Patents by Inventor Hiroyuki Suematsu

Hiroyuki Suematsu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6002895
    Abstract: A toner is comprised of a composition containing at least a polymer component and a charge control agent. The polymer component contains substantially no tetrahydrofuran (THF)-insoluble matter. The polymer component THF-soluble has a major peak and a minor peak in the specific molecular weight regions in gel permeation chromatography (GPC). The low molecular weight component and high molecular weight component of the polymer component, each of which shows the specific molecular weight region in GPC, have the specific acid values, respectively. The difference between the acid values is in the specific range.
    Type: Grant
    Filed: July 15, 1997
    Date of Patent: December 14, 1999
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashige Kasuya, Hiroyuki Suematsu, Koichi Tomiyama, Hiroshi Yusa, Takakuni Kobori, Masaichiro Katada
  • Patent number: 5942366
    Abstract: An electrophotographic toner composition suitable for heat-fixation and showing good storage characteristics is constituted by polymer components, a colorant and a metal-containing organic compound. The toner composition shows a melt index (at 125.degree. C., 10 kg-load) of 5-25 g/10 min., and the polymer components are characterized by (a) containing substantially no THF (tetrahydrofuran)-insoluble content, (b) including a THF-soluble content thereof providing a GPC (gel permeation chromatography) chromatogram showing i) a main peak in a molecular weight region of 2.times.10.sup.3 -3.times.10.sup.4, and a sub-peak or shoulder in a molecular weight region of at least 10.sup.5, and ii) an areal percentage of 3-10% in a molecular weight region of at least 10.sup.6, and (c) including a polymer component (H) in a molecular weight region of at least 10.sup.5 obtained by polymerization using a polyfunctional polymerization initiator and a mono-functional polymerization initiator.
    Type: Grant
    Filed: February 12, 1998
    Date of Patent: August 24, 1999
    Assignee: Canon Kabushiki Kaisha
    Inventors: Manabu Ohno, Hiroyuki Suematsu, Akihiko Nakazawa, Nobuyuki Okubo, Shunji Suzuki
  • Patent number: 5854365
    Abstract: The present invention relates a toner for developing electrostatic images, comprising: a resin composition, which contains a binder resin and low molecular weight wax, and a coloring agent, wherein the binder resin does not substantially contain insoluble tetrahydrofuran (THF) component, its chromatograph measured with soluble tetrahydrofuran (THF) component has a main peak in a region of a molecular weight of 2,000 to 30,000 and a subpeak or a shoulder in a high molecular weight region of a molecular weight of 100,000 or more, a ratio of weight average molecular weight (Mw)/number average molecular weight (Mn) thereof is 30 or more, the high molecular weight region has a crosslinking monomer unit as a component monomer unit and the binder resin contains high molecular weight polymer having a Mw of 1,200,000 or more polymerized by using both polyfunctional initiator and a mono-functional initiator. Moreover, the present invention relates to a method of manufacturing a resin composition for producing a toner.
    Type: Grant
    Filed: December 19, 1995
    Date of Patent: December 29, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventors: Manabu Ohno, Akihiko Nakazawa, Nobuyuki Okubo, Shunji Suzuki, Hiroyuki Suematsu, Masayoshi Kato
  • Patent number: 5802428
    Abstract: An image forming apparatus includes a member to be charged for carrying an electrostatic latent image; a contact charging means for contact charging the member to be charged and a developing means for developing the latent image. The developing means includes a developer having a magnetic toner and fine powder treated with a silicone oil or varnish-treating agent, wherein the magnetic toner particles include a binder resin and contain from 10-70 wt. % of magnetic fine powder. An image forming method includes the steps of contact charging, latent image forming and developing with a developer having the binder resin, 10 to 70 wt. % magnetic fine powder and fine powder treated with a silicone oil or varnish-treating agent.
