Patents by Inventor Hiroshi Mizuhata
Hiroshi Mizuhata has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20230236521Abstract: A method of producing a resin particle dispersion for toner, including, cooling a mixture including a resin particle dispersion containing an amorphous resin and a crystalline resin, and an aqueous medium. Where the cooling includes together fluidizing, continuously mixing, and continuously discharging the mixture of the resin particle dispersion and the aqueous medium.Type: ApplicationFiled: December 3, 2020Publication date: July 27, 2023Applicant: KAO CORPORATIONInventors: Sumihiro SUZUKI, Takayuki KIBATA, Tsuyoshi ODA, Hiroshi MIZUHATA
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Patent number: 10662342Abstract: The present invention provides a water-based ink that is excellent in adhesion to a resin printing medium formed of a resin such as polyethylene terephthalate, polyvinyl chloride, polyethylene, polypropylene, nylon, etc., gloss and anti-blocking properties upon storage of the printing medium after printing. The present invention relates to [1] a water-based ink including a colorant, polyester resin particles and modified polyolefin resin particles, in which the polyester resin particles are constituted of a resin containing an amorphous polyester having a glass transition temperature of not lower than 40° C. and not higher than 100° C.Type: GrantFiled: March 31, 2016Date of Patent: May 26, 2020Assignee: KAO CORPORATIONInventors: Hiroto Soma, Hiroshi Mizuhata
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Patent number: 10031432Abstract: According to the present invention, there are provided a process for producing a toner for development of electrostatic images which is capable of suppressing desorption and exposure of a releasing agent therein, and excellent in fusing property, suppression of toner cloud and durability; a process for producing a dispersion, and a kit for producing the dispersion.Type: GrantFiled: June 13, 2014Date of Patent: July 24, 2018Assignee: KAO CORPORATIONInventors: Hiroshi Mizuhata, Koji Shimokusa
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Publication number: 20180134906Abstract: The present invention provides a water-based ink that is excellent in adhesion to a resin printing medium formed of a resin such as polyethylene terephthalate, polyvinyl chloride, polyethylene, polypropylene, nylon, etc., gloss and anti-blocking properties upon storage of the printing medium after printing. The present invention relates to [1] a water-based ink including a colorant, polyester resin particles and modified polyolefin resin particles, in which the polyester resin particles are constituted of a resin containing an amorphous polyester having a glass transition temperature of not lower than 40° C. and not higher than 100° C.Type: ApplicationFiled: March 31, 2016Publication date: May 17, 2018Applicant: Kao CorporationInventors: Hiroto SOMA, Hiroshi MIZUHATA
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Patent number: 9529290Abstract: The present invention relates to a process for producing a toner for electrophotography which is capable of suppressing liberation of a wax from a resin binder and exposure of the wax to a surface of respective toner particles in the step of obtaining fused particles upon production of the toner, and reducing a content of fine powders in the toner, and which is characterized by an excellent low-temperature fusing property and an excellent anti-high-temperature offset property.Type: GrantFiled: October 4, 2013Date of Patent: December 27, 2016Assignee: KAO CORPORATIONInventors: Yasuhiro Shidahara, Manato Ikeda, Hiroshi Mizuhata, Koji Shimokusa
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Publication number: 20160179021Abstract: According to the present invention, there are provided a process for producing a toner for development of electrostatic images which is capable of suppressing desorption and exposure of a releasing agent therein, and excellent in fusing property, suppression of toner cloud and durability; a process for producing a dispersion, and a kit for producing the dispersion.Type: ApplicationFiled: June 13, 2014Publication date: June 23, 2016Applicant: KAO CORPORATIONInventors: Hiroshi MIZUHATA, Koji SHIMOKUSA
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Publication number: 20150277250Abstract: The present invention relates to a process for producing a toner for electrophotography which is capable of suppressing liberation of a wax from a resin binder and exposure of the wax to a surface of respective toner particles in the step of obtaining fused particles upon production of the toner, and reducing a content of fine powders in the toner, and which is characterized by an excellent low-temperature fusing property and an excellent anti-high-temperature offset property.Type: ApplicationFiled: October 4, 2013Publication date: October 1, 2015Applicant: KAO CORPORATIONInventors: Yasuhiro Shidahara, Manato Ikeda, Hiroshi Mizuhata, Koji Shimokusa
