Patents by Inventor Hirotaka Tomizawa
Hirotaka Tomizawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7517838Abstract: Disclosed herein is a lubricating oil for bearings comprising (a) a diester represented by General Formula (1) wherein R1 and R2 are the same or different, and each represents a C3-C17 linear alkyl group; A represents a C2-C10 linear alkylene group or A represents a branched alkylene group consisting of a linear alkylene group, the linear alkylene group being the principal chain, and one or more alkyl groups (branches) bonded to the linear alkylene group, wherein the total number of carbon atoms of the linear alkylene group and the one or more alkyl groups is 3 to 10; with the proviso that when A is a branched alkylene group and has two or more alkyl groups, the two or more alkyl groups are not bonded to the same carbon atom; or a mixture of the diester with an additional base oil and (b) at least one member selected from the group consisting of phenol-based antioxidants and amine-based antioxidants, and optionally containing (c) at least one member selected from the group consisting of Phosphorus-basedType: GrantFiled: August 22, 2003Date of Patent: April 14, 2009Assignee: New Japan Chemical Co., Ltd.Inventors: Yasuyuki Kawahara, Kouji Takahashi, Hirotaka Tomizawa
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Publication number: 20060019840Abstract: Disclosed herein is a lubricating oil for bearings comprising (a) a diester represented by General Formula (1) wherein R1 and R2 are the same or different, and each represents a C3-C17 linear alkyl group; A represents a C2-C10 linear alkylene group or A represents a branched alkylene group consisting of a linear alkylene group, the linear alkylene group being the principal chain, and one or more alkyl groups (branches) bonded to the linear alkylene group, wherein the total number of carbon atoms of the linear alkylene group and the one or more alkyl groups is 3 to 10; with the proviso that when A is a branched alkylene group and has two or more alkyl groups, the two or more alkyl groups are not bonded to the same carbon atom; or a mixture of the diester with an additional base oil and (b) at least one member selected from the group consisting of phenol-based antioxidants and amine-based antioxidants, and optionally containing (c) at least one member selected from the group consisting of phosphorus-basedType: ApplicationFiled: August 22, 2003Publication date: January 26, 2006Applicant: New Japan Chemical Co., Ltd.Inventors: Yasuyuki Kawahara, Kouji Takahashi, Hirotaka Tomizawa
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Patent number: 6855675Abstract: A lubricating oil composition that has excellent antiwear properties and is especially useful for internal combustion engine comprises a lubricating base oil and contains the following components: sulfoxymolybdenum dithiocarbamate, zinc dialkyldithiophosphate and a mixture of 100 to 50% by weight of calcium alkylsalicylate and 0 to 50% by weight of magnesium alkylsalicylate, the amount of molybdenum derived from the sulfoxymolybdenum dithiocarbamate being from 200 to 1000 ppm (weight basis) of the total weight of the composition, the amount of phosphorus derived from the zinc dialkyldithiophosphate being from 0.04 to 15% by weight of the total weight of the composition, and the total amount of the calcium alkylsalicylate and the magnesium alkylsalicylate being from 1 to 10% by weight of the total weight of the composition.Type: GrantFiled: May 24, 1995Date of Patent: February 15, 2005Assignee: TonenGeneral Sekiyu K.K.Inventors: Michiya Yamada, Satoshi Asano, Hirotaka Tomizawa
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Patent number: 6667285Abstract: The invention provides a lubricating oil for refrigerators, comprising (a) at least one ester represented by the formula (1) wherein R1 is C1 to C18 straight-chain alkyl or C3 to C18 branched-chain alkyl; R2 is H, C1 to C18 straight-chain alkyl or C3 to C18 branched-chain alkyl; with the proviso that the total number of carbons contained in the alkyls represented by R1 and R2 is 2 to 18 and that when R2 is H, R1 is branched-chain alkyl; and R3 is C1 to C20 straight-chain alkyl, C3 to C20 branched-chain alkyl or C3 to C10 cycloalkyl, optionally in combination with (b) at least one member selected from the group consisting of fatty acid polyol esters, phthalic acid esters, alicyclic dicarboxylic acid esters, polyvinyl ethers, hydrocarbon oils and polyalkylene glycols; as well as a method for lubricating a refrigerator using such a lubricating oil, and a working fluid composition for refrigerators comprising (I) component (a) or components (a) and (b) and (II) a refrigerant.Type: GrantFiled: November 8, 2001Date of Patent: December 23, 2003Assignee: New Japan Chemical Co., Ltd.Inventors: Yasuyuki Kawahara, Kouji Takahashi, Hirotaka Tomizawa
