Patents by Inventor Hiroshi Yoshizawa

Hiroshi Yoshizawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8399127
    Abstract: A nonaqueous electrolyte secondary battery, comprising a positive electrode having a positive-electrode active material layer reversibly inserting and extracting lithium ions on a positive-electrode current collector, a negative electrode having a negative-electrode active material layer reversibly inserting and extracting lithium ions on a negative-electrode current collector, and a nonaqueous electrolyte solution, wherein at least one of the positive and negative electrodes has a film on the surface and at least one of the positive electrode, the negative electrode and the nonaqueous electrolyte solution contains a nitrogen-containing cyclic compound. Such a nonaqueous electrolyte secondary battery is superior in high-temperature storage stability allowing preservation of favorable discharge rate even after high-temperature storage.
    Type: Grant
    Filed: February 20, 2008
    Date of Patent: March 19, 2013
    Assignee: Panasonic Corporation
    Inventors: Masaki Deguchi, Tooru Matsui, Hiroshi Yoshizawa
  • Patent number: 8349287
    Abstract: The present invention relates to a positive electrode active material comprising a lithium-containing composite oxide containing nickel with an oxidation state of 2.0 to 2.5 and manganese with an oxidation state of 3.5 to 4.0, the oxidation state determined by the shifts of energy at which absorption maximum is observed in the X-ray absorption near-K-edge structures, and to a non-aqueous electrolyte secondary battery using the same, the positive electrode active material being characterized in having a high capacity, a long storage life and excellent cycle life.
    Type: Grant
    Filed: May 1, 2007
    Date of Patent: January 8, 2013
    Assignees: Panasonic Corporation, Osaka City University
    Inventors: Tsutomu Ohzuku, Hiroshi Yoshizawa, Masatoshi Nagayama
  • Patent number: 8339435
    Abstract: An optical scanning unit may include a light source unit configured to emit a light beam, an optical housing configured to receive and support the light source unit, an optical device configured to deflect the light beam and to focus the light beam on a light receiving member, and a fixing member configured to fix the light source unit to the optical housing by applying pressure to the light source unit, wherein the pressure is applied in a direction, which is substantially perpendicular to an optical axis direction of the light source unit.
    Type: Grant
    Filed: November 30, 2006
    Date of Patent: December 25, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Takeshi Yamakawa, Hiroshi Yoshizawa, Katsunori Shoji
  • Patent number: 8338612
    Abstract: Because fluazinam is excellent as an active ingredient of pesticides and highly useful, it is desired to produce it efficiently in a proper form with simple operations at low cost in an environmentally friendly manner. The desired product is obtained in good yields with simple operations by using industrially advantageous reaction systems by a process comprising (1) a step of reacting ACTF and DCDNBTF in the presence of an alkali component, a solvent selected from the group consisting of ketones, nitriles, ethers and esters and a sufficient amount of water to substantially dissolve the alkali component, (2) a step of neutralizing or acidifying the reaction mixture with an acid and (3) a step of removing the solvent by distillation from the mixture containing fluazinam as the reaction product and the reaction solvent to precipitate crystals the product.
    Type: Grant
    Filed: July 29, 2008
    Date of Patent: December 25, 2012
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Shigeo Murai, Hiroshi Yoshizawa, Takeshi Ohshima, Katsuyoshi Murakami, Takayoshi Ando, Tadashi Nakamura, Norio Adachi, Akihiko Isogai
  • Patent number: 8318357
    Abstract: Disclosed is a secondary battery with a non-aqueous electrolyte that has excellent cycle characteristics and output characteristics. Also disclosed is a positive electrode active material for a secondary battery with a non-aqueous electrolyte that includes a powder of a volume resistivity of 20 ?·cm or more and 100 ?·cm or less when said powder has a bulk density of 3 g/cm3. The use of the lithium nickel composite oxide as a positive electrode active material can provide a secondary battery with a non-aqueous electrolyte that has excellent cycle characteristics and output characteristics.