    Type: Grant
    Filed: April 18, 1995
    Date of Patent: September 1, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventors: Manabu Ohno, Hisayuki Ochi, Tetsuhito Kuwashima, Hiroyuki Suematsu, Eiichi Imai, Tsuyoshi Takiguchi, Koichi Tomiyama, Tsutomu Kukimoto, Hiroshi Yusa
  • Patent number: 5744276
    Abstract: An electrophotographic toner composition suitable for heat-fixation and showing good storage characteristics is constituted by polymer components, a colorant and a metal-containing organic compound. The toner composition shows a melt index (at 125.degree. C., 10 kg-load) of 5-25 g/10 min., and the polymer components are characterized by (a) containing substantially no THF (tetrahydrofuran)-insoluble content, (b) including a THF-soluble content thereof providing a GPC (gel permeation chromatography) chromatogram showing i) a main peak in a molecular weight region of 2.times.10.sup.3 -3.times.10.sup.4, and a sub-peak or shoulder in a molecular weight region of at least 10.sup.5, and ii) an areal percentage of 3-10% in a molecular weight region of at least 10.sup.6, and (c) including a polymer component (H) in a molecular weight region of at least 10.sup.5 obtained by polymerization using a polyfunctional polymerization initiator and a monofunctional polymerization initiator.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: April 28, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventors: Manabu Ohno, Hiroyuki Suematsu, Akihiko Nakazawa, Nobuyuki Okubo, Shunji Suzuki
  • Patent number: 5736288
    Abstract: A toner is comprised of a composition containing at least a polymer component and a charge control agent. The polymer component contains substantially no tetrahydrofuran (THF)-insoluble matter. The polymer component THF-soluble has a major peak and a minor peak in the specific molecular weight regions in gel permeation chromatography (GPC). The low molecular weight component and high molecular weight component of the polymer component, each of which shows the specific molecular weight region in GPC, have the specific acid values, respectively. The difference between the acid values is in the specific range.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: April 7, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashige Kasuya, Hiroyuki Suematsu, Koichi Tomiyama, Hiroshi Yusa, Takakuni Kobori, Masaichiro Katada
  • Patent number: 5663026
    Abstract: A magnetic toner is formed from a binder resin and silicon-containing magnetic iron oxide particles. The magnetic toner has a weight-average particle size of at most 13.5 .mu.m, and the magnetic toner has a particle size distribution such that magnetic toner particles having a particle size of at least 12.7 .mu.m are contained in an amount of at most 50 wt. %. The magnetic iron oxide particles have a silicon content of 0.4-2.0 wt. % based on iron, and the magnetic iron oxide particles have an Fe/Si atomic ratio of 1.2-4.0 at the utmost surfaces thereof. Because of the use of such magnetic iron oxide particles having a specifically controlled overall and surface Si contents, the magnetic toner can show stable performances even after standing in a high humidity environment.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: September 2, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashige Kasuya, Hiroyuki Suematsu, Koichi Tomiyama, Hiroshi Yusa, Takakuni Kobori, Masaichiro Katada
  • Patent number: 5534981
    Abstract: An image forming apparatus includes a member to be charged for carrying an electrostatic image, a contact-charging means for charging the member to be charged in contact with the member to be charged, and a developing means for developing the electrostatic image carried on the member to be charged. The developing means includes a developer for developing the electrostatic image comprising a toner and hydrophobic inorganic fine powder. The hydrophobic fine powder has a hydrophobicity of 60% or higher and the toner has a volume average particle size of 4-8 microns. The hydrophobic inorganic fine powder not only improves the fluidity of the developer and adjusts the chargeability of the developer but also prevents difficulties due to interaction between the member to be charged and the contact charging means in the presence of residual developer, such as damages of the member to be charged and toner-sticking onto the member to be charged.
    Type: Grant
    Filed: August 19, 1993
    Date of Patent: July 9, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Manabu Ohno, Hisayuki Ochi, Tetsuhito Kuwashima, Hiroyuki Suematsu, Eiichi Imai, Tsuyoshi Takiguchi, Koichi Tomiyama, Tsutomu Kukimoto, Hiroshi Yusa
  • Patent number: 5510223
    Abstract: An image forming method, including the steps of: developing an electrostatic image formed on an electrostatic image-bearing member with a developer to form thereon thereon a developed image, the developer containing 100 wt. parts of a toner and 0.05 to 3 wt. parts of fine powder treated with a silicone oil or silicone varnish; and transferring the developed image on the electrostatic image-bearing member to a transfer material while causing a transfer device, such as a roller or belt to contact the electrostatic image-bearing member by the medium of the transfer material under a line pressure of 3 g/cm or higher.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: April 23, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tsutomu Kukimoto, Hiroshi Yusa, Koichi Tomiyama, Tsuyoshi Takiguchi, Eiichi Imai, Tetsuya Kuribayashi, Hisayuki Ochi, Hiroyuki Suematsu
  • Patent number: 5489498
    Abstract: The present invention relates a toner for developing electrostatic images, comprising: a resin composition, which contains a binder resin and low molecular weight wax, and a coloring agent, wherein the binder resin does not substantially contain insoluble tetrahydrofuran (THF) component, its chromatograph measured with soluble tetrahydrofuran (THF) component has a main peak in a region of a molecular weight of 2,000 to 30,000 and a subpeak or a shoulder in a high molecular weight region of a molecular weight of 100,000 or more, a ratio of weight average molecular weight (Mw)/number average molecular weight (Mn) thereof is 30 or more, the high molecular weight region has a crosslinking monomer unit as a component monomer unit and the binder resin contains high molecular weight polymer having a Mw of 1,200,000 or more polymerized by using both polyfunctional initiator and a mono-functional initiator. Moreover, the present invention relates to a method of manufacturing a resin composition for producing a toner.
