Abstract: A method for producing a glass preform for an optical fiber is disclosed. The method comprises forming a soot preform of glass fine particles comprising SiO.sub.2 by flame hydrolysis or solution hydrolysis of a starting glass material and sintering the soot preform in an atmosphere containing at least SiF.sub.4 to obtain a glass preform which is free from an increase in absorption due to impurities and has sufficiently low attenuation of light transmission.

Abstract: An improved method for fabricating an optical fiber preform by the vapor phase axial deposition (VAD) method, comprises forming core and cladding soots at the same time by the use of core and cladding burners. The improvement is that the cladding burner is designed so that at least one of the outlets for a feed material gas, a fuel gas, an auxiliary fuel gas, and an inert gas is composed of a plurality of openings. In this improved method, the temperature distribution from the boundary of the core soot to the periphery of the cladding soot is made smooth, and thus the cladding soot is prevented from cracking.

Abstract: A method for producing a glass preform for an optical fiber comprising a core and a cladding containing fluorine is fisclosed. The method comprises forming a porous glass layer of substantially pure quartz on an outer surface of a fused glass rod consisting of a central portion of substantially pure quartz and a peripheral portion of quartz glass containing fluorine, and heating a composite of the fused glass rod and the porous glass layer in an atmosphere containing fluorine to add fluorine to the porous glass layer and to make it transparent, by which contamination of glass with hydroxyl groups can be prevented and light transmission characteristics of an optical fiber fabricated from the glass preform are improved.

Abstract: A method for producing a glass preform for use in the fabrication of an optical fiber which comprises inserting a core rod made of quartz glass in a cladding tube made of quartz glass added with fluorine, heating them from the outside of the cladding tube to fuse them together to form a primary glass preform comprising a core rod and a first cladding layer around the core rod, depositing SiO.sub.2 soot particles around the primary glass preform and thermally treating the soot deposited glass preform in the presence of a fluorine-containing compound to form a final glass preform from which an optical fiber is fabricated. From the glass preform produced by this method, an optical fiber having low attenuation of light transmission in a wide range of wave-length is fabricated.

Abstract: A glass preform for use in the fabrication of a dispersion shifted single mode optical fiber is produced by a method for comprising steps of inserting a core member consisting of an inner core part made of a germanium-added quartz glass which optionally contains fluorine and an outer core part made of a quartz glass having a refractive index smaller than that of the inner core part in a glass tube made of a fluorine-added quartz glass having a refractive index smaller than that of the outer core part, heating the core member and the glass tube to collapse the glass tube and fuse them together to produce a glass perform. The glass preform comprises a core member consisting of an inner core part made of GeO.sub.2 -SiO.sub.2 glass or GeO.sub.2 -F-SiO.sub.2 glass and an outer core part made of F-SiO.sub.2 glass and a cladding made of F-SiO.sub.2 glass and provides a dispersion shifted single mode optical fiber having reduced attenuation of light transmission in the 1.5 .mu.m wavelength band.

Abstract: A method for producing a glass preform for optical fibers in which fluorine is efficiently incorporated into the preform without incorporation of Fe or Cu. A fine glass particle mass, made primarily of quartz, is converted into transparent glass by heating it in a gas atmosphere containing at least a fluorine-based compound gas and a chlorine-based compound gas. The preferred heating range is 1,100.degree. to 1,400.degree. C.

Abstract: A rod-in-tube method for producing a glass preform for use in the fabrication of an optical fiber, which comprises steps of inserting a glass rod constituting a core material in a glass tube constituting a cladding material, heating the rod-tube composite by an outer heating source with introducing, in the gap between the rod and the tube, a gaseous mixture containing a silicon halogenide, a fluorine-containing compound and oxygen gas in which a ratio of silicon and fluorine (Si/F) is larger than 1/300 and smaller than 1/5, and heating and fusing the composite at a temperature not lower than 1,900.degree. C. with filling the gap by a gaseous mixture comprising a halogen-containing compound and oxygen gas; from which glass preform, an optical fiber with low attenuation of light transmission, particularly in a long wavelength range, is fabricated.

Abstract: A method for producing a glass preform for use in fabrication of an optical fiber, which comprises steps of forming a cylindrical rod of glass having a refractive index distribution with axial symmetry around the rod axis by an VAD method, stretching the rod glass to decrease its diameter, inserting the stretched rod in a glass tube having a refractive index distribution with axial symmetry around the tube axis and heating and melting a complex of the stretched rod and the tube to integrate them from the glass preform produced by the method, an optical fiber having precisely controlled refractive index distribution can be fabricated.

Abstract: A method for producing a glass preform for a single mode optical fiber comprising a core and a cladding, which method comprises depositing fine glass particle of a glass raw material on a periphery of a cylindrical seed member having a smooth and clean outer surface by flame hydrolysis to form a soot of the fine glass material, pulling out the seed member from the soot, inserting a core glass rod in a hollow portion of the soot and dehydrating and sintering a complex of a core rod and a cladding to produce a glass preform from which a single mode optical fiber having low attenuation of light transmission, particularly due to absorption by hydroxyl groups can be drawn.

Abstract: A rod-in-tube method for producing a glass preform for use in the fabrication of an optical fiber, which comprises steps of inserting a glass rod as a core material in a glass tube as a cladding material, fusing and closing one end of the cladding material, filling a gap between the core and cladding materials with an atmosphere containing at least one gaseous halogen-containing compound and then heating the core and cladding materials at a temperature not lower than 1,900.degree. C. to collapse the gap between them and to fuse them together, from which glass preform, an optical fiber with low attenuation of light transmission is fabricated.

Abstract: A method of producing a highly pure glass tube having a smooth inner surface, said method comprising the steps ofdepositing by the flame hydrolysis of a glass-forming raw material, a first layer of glass soot particles having a bulk density no greater than 0.2 g/cm.sup.3 on a seed member having a smooth and clean outer surface,depositing on the surface of the first layer of glass soot particles, a second layer of glass soot particles having a bulk density greater than that of the first layer by at least 0.03 g/cm.sup.3,drawing the seed member from the deposited two-layered glass soot preform to form a tube of glass soot particles,removing the first inner layer of glass soot particles from the second layer, either simultaneously with or subsequent to the drawing of the seed member from the soot preform, andheating and vitrifying the tubular glass soot preform to form a transparent solid glass tube.

Abstract: A method for producing a glass preform for an optical fiber by an outside vapor-phase deposition method, which comprises forming fine glass particles by jetting gaseous glass raw material and fuel gas from a first burner to deposit the particles on a seed rod to form a soot rod at such a temperature that a specific bulk density of the soot rod being formed is low and subsequently heating the soot rod by a second burner so as to increase the bulk density of the soot and then sintering the soot rod to obtain a transparent glass preform for an optical fiber, by which method, a highly pure glass preform is produced in a good deposition yield without cracking.

Abstract: A method for producing an optical fiber preform comprising injecting a glass raw material, a gaseous fluorine-containing material and oxygen gas from a first nozzle, inactive gas from a second nozzle which surrounds the first nozzle and hydrogen gas from a third nozzle which surrounds the second nozzle, flame hydrolyzing the glass raw material to synthesis fine glass particles and depositing the fine glass particles on a tip of a rotating seed rod to produce the optical fiber preform containing fluorine.