    Type: Grant
    Filed: May 13, 2009
    Date of Patent: November 27, 2012
    Assignee: Panasonic Corporation
    Inventors: Junichi Sugaya, Tetsuo Nanno, Hiroshi Yoshizawa
  • Patent number: 8241790
    Abstract: In a non-aqueous electrolyte secondary battery comprising: a negative electrode containing, as a negative electrode active material, at least a material capable of absorbing and desorbing lithium ions or metal lithium; a positive electrode; and an electrolyte, an oxide containing nickel and manganese elements, the material comprising primary particles of the oxide having a twining portion and a superlattice arrangement of a [?{square root over ( )}3×?{square root over ( )}3] R30° when assigned as R3-m is used as a positive electrode active material.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: August 14, 2012
    Assignees: Panasonic Corporation, Osaka City University
    Inventors: Tsutomu Ohzuku, Hiroshi Yoshizawa, Masatoshi Nagayama
  • Patent number: 8221922
    Abstract: A non-aqueous electrolyte secondary battery including: a positive electrode that contains a transition metal oxide capable of absorbing and desorbing lithium ions; a negative electrode that is capable of absorbing and desorbing lithium ions; a porous film that is interposed between the positive electrode and the negative electrode; and a non-aqueous electrolyte, wherein at least one selected from inorganic oxide and polyamide is contained in the porous film, and 5 to 15 vol % of ethylene carbonate is contained in a non-aqueous solvent that is contained in the non-aqueous electrolyte.
    Type: Grant
    Filed: April 10, 2008
    Date of Patent: July 17, 2012
    Assignee: Panasonic Corporation
    Inventors: Masaki Deguchi, Tooru Matsui, Hiroshi Yoshizawa
  • Publication number: 20120156555
    Abstract: The present invention provides a non-aqueous electrolyte secondary battery including: a positive electrode including a first active material capable of occluding and releasing a lithium ion and a second active material capable of occluding and releasing an anion; a negative electrode including a negative electrode active material capable of occluding and releasing a lithium ion; and an electrolyte containing a salt of a lithium ion and the anion. The second active material is a polymer having a tetrachalcogenofulvalene skeleton in a repeating unit. According to the present invention, provided is a non-aqueous electrolyte secondary battery with improved output characteristics, in particular, a pulse discharge characteristic, without a significant decrease in energy density.
    Type: Application
    Filed: June 30, 2011
    Publication date: June 21, 2012
    Inventors: Nobuhiko Hojo, Yu Otsuka, Hiroshi Yoshizawa
  • Patent number: 8187744
    Abstract: A non-aqueous electrolyte secondary battery is produced using a non-aqueous electrolyte including: a non-aqueous solvent that primarily contains a solvent mixture of ethylene carbonate and propylene carbonate and includes a fluorine-substituted ether having a divalent group represented by a formula: —CFX—CH(CH3)—O—, where X is a hydrogen atom or fluorine atom, in a molecule thereof; and a lithium salt that is dissolved in the non-aqueous solvent. The non-aqueous electrolyte has favorable wettability towards a polyolefin separator, and improves the cycle characteristics and the load characteristics of the non-aqueous electrolyte secondary battery.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: May 29, 2012
    Assignee: Panasonic Corporation
    Inventors: Tooru Matsui, Tetsuo Nanno, Hiroshi Yoshizawa
  • Patent number: 8173301
    Abstract: A positive electrode active material for a non-aqueous electrolyte secondary battery including a lithium-containing transition metal oxide having a closest-packed cubic structure of oxygen, the lithium-containing transition metal oxide having a composition represented by the formula (1): Li[Lip(NixMnyCoz)1-p]O2, where x, y, and z represent element contents of nickel, manganese, and cobalt, respectively, and satisfies 0.2+y?x?0.7, 0.15?y, 0.05?z, x+y+z=1, and 0?p?0.1.
    Type: Grant
    Filed: November 5, 2008
    Date of Patent: May 8, 2012
    Assignee: Panasonic Corporation
    Inventors: Hidekazu Hiratsuka, Norihiro Yamamoto, Yutaka Kawatate, Hiroaki Furuta, Kensuke Nakura, Hiroshi Yoshizawa
  • Patent number: 8153297
    Abstract: In a non-aqueous electrolyte secondary battery comprising: a negative electrode containing, as a negative electrode active material, at least a material capable of absorbing and desorbing lithium ions or metal lithium; a positive electrode; and an electrolyte, an oxide containing nickel and manganese elements, the material comprising primary particles of the oxide having a twining portion and a superlattice arrangement of a [?{square root over (3)}×?{square root over (3)}] R30° when assigned as R3-m is used as a positive electrode active material.