    Type: Grant
    Filed: January 18, 1994
    Date of Patent: February 6, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Manabu Ohno, Akihiko Nakazawa, Nobuyuki Okubo, Shunji Suzuki, Hiroyuki Suematsu, Masayoshi Kato
  • Patent number: 5470686
    Abstract: An image forming apparatus is constituted by an image-bearing member for bearing a latent image, and a developing apparatus for developing the latent image. The developing apparatus is constituted by a developer container for containing a developer, a developer-carrying member for carrying and conveying the developer contained in the developer container to a developing zone opposite the image-bearing member, and an elastic blade for regulating the developer carried and conveyed on the developer-carrying member to a prescribed thickness to form a thin developer layer on the developer-carrying member. A developer suitable for use in the above developing apparatus is given by a toner, which comprises a binder resin composition which contains 10-70 wt. % of a THF (tetrahydrofuran)-insoluble content and the remainder of a THF-soluble content including a component with a molecular weight of 10000 or below on a GPC (gel permeation chromatography) chromatogram of the THF-soluble content constituting 10-50 wt.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: November 28, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroyuki Suematsu, Hisayuki Ochi, Manabu Ohno, Tetsuhito Kuwashima
  • Patent number: 5424810
    Abstract: A magnetic toner for electrophotography is composed from a binder resin and a silicon-containing magnetic iron oxide. The magnetic toner has a weigh-average particle size o at most 13.5 .mu.m and has a particle size distribution such that it contains o more than 50 wt, % of magnetic toner particles having a particle size of at least 12.7 .mu.m. The magnetic toner is able to show high developing performances because of richness in fine particles and is also provided with an improved environmental stability because the magnetic iron oxide used therein contains 0.5-4 wt, % silicon (based on total iron content) and has a specific silicon distribution such that the magnetic iron oxide has a total silicon content (A), a silicon content (B) dissolved together with the magnetic iron oxide when the magnetic iron oxide is dissolved up to 20 wt, % dissolution of iron, and a superficial silicon content (C), satisfying relations of B/A=44-84% and C/A=10-55%.
    Type: Grant
    Filed: September 10, 1992
    Date of Patent: June 13, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koichi Tomiyama, Hiroyuki Suematsu, Masayoshi Kato, Hiroshi Yusa, Takakuni Kobori
  • Patent number: 5392103
    Abstract: An image forming method, including the steps of: developing an electrostatic image formed on an electrostatic image-bearing member with a developer to form thereon thereon a developed image, the developer containing 100 wt. parts of a toner and 0.05 to 3 wt. parts of fine powder treated with a silicone oil or silicone varnish; and transferring the developed image on the electrostatic image-bearing member to a transfer material while causing a transfer device, such as a roller or belt to contact the electrostatic image-bearing member by the medium of the transfer material under a line pressure of 3 g/cm or higher.
    Type: Grant
    Filed: November 4, 1993
    Date of Patent: February 21, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tsutomu Kukimoto, Hiroshi Yusa, Koichi Tomiyama, Tsuyoshi Takiguchi, Eiichi Imai, Tetsuya Kuribayashi, Hisayuki Ochi, Hiroyuki Suematsu
  • Patent number: 5333059
    Abstract: The present invention provide a toner for developing an electrostatic image. The toner comprises a binder resin and a coloring agent. The binder resin comprises a styrene type binder resin. The amount of an aldehyde contained in the binder resin is not more than 0.005% by weight based on the weight of the toner. The binder resin is produced by a process comprising the steps of preparing a monomer composition comprising a polymerizable monomer containing at least not less than 50% by weight of a styrene monomer, and a polymerization initiator, and subjecting said monomer composition to suspension polymerization in an aqueous medium having dissolved oxygen in an amount of not more than 2.5 mg/lit to form a styrene polymer or copolymer containing an aldehyde monomer in an amount of not more than 0.01% by weight.
