineering-Plastics CorporationInventors: Haruhiko Kurokawa, Yutaka Nishibayashi, Hiromitsu Nagashima
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Publication number: 20120129990Abstract: To provide a high-thermal-conductivity polycarbonate resin composition that has further improved thermal conductivity and even insulating properties and flame resistance, and a formed product thereof. A high-thermal-conductivity polycarbonate resin composition, containing: 100 parts by mass of an (A) resin component mainly composed of a polycarbonate resin; 5 parts by mass or more and 100 parts by mass or less of (B) graphitized carbon fiber having a longitudinal thermal conductivity of 100 W/m K or more and an average fiber diameter in the range of 5 to 20 ?m; and 5 parts by mass or more and 200 parts by mass or less of glass beads having an average particle size in the range of 1 to 100 ?m and a sphericity in the range of 1 to 2.Type: ApplicationFiled: June 23, 2011Publication date: May 24, 2012Applicant: Mitsubishi Engineering-Plastics CorporationInventors: Tatsuya Kikuchi, Hiromitsu Nagashima
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Patent number: 6271336Abstract: A process for producing an aromatic-aliphatic copolycarbonate which is excellent in impact resistance and heat resistance and has large Abbe number, small photoelasticity constant, and excellent color tone. The process comprises conducting polycondensation in a reactor made of a stainless steel comprising at least 12 wt % nickel, at least 22 wt % chromium, and at least 50 wt % iron.Type: GrantFiled: November 30, 2000Date of Patent: August 7, 2001Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hiromitsu Nagashima, Shu Yoshida, Satoshi Nagai, Yoshinori Isahaya
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Publication number: 20010002418Abstract: A process for producing an aromatic-aliphatic copolycarbonate which is excellent in impact resistance and heat resistance and has large Abbe number, small photoelasticity constant, and excellent color tone. The process comprises conducting polycondensation in a reactor made of a stainless steel comprising at least 12 wt % nickel, at least 22 wt % chromium, and at least 50 wt % iron.Type: ApplicationFiled: November 30, 2000Publication date: May 31, 2001Inventors: Hiromitsu Nagashima, Shu Yoshida, Satoshi Nagai, Yoshinori Isahaya
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Patent number: 6111097Abstract: In a process of producing a carboxypolysaccharide by oxidizing a polysaccharide in the presence of a ruthenium compound and an oxidizing agent, the expensive ruthenium is easily and efficiently recovered. Ruthenium dissolved in a reaction mixture after the oxidation of the polysaccharide is converted, after or without being subjected to a heat. treatment, to high oxidation sate, which is then recovered by the extraction with a water-insoluble organic solvent. The recovered ruthenium is reduced to low oxidation state and reused in a subsequent production of the carboxypolysaccharide.Type: GrantFiled: June 4, 1999Date of Patent: August 29, 2000Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hiromitsu Nagashima, Hisashi Sakaitani, Hidechika Wakabayashi, Toshiaki Kozaki
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Patent number: 5399334Abstract: This invention provides a process for producing hydrogen peroxide through catalytic reaction of oxygen with hydrogen in an aqueous medium in the presence of a platinum group metal catalyst, in which an organic solvent having only limited solubility with water and less hydrogen peroxide-dissolving ability compared to that of water is caused to be concurrently present in the reactor, and oxygen and hydrogen are catalytically reacted in an aqueous medium in the presence of a water- and organic solvent-insoluble, hydrophilic platinum group metal catalyst, under a low reaction pressure, to form high concentration aqueous hydrogen peroxide solution within a short time.Type: GrantFiled: May 6, 1994Date of Patent: March 21, 1995Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Michiya Kawakami, Yukio Ishiuchi, Hiromitsu Nagashima, Takeshi Tomita, Yasushi Hiramatsu