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Patent number: 6403541Abstract: Disclosed are a composition for preventing clogging of oil filters for various internal combustion engines, the composition comprising at least one hydroxyl-containing component selected from the group consisting of: compounds represented by the formula (1) R1O—(R2O)m—H (1) wherein R1 is hydrogen or C1 to C8 alkyl, R2 is C2 to C10 alkylene, m is an integer of 1 to 10, and when m is 2 or more, the two or more R2 groups may be the same or different; and compounds represented by the formula (2) wherein R3 is C2 to C4 alkylene, R4 is hydrogen or C1 to C10 alkyl, n is an integer of 0 to 8, and when n is 2 or more, the two or more R3 groups may be the same or different; a method for preventing oil filter clogging using the composition, and an engine oil composition containing the composition.Type: GrantFiled: March 14, 2000Date of Patent: June 11, 2002Assignee: New Japan Chemical Co., Ltd.Inventors: Yoshikuni Kambara, Hirotaka Tomizawa
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Patent number: 5880073Abstract: A lubricating oil composition comprising (A) a base oil containing 3% by weight or less of aromatics, 20% by weight or more of monocyclic naphthenes, 50 ppm by weight or less of N and 50 ppm by weight or less of S, having a viscosity (100.degree. C.) of 2 to 50 mm.sup.2 /s, (B) alkyldiphenylamines and/or phenyl-alpha-naphthylamines in an amount of 0.05 to 2% by weight of the total weight of the composition, and (C) C.sub.8 -C.sub.23 MoDTC and/or C.sub.8 -C.sub.18 MoDTP and/or C.sub.8 -C.sub.18 MoDTX in such an amount that the amount of Mo is 50 to 2000 ppm by weight of the total weight of the composition. The lubricating oil composition has high heat resistance, high oxidation stability and excellent lubricating properties, and is particularly useful for a lubricating oil for internal combustion engines and the like.Type: GrantFiled: February 6, 1998Date of Patent: March 9, 1999Assignee: Tonen CorporationInventors: Hirotaka Tomizawa, Arai Katsuya
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Patent number: 5719109Abstract: The present invention provides a lubricating oil composition excellent in wear-resistant properties and frictional characteristics. The present invention relates to a lubricating oil composition containing a lubricating base oil(A) a complex obtained by reacting a metallic salt of dithiophosphoric acid having lipophilic groups, the average number of the carbon atoms of which is 4 or more, with a primary alkylamine having 8 or less carbon atoms, and(B) at least one kind of compound selected from the group consisting of oxymolybdenum sulfide dithiocarbamate, oxymolybdenum sulfide organophosphorodithioate, fatty esters, and organic amides.Type: GrantFiled: November 12, 1996Date of Patent: February 17, 1998Assignee: Exxon Chemical Patents IncInventors: Michide Tokashiki, Hirotaka Tomizawa, Michiya Yamada
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Patent number: 5696063Abstract: The present invention provides novel basic metallic salts of dithiocarbamic acid, in which the content of the basic ingredient (=a.times.3.times.100) is 30-100 mol %, represented by general formula (1): ##STR1## wherein R.sup.1 to R.sup.4, which may be the same or different, are each a lipophilic group having 1-30 carbon atoms, M is a metal atom selected from the group consisting of zinc, copper, nickel, iron, cadmium, silver, lead, antimony, tin, and bismuth, and "a" is a coefficient of 1/3 to 1/10,said basic metallic salts of dithiocarbamic acid containing no phosphorus atoms and imparting low-wear properties when used as an additive for lubricating oils. The present invention also provides lubricating oil compositions containing in a lubricating base oil said basic metal salt of dithiocarbamic acid, which compositions are excellent in wear-resistant properties and frictional characteristics and suitable as a lubricating oil for automotive internal combustion engines.Type: GrantFiled: September 11, 1996Date of Patent: December 9, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Michihide Tokashiki, Hirotaka Tomizawa, Katsuya Arai
