Abstract: Provided are a fluorine-free soil resistant agent and a soil resistant treatment method which give excellent water-repellency and excellent antifouling property to a substrate, especially a carpet. The soil resistant agent contains (1) a fluorine-free copolymer having (a) a repeating unit formed from an acrylic monomer having a hydrocarbon group containing 7 to 40 carbon atoms, and (b) a repeating unit formed from an acrylic monomer having a hydrophilic group, and (2) water or a mixture of water and an organic solvent dispersing the fluorine-free copolymer (1). A method of treating the substrate, includes applying the soil resistant agent to the substrate.

Abstract: An oil-resistant agent for paper, which contains a non-fluorine copolymer that has a repeating unit formed from (a) an acrylic monomer having a long-chain hydrocarbon group with 7-40 carbon atoms and a repeating unit formed from (b) an acrylic monomer having a hydrophilic group. The oil-resistant agent for paper also contains a liquid medium that is composed of water and/or an organic solvent, preferably of water or a mixture (aqueous medium) of water and an organic solvent. The non-fluorine copolymer preferably has a repeating unit formed from (c) a monomer having an ion donor group in addition to the repeating units formed from the monomers (a) and (b). Also disclosed is an oil-resistant paper having an oil-resistant layer including the oil-resistant agent for paper, and starch or modified starch, on a surface of the paper as well as a method of treating paper.

Abstract: An oil-resistant agent and an oil-resistant composition, which are capable of imparting excellent oil-resistance to paper. The oil-resistant composition contains a polysaccharide (1) and an oil-resistant polymer (2). The polysaccharide (1) is preferably starch. The oil-resistant polymer (2) preferably has (a) a repeating unit formed from an acrylic monomer that has a long-chain hydrocarbon group having 7-40 carbon atoms, and (b) a repeating unit formed from an acrylic monomer that has a hydrophilic group. A polyvinyl alcohol or glucose may be present as an additive.

Abstract: A non-fluorinated copolymer composition containing (1) a fluorine-free copolymer and (2) acetylene alcohol. The non-fluorinated copolymer (1) has a repeating unit formed from (a) an acrylic monomer having a long-chain hydrocarbon group having 7 to 40 carbon atoms; and a repeating unit formed from (c) an acrylic monomer having an olefinic carbon-carbon double bond and an ion donating group. Also disclosed is an oil-resistant agent containing a fluorine-free composition including (1) a fluorine-free copolymer, and (2) an acetylene alcohol, wherein the fluorine-free copolymer (1) has a repeating unit formed from (a) an acrylic monomer having a long-chain hydrocarbon group having 7 to 40 carbon atoms; an oil-resistant agent kit; a method for producing the fluorine-free copolymer; an oil-resistant paper; and a method for eliminating foam during treatment of paper with the fluorine-free copolymer composition.

Abstract: A composition including at least one compound having a perfluoropolyether group and a curable site, wherein in a molecular weight distribution curve in gel permeation chromatography measurement, the following formula is satisfied: M2/M1?3.5, wherein M1 is a molecular weight at a main peak, and M2 is a molecular weight at 25% intensity of an intensity of the main peak on a higher molecular weight side than M1. Also disclosed is a curable composition containing the composition and a method for producing the curable composition.

Abstract: A paper oil-resistant agent which is added to the interior of paper and includes (1) a non-fluorine polymer and (2) at least one type of particles selected from inorganic particles or organic particles, the amount of the particles (2) being 1-99.9 wt % of the total weight of the non-fluorine polymer (1) and the particles (2). Also disclosed is an oil-resistant paper including the paper oil-resistant agent and a method for producing the oil-resistant paper.

Abstract: A composition including at least one compound having a perfluoropolyether group and a curable site, wherein in a molecular weight distribution curve in gel permeation chromatography measurement, the following formula is satisfied: M2/M1?3.5, wherein M1 is a molecular weight at a main peak, and M2 is a molecular weight at 25% intensity of an intensity of the main peak on a higher molecular weight side than M1. Also disclosed is a curable composition containing the composition and a method for producing the curable composition.

Abstract: An oil-resistant agent for paper, which contains a non-fluorine copolymer that has a repeating unit formed from (a) an acrylic monomer having a long-chain hydrocarbon group with 7-40 carbon atoms and a repeating unit formed from (b) an acrylic monomer having a hydrophilic group. The oil-resistant agent for paper also contains a liquid medium that is composed of water and/or an organic solvent, preferably of water or a mixture (aqueous medium) of water and an organic solvent. The non-fluorine copolymer preferably has a repeating unit formed from (c) a monomer having an ion donor group in addition to the repeating units formed from the monomers (a) and (b). Also disclosed is an oil-resistant paper having an oil-resistant layer including the oil-resistant agent for paper, and starch or modified starch, on a surface of the paper as well as a method of treating paper.