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Patent number: 9005868Abstract: The present invention relates to a process for producing a toner for electrophotography which includes the step of fusing aggregated particles containing resin particles (A) and releasing agent particles in an aqueous mixed solution containing the aggregated particles and an anionic surfactant having a polyalkylene glycol moiety with an average molar number of addition of an alkylene oxide having 2 to 3 carbon atoms of from 5 to 100 after and/or while adjusting a pH value of the aqueous mixed solution to 2.0 to 6.0 as measured at 25° C., and a toner for electrophotography obtained by the process.Type: GrantFiled: December 9, 2011Date of Patent: April 14, 2015Assignee: Kao CorporationInventors: Shoichi Murata, Takayuki Ikenaga, Takashi Okuno, Hiroshi Mizuhata, Keishi Yokota, Koji Shimokusa, Koji Kameyama
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Patent number: 8980522Abstract: The present invention relates to a process for producing a toner for development of electrostatic latent images which includes a step (1) of mixing and aggregating resin particles (A), releasing agent particles and an aggregating agent formed of a divalent to pentavalent amine salt in an aqueous medium to obtain aggregated particles, and a toner for development of electrostatic latent images obtained by the process.Type: GrantFiled: December 21, 2011Date of Patent: March 17, 2015Assignee: Kao CorporationInventor: Hiroshi Mizuhata
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Patent number: 8956798Abstract: The present invention relates to a process for producing a toner for electrophotography which is excellent in dispersibility of a colorant in the toner and capable of considerably improving an image density, as well as a toner for electrophotography which is produced by the process. There is provided a process for producing a toner for electrophotography which includes the step of mixing a dispersion of colorant-containing polymer particles with a dispersion of resin particles containing substantially no colorant to aggregate the colorant-containing polymer particles and the resin particles, wherein the polymer contains a constitutional unit derived from a salt-forming group-containing monomer (a) and a constitutional unit derived from an aromatic ring-containing monomer (b).Type: GrantFiled: July 15, 2009Date of Patent: February 17, 2015Assignee: Kao CorporationInventors: Shinichi Sata, Takehiro Tsutsumi, Hiroshi Mizuhata
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Patent number: 8940468Abstract: Disclosed is a process for production of a decolorable toner, including: aggregating dispersed fine particles of a color material comprising at least a color-forming compound, a color-developing agent and a decoloring agent with dispersed fine particles comprising at least a binder resin comprising a polyester resin to form aggregates in an aqueous medium, adding a reactive polymer having an oxazoline group in to the aqueous medium, and fusing the aggregates in the aqueous medium. As a result, it becomes possible to produce a decolorable toner which suppresses the generation of fine powder due to the release of fine particles of an erasable color material from the toner.Type: GrantFiled: June 29, 2012Date of Patent: January 27, 2015Assignee: Toshiba Tec Kabushiki KaishaInventors: Takayasu Aoki, Takafumi Hara, Tsuyoshi Itou, Masahiro Ikuta, Motonari Udo, Koji Shimokusa, Hiroshi Mizuhata
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Patent number: 8652746Abstract: The present invention relates to a process for producing a dispersion of polyester particles which includes the step of emulsifying mixed polyester containing (1) an amorphous polyester containing a constitutional unit derived from a trivalent or higher-valent carboxylic acid in an amount of from 2.0 to 12.0 mol % on the basis of whole constitutional units of the whole amorphous polyester and (2) a crystalline polyester, in an aqueous medium in a single vessel, or the step of mixing the mixed polyester with an organic solvent and then adding the aqueous medium to the resulting mixture to emulsify the mixed polyester in a single vessel.Type: GrantFiled: September 7, 2009Date of Patent: February 18, 2014Assignee: Kao CorporationInventors: Shoichi Murata, Hiroshi Mizuhata, Nobumichi Kamiyoshi, Eiji Shirai
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Patent number: 8652748Abstract: The invention provides a process for producing a toner for electrophotography including the following (1) to (4): (1): adding an aggregating agent to a resin particle dispersion (a) so as to attain an aggregating agent concentration Ea (wt %), to thereby produce an aggregated particle dispersion (A); (2): adding a resin microparticle dispersion (b) to the dispersion (A), to thereby produce a dispersion (B) having an aggregating agent concentration Eb (wt %) satisfying 0.60?Eb/Ea<1; (3): modifying the aggregating agent concentration of the dispersion (B), to thereby produce a dispersion (C) of resin microparticle-deposited aggregated particles, having an aggregating agent concentration Ec (wt %) satisfying 0<Ec/Ea?0.30; and (4): heating the resin microparticle-deposited aggregated particles in the dispersion (C) at a temperature falling within a range between Tg and Tg+20 (0 C) of the resin microparticles in the resin microparticle dispersion (b), to thereby coalesce the aggregated particles.Type: GrantFiled: December 22, 2010Date of Patent: February 18, 2014Assignee: Kao CorporationInventors: Manabu Suzuki, Hiroshi Mizuhata