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Patent number: 5688748Abstract: Providing a lubricating oil composition for internal combustion engines which has high resistance to oxidation by nitrogen oxides, excellent friction characteristics that is maintained for a prolonged period, and reduces the fuel consumption for a prolonged period. A lubricating oil composition for internal combustion engines is provided consisting of a base oil principally consisting of a hydrocarbon oil which has a dynamic viscosity of 2-20 mm.sup.2 /s at 100.degree. C. and contains 3 wt % or less aromatic components in total, 45 wt% or more one- and two-ring naphthenes in total, 50 wt ppm or less sulfur and 50 wt ppm or less nitrogen, to which are added, with respect to the total weight of the composition, 0.02-0.2 wt % as molybdenum of molybdenum dithiocarbamate, 0.02-0.15 wt % as phosphorus of zinc dithiophosphate, and 0.05-3 wt % of phenol-based antioxidant.Type: GrantFiled: January 26, 1996Date of Patent: November 18, 1997Assignee: Tonen CorporationInventor: Hirotaka Tomizawa
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Patent number: 5605880Abstract: A lubricating oil composition is provided which is obtained by containing in (A) a base oil in which the content of the aromatic ingredients is 3.0% by weight or less, N is 50 ppm by weight or less, S is 50 ppm by weight, and the viscosity is 2.0-50.0 mm.sup.2 /s, based on the total weight of the composition, (B) 0.05-2.0% by weight of alkyldiphenylamine(s) and/or phenyl-.alpha.-naphthylamine(s) and (C) MoDTC of C.sub.8-23 and/or C.sub.3-18 in an amount of 50-2,000 ppm by weight in terms of the amount of molybdenum. Such a lubricating oil composition has high heat-resistant properties, a high stability to oxidation, and improved friction characteristics, and is suitably used especially as a lubricating oil for internal combustion engines.Type: GrantFiled: February 9, 1996Date of Patent: February 25, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Katsuya Arai, Hirotaka Tomizawa
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Patent number: 5603861Abstract: An electroviscous fluid wherein an electrically insulating fluid is mixed with silica fine particles having esterified surfaces, and a polyhydric alcohol. Thus, it is possible to provide an electroviscous fluid which is excellent in dispersion stability and shelf stability, free from aggregation of particles even under heating conditions and capable of manifesting high electroviscous effect.Type: GrantFiled: May 26, 1995Date of Patent: February 18, 1997Assignee: Tonen CorporationInventors: Nobuharu Umamori, Tetsuo Miyamoto, Makoto Kanbara, Hirotaka Tomizawa
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Patent number: 5387370Abstract: Electroviscous fluid according to the present invention is used for vibration control machines and devices such as variable damper, engine mount, bearing damper, clutch, valve, shock absorber, precision machine, accoustic machine, etc. and for display element. It has high electroviscous effect and wider application temperature range, and the electroviscous effect is stable.Type: GrantFiled: March 24, 1993Date of Patent: February 7, 1995Assignee: Tonen CorporationInventors: Hirotaka Tomizawa, Makoto Kanbara, Tetsuo Miyamoto
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Patent number: 5364545Abstract: An improved lubricating oil composition having a low coefficient of friction and reduced copper corrosion comprising (a) a lubricating oil basestock, (b) from 0.01 to 10% by weight, based on the oil composition, of at least one organomolybdenum compound selected from the group consisting of oxymolybdenum monoglyceride and oxymolybdenum diethylatoamide; and (c) from 0.5 to 7% by weight, based on the oil composition, of at least one organozinc compound selected from the group consisting of zinc dithiophosphate and zinc dithiocarbamate.Type: GrantFiled: July 9, 1993Date of Patent: November 15, 1994Assignee: Tonen CorporationInventors: Katsuya Arai, Toshikazu Tsukada, Hirotaka Tomizawa
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Patent number: 5356547Abstract: An improved lubricating oil composition having a low coefficient of friction and reduced copper corrosion comprising (a) lubricating oil basestock, (b) 0.01 to less than 0.2% by weight, based on the oil composition, of at least one organomolybdenum compound selected from the group consisting of sulfurized oxymolybdenum dithiocarbamate and sulfurized oxymolybdenum organophosphorodithioate; and (c) from 0.5 to 7% by weight, based on the oil composition, of at least one organozinc compound selected from the group consisting of zinc dithiophosphate and zinc dithiocarbamate.Type: GrantFiled: July 9, 1993Date of Patent: October 18, 1994Assignee: Exxon Research & Engineering Co.Inventors: Katsuya Arai, Toshikazu Tsukada, Hirotaka Tomizawa
