Patents by Inventor Hisao Yamashita

Hisao Yamashita has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9522391
    Abstract: The first object is to increase the life of a selective CO methanation catalyst, and the second object is to enhance the CO removal rate of a selective CO methanation catalyst to reduce the outlet CO concentration in a wide temperature range. Provided a selective CO methanation catalyst including a supported metal catalyst which selectively methanizes CO in a hydrogen-rich gas containing CO and CO2 and a coating layer which covers a surface of the supported metal catalyst, has many pores, and is configured to reduce a CO concentration on the surface of the supported metal catalyst.
    Type: Grant
    Filed: August 26, 2013
    Date of Patent: December 20, 2016
    Assignee: University of Yamanashi
    Inventors: Toshihiro Miyao, Kazutoshi Higashiyama, Weihua Shen, Hisao Yamashita, Noboru Hashimoto, Shigehito Deki, Masahiro Watanabe
  • Patent number: 9431666
    Abstract: A metallic separator for fuel cells having a metal plate, an electroconductive coating layer covering at least a surface in front and back surfaces of the metal plate which contacts a raw material and/or a reaction product, and an electroconductive channel-forming member disposed on a surface of the coating layer and forming a channel for the raw material and/or the reaction product and/or a channel for a cooling medium for cooling. A surface layer on the metal plate has a tensile residual stress within such a range that no stress-corrosion cracking occurs.
    Type: Grant
    Filed: June 24, 2015
    Date of Patent: August 30, 2016
    Assignee: University of Yamanashi
    Inventors: Masahiro Watanabe, Hiroyuki Uchida, Hisao Yamashita, Kenji Miyatake
  • Publication number: 20150295252
    Abstract: A metallic separator for fuel cells having a metal plate, an electroconductive coating layer covering at least a surface in front and back surfaces of the metal plate which contacts a raw material and/or a reaction product, and an electroconductive channel-forming member disposed on a surface of the coating layer and forming a channel for the raw material and/or the reaction product and/or a channel for a cooling medium for cooling. A surface layer on the metal plate has a tensile residual stress within such a range that no stress-corrosion cracking occurs.
    Type: Application
    Filed: June 24, 2015
    Publication date: October 15, 2015
    Applicant: UNIVERSITY OF YAMANASHI
    Inventors: Masahiro WATANABE, Hiroyuki UCHIDA, Hisao YAMASHITA, Kenji MIYATAKE
  • Publication number: 20150246347
    Abstract: The first object is to increase the life of a selective CO methanation catalyst, and the second object is to enhance the CO removal rate of a selective CO methanation catalyst to reduce the outlet CO concentration in a wide temperature range. Provided a selective CO methanation catalyst including a supported metal catalyst which selectively methanizes CO in a hydrogen-rich gas containing CO and CO2 and a coating layer which covers a surface of the supported metal catalyst, has many pores, and is configured to reduce a CO concentration on the surface of the supported metal catalyst.
    Type: Application
    Filed: August 26, 2013
    Publication date: September 3, 2015
    Applicant: University of Yamanashi
    Inventors: Toshihiro Miyao, Kazutoshi Higashiyama, Weihua Shen, Hisao Yamashita, Noboru Hashimoto, Shigehito Deki, Masahiro Watanabe
  • Patent number: 9099690
    Abstract: A metallic separator for fuel cells having a metal plate, an electroconductive coating layer covering at least a surface in front and back surfaces of the metal plate which contacts a raw material and/or a reaction product, and an electroconductive channel-forming member disposed on a surface of the coating layer and forming a channel for the raw material and/or the reaction product and/or a channel for a cooling medium for cooling. A surface layer on the metal plate has a tensile residual stress within such a range that no stress-corrosion cracking occurs.
