Abstract: An inter-cylinder air-fuel ratio imbalance determination apparatus that obtains, based on an output value Vabyfs of an air-fuel ratio sensor, an air-fuel ratio fluctuation indicating amount (AFD) which becomes larger as an air-fuel ratio fluctuation of an exhaust gas passing through a position at which the air-fuel ratio sensor is disposed becomes larger, during a parameter obtaining period. The determination apparatus estimates an air-fuel ratio sensor element temperature (Temps) having a strong relation with responsiveness of the air-fuel ratio sensor during the parameter obtaining period, and obtains a corrected air-fuel ratio fluctuation indicating amount by correcting the AFD based on the estimated Temps.

Abstract: An inter-cylinder air-fuel ratio imbalance determination apparatus (determination apparatus) according to the present invention obtains, based on the output value of the air-fuel ratio sensor 67, an air-fuel ratio fluctuation indicating amount whose absolute value becomes larger as a fluctuation of the air-fuel ratio of the exhaust gas passing through a position at which the air-fuel ratio sensor is disposed becomes larger, and further obtains an imbalance determination parameter which becomes larger as an absolute value of the air-fuel ratio fluctuation indicating amount becomes larger. In addition, the determination apparatus obtains an average value of the air-fuel ratio of the exhaust gas during a period in which the imbalance determination parameter is being obtained, and obtains an imbalance determination threshold which becomes smaller as the average value of the air-fuel ratio is closer to the stoichiometric air-fuel ratio.

Abstract: A positive electrode active material is made of sodium containing oxide. The sodium containing oxide contains NaALiBMO2±? that belongs to a space group P63/mmc of a hexagonal system, where the M includes at least one of manganese (Mn) and cobalt (Co). In the NaALiBMO2±?, the composition ratio A of sodium (Na) is not less than 0.5 and not more than 1.1, the composition ratio B of lithium (Li) is larger than 0 and not more than 0.3, and the ? is not less than 0 and not more than 0.3.

Abstract: An ink composition for ink jet providing excellent in the curability based on ultraviolet irradiation in the presence of water or a solvent, the ejection stability with respect to the factors such as dot loss or flight deflection, and the storage stability of ink. Also provided herein is an ink composition for ink jet including: a pigment; a water-soluble organic solvent; a surfactant; at least either of a urethane (meth)acrylate being represented by the following general formula (1) and having a weight average molecular weight of 1,000 to 10,000 and a cross-linked urethane (meth)acrylate having a constitutional unit including the urethane (meth)acrylate; a compound having a radical polymerizable group(s); a photoradical polymerization initiator; and water: A1-O—(CONH—B1—NHCOO—C1—O)n—CONH—B1—NH—COO-D1??(1) where each of A1, B1, C1, D1, and n in formula (1) are described herein.

Abstract: For the purpose of providing a urethane(meth)acrylate excellent in emulsifiability in water and a production method thereof, and a light curable aqueous emulsion using the urethane(meth)acrylate having a low viscosity and excellent in the curability, provided is a urethane(meth)acrylate being represented by the following general formula (1) and having a weight average molecular weight of 1,000 to 10,000: A1-O—(CONH—B1-NHCOO—C1-O)n-CONH—B1-NH—COO-D1??(1) wherein in formula (1), n represents a natural number of 1 to 30, A1 represents a residue of a hydroxyl group-containing (meth)acrylate, B1 represents a residue of diisocyanate, C1 represents a residue of a diol of an acyclic hydrocarbon or a cyclic hydrocarbon, and D1 represents a residue of a polyoxyalkylene glycol monoalkyl ether.

Abstract: An exhaust gas sensor abnormality diagnostic device includes an exhaust gas sensor, and a judgment means that judges whether execution conditions are established for making an abnormality diagnosis of element breakage in the exhaust gas sensor. The device also includes an abnormality diagnosis means that makes the abnormality diagnosis in accordance with an output signal generated by the exhaust gas sensor. Further, when the integrated value of intake air amounts of an internal combustion engine is not smaller than a predetermined value, the judgment means judges that the execution conditions are established. The abnormality diagnosis means cancels the establishment of the execution conditions when an intake air amount of the internal combustion engine remains less than a predetermined value for a predetermined period of time.