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Patent number: 5344582Abstract: A traction fluid lubricant is disclosed which contains a naphthenic ingredient having a weight average molecular weight of 200-300 and obtained by hydrogenating oligomers of cyclopentadiene having a ratio of the number of norbornenic double bond to that of cyclopentenic double bond of smaller than 0.9 but not smaller than 0.1. The naphthenic ingredient is suitably used in conjunction with an auxiliary ingredient selected from a polybutene having a viscosity of 5-60 cSt at 40.degree. C. and a bicyclohexyl compound.Type: GrantFiled: July 29, 1992Date of Patent: September 6, 1994Assignee: Tonen CorporationInventors: Noboru Umemoto, Takeshi Nomura, Toshiaki Kuribayashi, Takehisa Sato, Hirotaka Tomizawa
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Patent number: 5334320Abstract: A composition for hydraulic, lubricating and coupling is disclosed herein, which comprises organopolysiloxane and as an anti-wear agent at least one compound selected from those of the general formulas (I) to (IV), or an anti-wear agent of at least one compound selected from those of the general formulas (I) to (IV) together with a storage stabilizer. A composition for hydraulic, lubricating and coupling is also disclosed herein, which comprises organopolysiloxane together with a combination of two or more compounds selected from those of the general formulas (V) and (VI) as an anti-wear agent, or a combination of at least one compound selected from those of the general formulas (V) and (VI) as an anti-wear agent and a storage stabilizer. If necessary, the composition according to the present invention further comprises an antioxidant. The composition according to the present invention can be used at high temperature for a long period, without showing a significant increase in viscosity.Type: GrantFiled: January 13, 1993Date of Patent: August 2, 1994Assignee: Tonen CorporationInventors: Hirotaka Tomizawa, Noboru Umemoto, Hitoshi Ohenoki
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Patent number: 5334319Abstract: A composition for hydraulic, lubricating and coupling is disclosed herein, which comprises organopolysiloxane and at least one additive selected from the group consisting of an anti-wear agent which is phosphorus type or sulfur type, a metal deactivator and a corrosion inhibitor. The composition according to the present invention further comprises an antioxidant. The composition according to the present invention can be used at high temperature for a long period, without showing a significant increase in viscosity.Type: GrantFiled: December 1, 1992Date of Patent: August 2, 1994Assignee: Tonen CorporationInventors: Hirotaka Tomizawa, Noboru Umemoto, Hitoshi Ohenoki
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Patent number: 5332515Abstract: In the fluid for viscous coupling according to the present invention, organopolysiloxane is used as base oil, and by adding phosphorus type anti-wear agent or by adding the combination of said phosphorus type anti-wear agent with antioxidant or by adding the combination of phosphorus type anti-wear agent with sulfur type anti-wear agent and/or zinc dithiophosphate type anti-wear agent or further by adding antioxidant, it is possible to increase heat-resistant property without changing the viscosity when viscous coupling is in operation and to provide the fluid for viscous coupling with few wear fragment iron quantity and with high durability.Type: GrantFiled: December 4, 1992Date of Patent: July 26, 1994Assignee: Tonen CorporationInventors: Hirotaka Tomizawa, Noboru Umemoto, Hitoshi Ohenoki
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Patent number: 5288535Abstract: An electrode for applying voltage to electroviscous fluid, particularly where the electroviscous fluid has electrically insulating fluid and porous solid particles, the ER effect can be stably maintained up to a high temperature range and high durability can be obtained by laminating an insulating layer on the surface of the electrode in contact with the electroviscous fluid.Type: GrantFiled: November 25, 1992Date of Patent: February 22, 1994Assignee: Tonen CorporationInventors: Makoto Kanbara, Masahiko Hayafune, Hirotaka Tomizawa, Katsuya Arai
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Patent number: 5266229Abstract: An electro-rheological fluid comprising an electrically insulating liquid as the dispersion medium, porous solid particles as the dispersed phase, a dispersant, and a polyhydric alcohol having a boiling point of not lower than 250.degree. C., a melting point of not higher than 15.degree. C. and a viscosity of not higher than 300 cp (as measured at 20.degree. C.), or comprising an electrically insulating liquid as the dispersion medium, porous solid particles as the dispersed phase, a polyhydric alcohol and/or water, and an ashless dispersant.Type: GrantFiled: June 14, 1991Date of Patent: November 30, 1993Assignee: Tonen CorporationInventors: Hirotaka Tomizawa, Makoto Kanbara, Narihiko Yoshimura, Junichi Mitsui, Hiroshi Hirano