    Type: Grant
    Filed: August 3, 2007
    Date of Patent: April 10, 2012
    Assignees: Panasonic Corporation, Osaka City University
    Inventors: Tsutomu Ohzuku, Hiroshi Yoshizawa, Masatoshi Nagayama
  • Patent number: 8148017
    Abstract: An electrochemical energy storage device includes a negative electrode which contains a carbon material and has a negative electrode potential of 1.4 V or less relative to a lithium reference when being charged, and a non-aqueous electrolyte solution prepared by dissolving a lithium salt, an ammonium salt, and at least one kind of fluorinated benzene selected among hexafluorobenzene, pentafluorobenzene, 1,2,3,4-tetrafluorobenzene, 1,2,3,5-tetrafluorobenzene, 1,2,4,5-tetrafluorobenzene and 1,2,3-trifluorobenzene, in a non-aqueous solvent.
    Type: Grant
    Filed: March 1, 2007
    Date of Patent: April 3, 2012
    Assignee: Panasonic Corporation
    Inventors: Tooru Matsui, Masaki Deguchi, Hiroshi Yoshizawa
  • Patent number: 8137847
    Abstract: An active material for a non-aqueous electrolyte secondary battery including a lithium-containing transition metal oxide containing nickel and manganese and having a closest-packed structure of oxygen, wherein an atomic ratio MLi/MT between the number of moles of lithium MLi and the number of moles of transition metal Mt contained in the lithium-containing transition metal oxide is greater than 1.0; the lithium-containing transition metal oxide has a crystal structure attributed to a hexagonal system, and the X-ray diffraction image of the crystal structure has a peak P003 attributed to the (003) plane and a peak P104 attributed to the (104) plane; an integrated intensity ratio I003/I104 between the peak P003 and the peak P104 varies reversibly within a range from 0.7 to 1.5 in association with absorption and desorption of lithium by the lithium-containing transition metal oxide; and the integrated intensity ratio varies linearly and continuously.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: March 20, 2012
    Assignees: Panasonic Corporation, Public University Corporation Osaka City University
    Inventors: Tsutomu Ohzuku, Hiroshi Yoshizawa, Kensuke Nakura
  • Patent number: 8067120
    Abstract: The non-aqueous electrolyte secondary battery of the present invention includes a positive electrode containing a lithium-containing transition metal oxide as a positive electrode active material, a negative electrode, a separator interposed between the positive electrode and the negative electrode and a non-aqueous electrolyte. The non-aqueous electrolyte includes a non-aqueous solvent and a solute dissolved therein, and the non-aqueous solvent includes a solvent having an electron-withdrawing substituent. The solvent having an electron-withdrawing substituent includes at least one selected from the group consisting of a sulfonic solvent, a nitrile solvent, a ketonic solvent, a fluorine-containing solvent, a chlorine-containing solvent and a carboxylic acid ester solvent. The separator includes a material containing an electron-withdrawing substituent or an atom having an unshared electron pair.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: November 29, 2011
    Assignee: Panasonic Corporation
    Inventors: Masaki Deguchi, Tooru Matsui, Hiroshi Yoshizawa
  • Patent number: 8067119
    Abstract: A non-aqueous electrolyte secondary battery of the present invention includes a positive electrode including an active material absorbing and desorbing lithium ions, a negative electrode including an active material absorbing and desorbing lithium ions, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The separator includes a material containing a substituent group with electron-withdrawing property. The non-aqueous electrolyte includes a non-aqueous solvent and a solute dissolved therein, and the non-aqueous solvent includes at least one selected from the group consisting of a fluorine-containing aromatic solvent, a fluorine-containing cyclic carbonic acid ester, and a fluorine-containing cyclic carboxylic acid ester.