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Patent number: 5378450Abstract: The present invention provides a process for producing hydrogen peroxide by reacting oxygen and hydrogen in a reaction medium catalytically using, as a catalyst, a tin-modified platinum group metal supported on a carrier. In the process using said catalyst, the presence of halogen and acid in reaction medium is unnecessary unlike the prior art methods, and hydrogen peroxide of high concentration can be produced efficiently. Thus, the present process has no restriction for reactor material as seen the prior art methods and further allows for easy purification of produced hydrogen peroxide.Type: GrantFiled: April 12, 1994Date of Patent: January 3, 1995Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Takeshi Tomita, Yukio Ishiuchi, Michiya Kawakami, Hiromitsu Nagashima
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Patent number: 5320821Abstract: A method for producing a high concentration of hydrogen peroxide by reacting oxygen and hydrogen directly in a neutral reaction medium that contains a promoter comprising a halogen containing compound, which halogen containing compound contains at least one halogen other than fluorine, at a reaction temperature in the range of from 0.degree. to 50.degree. C. and at a reaction pressure in the range of from 3 to 150 kg/cm.sup.2 .multidot.G in the presence of a platinum group metal catalyst supported on a catalyst carrier containing a heteropolyacid that has been made insoluble in water or a platinum group metal catalyst supported on a catalyst carrier comprising activated carbon that is supporting a heteropolyacid.Type: GrantFiled: March 10, 1993Date of Patent: June 14, 1994Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hiromitsu Nagashima, Yukio Ishiuchi, Yasushi Hiramatsu, Michiya Kawakami
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Patent number: 5292496Abstract: Oxygen and hydrogen are catalytically reacted in an acidic reaction medium in the presence of a platinum group metal catalyst to prepare hydrogen peroxide using as a carrier for the platinum group metal catalyst a composite oxide containing cerium. The process need not halogen ions in the acidic reaction medium and enables preparation of hydrogen peroxide in high concentration on an industrial scale advantageously.Type: GrantFiled: October 28, 1992Date of Patent: March 8, 1994Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hiromitsu Nagashima, Yukio Ishiuchi, Yasushi Hiramatsu, Michiya Kawakami
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Patent number: 5236692Abstract: A method for producing a high concentration of hydrogen peroxide by reacting oxygen and hydrogen directly in a reaction medium containing a promoter such as a halogen containing compound using a platinum group metal catalyst supported on a solid acid carrier or a solid super acid carrier.Type: GrantFiled: March 18, 1992Date of Patent: August 17, 1993Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hiromitsu Nagashima, Yukio Ishiuchi, Yasushi Hiramatsu
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Patent number: 5180573Abstract: This invention provides a method for high efficiency, high concentration production of hydrogen peroxide wherein oxygen and hydrogen are reacted in the reaction medium in the presence of a catalyst comprising a metallic or carrier supported platinum group metal catalyst onto which an organic halogen compound which is insoluble in water, which compound excludes compounds which contain no halogen other than fluorine, has been adsorbed or a platinum group metal catalyst supported on a carrier in which a halogenated organic compound, which compound excludes compounds that contain no halogen other than fluorine, has been adsorbed to the carrier prior to supporting the platinum group metal. Since it is not necessary for halogen ions to be present in the reaction medium as it was in the prior art, the problems of deterioration due to the dissolution of the catalyst and of corrosion of the structural materials of the reaction vessel are alleviated.Type: GrantFiled: December 20, 1991Date of Patent: January 19, 1993Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yasushi Hiramatsu, Yukio Ishiuchi, Hiromitsu Nagashima
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Patent number: 5132099Abstract: A method for producing hydrogen peroxide by the reaction of hydrogen and oxygen in the reaction medium in the presence of a platinum group metal catalyst supported on a halogenated resin, in which, since there are no halogen ion nor high concentrations of acid in the reaction medium of this invention as there are in prior art methods, the problems of dissolution of catalyst and corrosion of the reaction vessel are solved.Type: GrantFiled: September 20, 1991Date of Patent: July 21, 1992Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yasushi Hiramatsu, Yukio Ishiuchi, Hiromitsu Nagashima