Abstract: An inter-cylinder air-fuel ratio imbalance determination apparatus (determination apparatus) according to the present invention obtains, as an “EGR supplying state imbalance determination parameter”, a value corresponding to a differential value d(abyfs)dt of a detected air-fuel ratio abyfs represented by an output value of an air-fuel ratio sensor when an EGR gas is being supplied, and obtains, as an “EGR stop state imbalance determination parameter”, a value corresponding to a differential value d(abyfs)dt when an EGR gas supply is being stopped. The determination apparatus obtains an “EGR-causing imbalance determination parameter Pegr” by subtracting the EGR stop state imbalance determination parameter Poff from the EGR supplying state imbalance determination parameter Pon, and determines that an inter-cylinder air-fuel ratio imbalance state has occurred due to the supply of the EGR gas when the parameter Pegr is larger than a threshold Pegrth.

Abstract: When the intake air amount is smaller than the specific intake air amount, the unit air-fuel ratio change amount calculated during the engine operation is corrected such that the unit air-fuel ratio change amount increases in the condition that the base unit air-fuel ratio change amount is an upper limit and when the intake air amount is greater than the specific intake air amount, the unit air-fuel ratio change amount calculated during the engine operation is corrected such that the unit air-fuel ratio change amount decreases in the condition that the base unit air-fuel ratio change amount is a lower limit. When the corrected unit air-fuel ratio change amount is greater than the judgment value, it is judged that the inter-cylinder air-fuel ratio imbalance condition occurs.

Abstract: In an exhaust purification system having a urea addition device adding a urea aqueous solution to an NOx catalyst of selective reduction type provided in an exhaust passage in an internal combustion engine, a sensor detecting an ammonia concentration is provided at the downstream side of the NOx catalyst. During fuel cut, a predetermined amount of urea aqueous solution is added. Then, based on a sensor output obtained at this time, an abnormality in at least one of the urea addition device and the urea aqueous solution is detected. The addition of the urea aqueous solution during the fuel cut prevents reactive consumption between urea and NOx. The sensor output corresponding to the amount of the urea aqueous solution is obtained. This output condition is compared with a normal one to allow determination of whether or not an appropriate amount of urea aqueous solution of appropriate quality has been added.

Abstract: An abnormality diagnosis device according to the present invention can calculate a calculation air-fuel ratio A/Fk based upon a fuel injection quantity and an intake air quantity, and determine the abnormality of the air-fuel ratio sensor based upon the calculation air-fuel ratio and an actual air-fuel ratio detected by an air-fuel ratio sensor, when an operating condition in the internal combustion engine relatively rapidly changes according to an engine operating demand and thereby the calculation air-fuel ratio relatively rapidly changes. Since the air-fuel ratio is not forcibly changed and fluctuated, deterioration of the exhaust emission and the combustion state, and deterioration of the vibration and the noise at abnormality diagnosing can be certainly prevented.

Abstract: An apparatus for determining an air-fuel ratio imbalance among cylinders based on an output value of an air-fuel ratio sensor, an imbalance determination parameter which becomes larger or smaller as a difference among air-fuel ratios becomes larger, and performs determining an air-fuel ratio imbalance among cylinders based on a result of a comparison between the imbalance determination parameter and a imbalance determination threshold. The determining apparatus calculates a purge correction coefficient which compensates for a change in the air-fuel ratio due to an evaporated fuel gas which is generated in a fuel tank, while the evaporated fuel gas is being introduced into an intake passage, and corrects a fuel injection amount with the purge correction coefficient FPG.

Abstract: According to a first aspect of the present invention, there is provided an apparatus for detecting variation abnormality in an air-fuel ratio between cylinders comprising a wide-range air-fuel ratio sensor and an O2 sensor provided in an exhaust passage upstream of an exhaust gas purifying apparatus arranged in the exhaust passage for an internal combustion engine having a plurality of cylinders, air-fuel ratio controlling unit for performing air-fuel ratio control for a predetermined period in such a manner as to make an exhaust air-fuel ratio be equal to a stoichiometric air-fuel ratio based upon output from the wide-range air-fuel ratio sensor, and abnormality detecting unit for detecting variation abnormality in an air-fuel ratio between cylinders based upon output from the O2 sensor for the predetermined period when the air-fuel ratio control is performed.

Abstract: The NOx sensor malfunction diagnostic device includes a control section. The control section performs the supplying of an excess amount of reducing agent, which is more than an amount required to reduce adsorbed NOx in a NOx reduction catalyst when a predetermined amount of NOx has been adsorbed in the NOx catalyst, and detects malfunctions of the NOx sensor based on NOx sensor output signal when the excess amount of reduction agent is supplied.