Abstract: Provided are a fluorine-free soil resistant agent and a soil resistant treatment method which give excellent water-repellency and excellent antifouling property to a substrate, especially a carpet. The soil resistant agent contains (1) a fluorine-free copolymer having (a) a repeating unit formed from an acrylic monomer having a hydrocarbon group containing 7 to 40 carbon atoms, and (b) a repeating unit formed from an acrylic monomer having a hydrophilic group, and (2) water or a mixture of water and an organic solvent dispersing the fluorine-free copolymer (1). A method of treating the substrate, includes applying the soil resistant agent to the substrate.

Abstract: An aqueous emulsion composition comprising (A) an aqueous resin emulsion comprising a fluorine-containing polymer and (B) a surfactant of the formula: R1O—(CH2CH2O)p—(R2O)q—R3??(1) wherein R1 is an alkyl group or an alkenyl group, R2 is an alkylene group, R3 is a hydrogen atom, an alkyl group or an alkenyl group, p is the number of at least 2, q is the number of at least 1, and p and q are such numbers that the weight ratio of the polyoxyethylene block is from 5 to 80% by weight based on whole molecule, is excellent in stability against impurity and mechanical stability.

Abstract: A fluorine-containing allyl ether polymer having a number average molecular weight of 1,000 to 1,000,000 and consisting of chains of at least one repeating unit of the formula: wherein A is an organic group having 1 to 100 carbon atoms.

Abstract: An aqueous emulsion composition comprising (A) an aqueous resin emulsion comprising a fluorine-containing polymer and (B) a surfactant of the formula: R1O—(CH2CH2O)p—(R2O)q—R3 ??(1) wherein R1 is an alkyl group or an alkenyl group, R2 is an alkylene group, R3 is a hydrogen atom, an alkyl group or an alkenyl group, p is the number of at least 2, q is the number of at least 1, and p and q are such numbers that the weight ratio of the polyoxyethylene block is from 5 to 80% by weight based on whole molecule, is excellent in stability against impurity and mechanical stability.

Abstract: A fluorine-containing allyl ether polymer having a number average molecular weight of 1,000 to 1,000,000 and consisting of chains of at least one repeating unit of the formula: wherein A is an organic group having 1 to 100 carbon atoms.

Abstract: A fluorine-containing allyl ether polymer having a number average molecular weight of 1,000 to 1,000,000 and consisting of chains of at least one repeating unit of the formula: wherein A is an organic group having 1 to 100 carbon atoms.

Abstract: A water- and oil-repellent containing a copolymer of (a) a fluoroalkyl group-containing monomer having a melting point of 60 to 80° C. in the state of a homopolymer, and (b) a hydrophilic group-containing monomer is extremely superior in soil releasability.

Abstract: A mold releasing agent comprising a silicon-containing compound represented by the formula:R.sup.1.sub.n SiR.sup.2.sub.4-nwherein R.sup.1 is ##STR1## (R.sup.3 and R.sup.4 are a hydrocarbon group having 1 to 4 carbon atoms), R.sup.2 is a hydrocarbon group having 1 to 4 carbon atoms or a halogenated hydrocarbon group having 1 to 4 carbon atoms, n is 3 or 4, and a silicon- and/or fluorine-containing compound having at least two hydroxyl groups or alkoxyl groups in one molecule. The mold releasing agent of the present invention is excellent in mold releasing property, has a long life, provides a good surface finishing of molded article, and has no influence on secondary processability.

Abstract: A mold release agent containing (A) a silane compound, (B) a silicon and/or fluorine-containing compound having at least two hydroxyl groups or alkoxy groups in one molecule and (C) a polymer of a perfluoroalkyl group-containing (meth)acrylate ester gives a long mold release life and a good surface finishing property of a molded article, and does not exert a harmful influence on fabricability such as painting and adhesion of the molded article.

Abstract: A novel fluorosilicone compound having at least two hydroxyl groups in its molecule and a curable composition containing such a compound and a commercially available general purpose curing agent; the compound is used suitably for a lubricant and a fiber treating agent, and the curable composition is used suitably for a mold releasing agent, a water- and oil-repelling agent, a stain-proof coating agent, a non-tackifying coating agent, a coating agent for optical use and a sealant.