    Type: Grant
    Filed: May 18, 2007
    Date of Patent: November 29, 2011
    Assignee: Panasonic Corporation
    Inventors: Masaki Deguchi, Tooru Matsui, Hiroshi Yoshizawa
  • Patent number: 7998615
    Abstract: The present invention relates to a nonaqueous electrolyte for electrochemical devices, and to electric double-layer capacitor and secondary battery using the said nonaqueous electrolyte. The nonaqueous electrolyte according to the present invention comprises a room temperature molten salt and a fluorohydrocarbon. The nonaqueous electrolyte is flame resistant and can suppress the rise in its viscosity. Therefore, high quality electrochemical devices can be obtained by using the nonaqueous electrolyte. The electric double-layer capacitor according to the present invention comprises a pair of polarizable electrode plates, a separator interposed between the pair of electrode plates, and the inventive nonaqueous electrolyte.
    Type: Grant
    Filed: January 12, 2005
    Date of Patent: August 16, 2011
    Assignee: Panasonic Corporation
    Inventors: Tooru Matsui, Masaki Deguchi, Hiroshi Yoshizawa
  • Patent number: 7939200
    Abstract: As an alternative technique to lead-acid batteries, the present invention provides an inexpensive 2 V non-aqueous electrolyte secondary battery having excellent cycle life at a high rate by preventing volume change during charge and discharge. The non-aqueous electrolyte secondary battery uses: a positive electrode active material having a layered structure, being represented by chemical formula Li1±?[Me]O2, where 0??<0.2, and Me is a transition metal including Ni and at least one selected from the group consisting of Mn, Fe, Co, Ti and Cu, and including elemental nickel and elemental cobalt in substantially the same ratio; and a negative electrode active material including Li4Ti5O12(Li[Li1/3Ti5/3]O4).
    Type: Grant
    Filed: May 10, 2006
    Date of Patent: May 10, 2011
    Assignees: Panasonic Corporation, Osaka City University
    Inventors: Tsutomu Ohzuku, Hiroshi Yoshizawa, Kensuke Nakura
  • Patent number: 7935443
    Abstract: A nonaqueous electrolytic secondary cell produced at low cost and having a large capacity comprises a negative electrode having an active material mainly composed of a material that at least absorbs and releases lithium ions or metallic lithium, a positive electrode, and an electrolyte. The active material of the positive electrode is an oxide containing nickel, manganese, and cobalt, and the contents of the elements are substantial the same.
    Type: Grant
    Filed: April 15, 2002
    Date of Patent: May 3, 2011
    Assignee: Panasonic Corporation
    Inventors: Tsutomu Ohzuku, Hiroshi Yoshizawa, Masatoshi Nagayama
  • Patent number: 7919205
    Abstract: A negative electrode for a lithium ion secondary battery of the present invention includes a current collector and an active material layer carried on the current collector. The active material layer contains silicon and oxygen. In the thickness direction of the active material layer, an oxygen ratio of the active material is greater at the side of the active material layer in contact with the current collector than at the side of the active material layer not in contact with the current collector. The active material layer contains no binder. By using the negative electrode described above, it is possible to provide a high capacity lithium ion secondary battery having superior high rate charge/discharge characteristics and excellent cycle characteristics.
    Type: Grant
    Filed: November 4, 2005
    Date of Patent: April 5, 2011
    Assignee: Panasonic Corporation
    Inventors: Yasutaka Kogetsu, Kazuyoshi Honda, Toshitada Sato, Hiroshi Yoshizawa
  • Patent number: 7879489
    Abstract: To provide a high-capacity non-aqueous electrolyte secondary battery that exhibits satisfactory charge/discharge cycle characteristics even in a high temperature environment. The battery has: a positive electrode including a nickel-containing lithium composite oxide; a negative electrode capable of charging and discharging; a separator interposed between the positive and negative electrodes; and a non-aqueous electrolyte containing a non-aqueous solvent and a solute dissolved therein. The non-aqueous electrolyte contains a fluorine atom-containing aromatic compound. The nickel-containing lithium composite oxide is represented by, for example, LiNixM1-x-yLyO2 where element M is at least one selected from the group consisting of Co and Mn; element L is at least one selected from the group consisting of Al, Sr, Y, Zr, Ta, Mg, Ti, Zn, B, Ca, Cr, Si, Ga, Sn, P, V, Sb, Nb, Mo, W and Fe; and x and y satisfy 0.1?x?1 and 0?y?0.1.
    Type: Grant
    Filed: January 9, 2006
    Date of Patent: February 1, 2011
    Assignee: Panasonic Corporation
    Inventors: Masaki Deguchi, Tooru Matsui, Hiroshi Yoshizawa