    Type: Grant
    Filed: March 25, 1992
    Date of Patent: July 26, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshihiko Hyosu, Seiichi Takagi, Hiroyuki Suematsu, Manabu Ohno, Tetsuhito Kuwashima, Eiichi Imai, Yoshinobu Nagai
  • Patent number: 5307122
    Abstract: An image forming apparatus includes a member to be charged for carrying an electrostatic image, a contact-charging means for charging the member to be charged in contact with the member to be charged, and a developing means for developing the electrostatic image carried on the member to be charged. The developing means includes a developer for developing the electrostatic image comprising a toner and hydrophobic inorganic fine powder. The hydrophobic inorganic fine powder not only improves the fluidity of the developer and adjusts the chargeability of the developer but also prevents difficulties due to interaction between the member to be charged and the contact charging means in the presence of residual developer, such as damages of the member to be charged and toner-sticking onto the member to be charged.
    Type: Grant
    Filed: July 26, 1990
    Date of Patent: April 26, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Manabu Ohno, Hisayuki Ochi, Tetsuhito Kuwashima, Hiroyuki Suematsu, Eiichi Imai, Tsuyoshi Takiguchi, Koichi Tomiyama, Tsutomu Kukimoto, Hiroshi Yusa
  • Patent number: 5270770
    Abstract: An image forming method, including the steps of: developing an electrostatic image formed on an electrostatic image-bearing member with a developer to form thereon thereon a developed image, the developer containing 100 wt. parts of a toner and 0.05 to 3 wt. parts of fine powder treated with a silicone oil or silicone varnish; and transferring the developed image on the electrostatic image-bearing member to a transfer material while causing a transfer device, such as a roller or belt, to contact the electrostatic image-bearing member by the medium of the transfer material under a line pressure of 3 g/cm or higher.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: December 14, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tsutomu Kukimoto, Hiroshi Yusa, Koichi Tomiyama, Tsuyoshi Takuguchi, Eiichi Imai, Tetsuya Kuribayashi, Hisayuki Ochi, Hiroyuki Suematsu
  • Patent number: 5164780
    Abstract: An image forming apparatus comprising an electrostatic latent image bearing member and a developing apparatus for developing an electrostatic latent image. The developing apparatus comprises a developer container in which a developer is held, and a developer-carrying member for carrying thereon the developer and transporting the developer to a developing zone. The developer-carrying member has a surface layer of a resin containing at least conductive fine particles and a solid lubricant, and the surface layer has in its relative load curve (Abbot's load curve) a cutting depth C.sub.v of not more than 5 .mu.m when a relative load length t.sub.p is 5%; and the developer contains a toner and a fine powder pretreated with a silicone oil or silicone varnish.
    Type: Grant
    Filed: June 14, 1991
    Date of Patent: November 17, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Manabu Ohno, Yukari Ishibashi, Tetsuhito Kuwashima, Hiroyuki Suematsu
  • Patent number: 5153377
    Abstract: An image forming apparatus is constituted by an image-bearing member for bearing a latent image, and a developing apparatus for developing the latent image. The developing apparatus is constituted by a developer container for containing a toner, and a developer-carrying member for carrying and conveying the toner contained in the developer container to a developing zone opposite the image-bearing member. The developer-carrying member is provided with a coating layer containing electroconductive fine particles. A developer suitable for use in the above developing apparatus is given by a toner, which comprises a binder resin composition which contains 10-70 wt. % of a THF (tetrahydrofuran)-insoluble content and the remainder of a THF-soluble content including a component with a molecular weight of 10000 or below on a GPC (gel permeation chromatography) chromatogram of the THF-soluble content constituting 10-50 wt. % of the binder resin.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: October 6, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuhito Kuwashima, Hiroyuki Suematsu, Hisayuki Ochi, Manabu Ohno
  • Patent number: 5126224
    Abstract: The present invention provide a toner for developing an electrostatic image. The toner comprises a binder resin and a coloring agent. The binder resin comprises a styrene type binder resin. The amount of an aldehyde contained in the binder resin is not more than 0.005% by weight based on the weight of the toner. The binder resin is produced by a process comprising the steps of preparing a monomer composition comprising a polymerizable monomer containing at least not less than 50% by weight of a styrene monomer, and a polymerization initiator, and subjecting said monomer composition to suspension polymerization in an aqueous medium having dissolved oxygen in an amount of not more than 2.5 mg/lit to form a styrene polymer or copolymer containing an aldehyde monomer in an amount of not more than 0.01% by weight.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: June 30, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshihiko Hyosu, Seiichi Takagi, Hiroyuki Suematsu, Manabu Ohno, Tetsuhito Kuwashima, Eiichi Imai, Yoshinobu Nagai