Abstract: An air-fuel ratio imbalance among cylinders determining apparatus according to the present invention comprises an air-fuel ratio sensor having a protective cover and an air-fuel ratio detection element accommodated in the protective cover, and imbalance determining means. The imbalance determining means obtains a detected air-fuel ratio abyfs based on an output Vabyfs of the air-fuel ratio sensor every elapse of a constant sampling time ts, and obtains, as an indicating amount of air-fuel ratio change rate, a difference (detected air-fuel ratio change rate ?AF) between a present detected air-fuel ratio abyfs which is newly detected and a previous air-fuel ratio abyfsold which was detected the sampling time ts ago, an average of the detected air-fuel ratio change rate ?AF, and the like.

Abstract: An air-fuel ratio imbalance among cylinders determining apparatus according to the present invention obtains an output Vabyfs of an air-fuel ratio sensor disposed at a portion downstream of an exhaust gas aggregated portion of an exhaust gas passage, and obtains a second-order differential value d2AF (a change rate of a change rate of a detected air-fuel ratio abyfs) of a detected air-fuel ratio abyfs represented by the air-fuel ratio sensor output Vabyfs. The imbalance determining apparatus determines that an air-fuel ratio imbalance state among cylinders is occurring when a detected air-fuel ratio second-order differential corresponding value (for example, a second-order differential value d2AF per se) obtained in accordance with the second-order differential value d2AF is larger than a first threshold value.

Abstract: An exhaust gas sensor abnormality diagnostic device includes an exhaust gas sensor, and a judgment means that judges whether execution conditions are established for making an abnormality diagnosis of element breakage in the exhaust gas sensor. The device also includes an abnormality diagnosis means that makes the abnormality diagnosis in accordance with an output signal generated by the exhaust gas sensor. Further, when the integrated value of intake air amounts of an internal combustion engine is not smaller than a predetermined value, the judgment means judges that the execution conditions are established. The abnormality diagnosis means cancels the establishment of the execution conditions when an intake air amount of the internal combustion engine remains less than a predetermined value for a predetermined period of time.

Abstract: An air-fuel ratio imbalance among cylinders determining apparatus according to the present invention is applied to a multi-cylinder internal combustion engine in which a compression ratio is variable. The determining apparatus obtains, using at least an output value of an upstream air-fuel ratio sensor disposed for a catalyst, an “imbalance determining parameter” which becomes larger as a degree of an imbalance among “individual cylinder air-fuel ratios” becomes larger, each of the individual cylinder air-fuel ratios being an air-fuel ratio of a mixture supplied to each of cylinders. Further, the determining apparatus determines that an air-fuel ratio imbalance state among cylinders is occurring, when the imbalance determining parameter is larger than a predetermined threshold. The determining apparatus changes the predetermined threshold in accordance with a mechanical compression ratio of the engine.

Abstract: When the intake air amount is smaller than the specific intake air amount, the unit air-fuel ratio change amount calculated during the engine operation is corrected such that the unit air-fuel ratio change amount increases in the condition that the base unit air-fuel ratio change amount is an upper limit and when the intake air amount is greater than the specific intake air amount, the unit air-fuel ratio change amount calculated during the engine operation is corrected such that the unit air-fuel ratio change amount decreases in the condition that the base unit air-fuel ratio change amount is a lower limit. When the corrected unit air-fuel ratio change amount is greater than the judgment value, it is judged that the inter-cylinder air-fuel ratio imbalance condition occurs.

Abstract: An abnormality diagnosis apparatus for an NOx catalyst of the present invention measures an index value (R) regarding an NOx clarification capacity of an NOx catalyst and determines an abnormality of the NOx catalyst based on index values (R1, R2) respectively measured at a timing (Tc1) at which the NOx catalyst has a relatively-low activation level and a timing (Tc2) at which the NOx catalyst has a relatively-high activation level. Since the index value at the timing at which the NOx catalyst has a relatively-low activation level (i.e., a timing at which the NOx catalyst originally does not have a sufficient NOx clarification capacity) is used, the abnormality diagnosis for the NOx catalyst can be carried out without intentionally deteriorating emission.

Abstract: When the NOx SCR catalyst (15) deteriorates, the NOx removal efficiency increases with an increase in the catalyst temperature as indicated by the curves B1 and B2. When there is an irregularity in the amount or quality of aqueous urea solution that is supplied to the NOx SCR catalyst, the NOx removal efficiency decreases at a constant rate as indicated by the curve C. When the NOx removal efficiency is first within the region X2 and then brought into the region Y1, it is determined that the NOx SCR catalyst deteriorates. When the NOx removal efficiency is first within the region X2 and then brought into the region Y2, it is determined that there is an irregularity in the amount or quality of the aqueous urea solution that is supplied to the NOx SCR catalyst.