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Patent number: 8632936Abstract: A method for producing an electrophotographic toner, including steps of: (1) preparing a thermally treated resin particle dispersion by retaining, for one hour or longer at a temperature satisfying the formula: (melting point of the crystalline polyester (a1)?35) (° C.)<T<melting point of the crystalline polyester (a1) (° C.), a dispersion of resin particles (A) having a volume median particle size of 0.Type: GrantFiled: December 17, 2010Date of Patent: January 21, 2014Assignee: KAO CorporationInventors: Shoichi Murata, Eiji Shirai, Hiroshi Mizuhata, Manabu Suzuki
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Publication number: 20130316284Abstract: The present invention relates to a process for producing a toner for development of electrostatic latent images which includes a step (1) of mixing and aggregating resin particles (A), releasing agent particles and an aggregating agent formed of a divalent to pentavalent amine salt in an aqueous medium to obtain aggregated particles, and a toner for development of electrostatic latent images obtained by the process.Type: ApplicationFiled: December 21, 2011Publication date: November 28, 2013Applicant: KAO CORPORATIONInventor: Hiroshi Mizuhata
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Publication number: 20130295499Abstract: The present invention relates to a process for producing a toner for electrophotography which includes the step of fusing aggregated particles containing resin particles (A) and releasing agent particles in an aqueous mixed solution containing the aggregated particles and an anionic surfactant having a polyalkylene glycol moiety with an average molar number of addition of an alkylene oxide having 2 to 3 carbon atoms of from 5 to 100 after and/or while adjusting a pH value of the aqueous mixed solution to 2.0 to 6.0 as measured at 25° C., and a toner for electrophotography obtained by the process.Type: ApplicationFiled: December 9, 2011Publication date: November 7, 2013Applicant: KAO CORPORATIONInventors: Shoichi Murata, Takayuki Ikenaga, Takashi Okuno, Hiroshi Mizuhata, Keishi Yokota, Koji Shimokusa, Koji Kameyama
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Patent number: 8574808Abstract: The present invention relates to a resin emulsion being produced by neutralizing a resin binder containing acid group with a basic compound in an aqueous medium wherein the resin binder containing acid group contains a polyester produced from a raw monomer composition containing a trivalent or higher-valent polyhydric alcohol in an amount of 1 to 15 mol %; a process for producing the resin emulsion; and a toner for electrophotography using the resin emulsion. In the resin emulsion of the present invention, a resin is readily emulsified therein even when using a crosslinked polyester as the resin, and the resin emulsion is substantially free from hydrolysis of the resin and can produce a toner having an excellent heat-resistant storage property.Type: GrantFiled: July 6, 2007Date of Patent: November 5, 2013Assignee: KAO CorporationInventors: Hiroshi Mizuhata, Takashi Kubo, Takashi Mukai
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Patent number: 8460847Abstract: The present invention relates to a toner for electrophotography including a polyester obtained by subjecting a crystalline polyester-containing aqueous dispersion and a non-crystalline polyester-containing aqueous dispersion to aggregation and coalescence, as a resin binder, wherein the crystalline polyester is produced by polycondensing an alcohol component containing 70 mol % or more of an aliphatic diol having 2 to 8 carbon atoms with a carboxylic acid component containing 50 mol % or more of terephthalic acid. The toner is excellent in low-temperature fusing ability and pressure storage stability.Type: GrantFiled: August 14, 2009Date of Patent: June 11, 2013Assignee: Kao CorporationInventors: Eiji Shirai, Takashi Kubo, Hiroshi Mizuhata, Shoichi Murata
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Publication number: 20130011777Abstract: Disclosed is a process for production of a decolorable toner, including: aggregating dispersed fine particles of a color material comprising at least a color-forming compound, a color-developing agent and a decoloring agent with dispersed fine particles comprising at least a binder resin comprising a polyester resin to form aggregates in an aqueous medium, adding a reactive polymer having an oxazoline group in to the aqueous medium, and fusing the aggregates in the aqueous medium. As a result, it becomes possible to produce a decolorable toner which suppresses the generation of fine powder due to the release of fine particles of an erasable color material from the toner.Type: ApplicationFiled: June 29, 2012Publication date: January 10, 2013Applicant: TOSHIBA TEC KABUSHIKI KAISHAInventors: Takayasu Aoki, Takafumi Hara, Tsuyoshi Itou, Masahiro Ikuta, Motonari Udo, Koji Shimokusa, Hiroshi Mizuhata
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Patent number: 8288070Abstract: The present invention relates to a toner for electrophotography which exhibits an excellent heat-resistant storage property and a wide fusing temperature range, and a process for producing the toner for electrophotography.Type: GrantFiled: August 6, 2008Date of Patent: October 16, 2012Assignee: Kao CorporationInventors: Hiroshi Mizuhata, Yutaka Murai, Manabu Suzuki, Hiromi Nambu