    Type: Grant
    Filed: June 16, 2006
    Date of Patent: August 4, 2015
    Assignee: University of Yamanashi
    Inventors: Masahiro Watanabe, Hiroyuki Uchida, Hisao Yamashita, Kenji Miyatake
  • Patent number: 9005552
    Abstract: Provided is a new catalyst capable of removing carbon monoxide economically without adding particular reaction gas externally. Also provided are a process for producing and an apparatus using such a catalyst. Impregnation of a Ni—Al composite oxide precursor of a nonstoichiometric composition prepared by the solution-spray plasma technique with a ruthenium salt to be supported and performing reduction treatment allows CO methanation reaction to selectively proceed even in the high-temperature range in which CO2 methanation reaction and reverse water-gas-shift reaction proceed preferentially with conventional catalysts. Selective CO methanation reaction occurs reproducibly with another Ni—Al composite oxide precursor or an additive metallic species.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: April 14, 2015
    Assignee: University of Yamanashi
    Inventors: Masahiro Watanabe, Hisao Yamashita, Kazutoshi Higashiyama, Toshihiro Miyao, Aihua Chen
  • Publication number: 20120063963
    Abstract: Provided is a new catalyst capable of removing carbon monoxide economically without adding particular reaction gas externally. Also provided are a process for producing and an apparatus using such a catalyst. Impregnation of a Ni—Al composite oxide precursor of a nonstoichiometric composition prepared by the solution-spray plasma technique with a ruthenium salt to be supported and performing reduction treatment allows CO methanation reaction to selectively proceed even in the high-temperature range in which CO2 methanation reaction and reverse water-gas-shift reaction proceed preferentially with conventional catalysts. Selective CO methanation reaction occurs reproducibly with another Ni—Al composite oxide precursor or an additive metallic species.
    Type: Application
    Filed: October 21, 2011
    Publication date: March 15, 2012
    Applicant: UNIVERSITY OF YAMANASHI
    Inventors: Masahiro WATANABE, Hisao YAMASHITA, Kazutoshi HIGASHIYAMA, Toshihiro MIYAO, Aihua CHEN
  • Publication number: 20090214926
    Abstract: A metallic separator for fuel cells having a metal plate, an electroconductive coating layer covering at least a surface in front and back surfaces of the metal plate which contacts a raw material and/or a reaction product, and an electroconductive channel-forming member disposed on a surface of the coating layer and forming a channel for the raw material and/or the reaction product and/or a channel for a cooling medium for cooling. A surface layer on the metal plate has a tensile residual stress within such a range that no stress-corrosion cracking occurs.
    Type: Application
    Filed: June 16, 2006
    Publication date: August 27, 2009
    Applicant: UNIVERSITY OF YAMANASHI
    Inventors: Masahiro Watanabe, Hiroyuki Uchida, Hisao Yamashita, Kenji Miyatake
  • Publication number: 20090142244
    Abstract: An object of the present invention is to improve the decomposition at low temperatures of perfluorocompounds containing only fluorine as a halogen, such as CF4, C2F6 and the like. In the present invention, a perfluorocompound containing only fluorine as a halogen is brought into contact with a catalyst comprising Al, Ni and W as catalytically active ingredients and comprising a mixed oxide or complex oxide of Ni and Al and a mixed oxide or complex oxide of W and Ni, in the presence of steam or a combination of steam and air at a temperature of 500 to 800° C. to convert the fluorine in the perfluorocompound to hydrogen fluoride. Employment of the catalyst of the present invention improves the decomposition at low temperatures and hence makes it possible to decompose the perfluoro-compound at a high percentage of decomposition at a lower temperature.
    Type: Application
    Filed: February 6, 2009
    Publication date: June 4, 2009
    Inventors: Shuichi Kanno, Shin Tamata, Shinichi Ichikawa, Terufumi Kawasaki, Hisao Yamashita
  • Publication number: 20090108975
    Abstract: A high-voltage transformer includes a core, a secondary coil bobbin surrounding the core, and a secondary winding which is wound on the secondary coil bobbin. The secondary winding includes a first partial secondary winding and a second partial secondary winding which are wound on the secondary coil bobbin. Between the first and second partial secondary windings of the secondary winding, there are provided insulators and parallel-connected diodes. The diodes are arranged in a direction away from the core. These diodes are not required to be resistant to high current, thus achieving a compact high-voltage transformer.
    Type: Application
    Filed: April 26, 2007
    Publication date: April 30, 2009
    Inventors: Takesi Nomura, Toshihiro Nakadai, Takaya Nagai, Tadao Yubune, Hisao Yamashita
  • Publication number: 20090096562
    Abstract: A high-voltage transformer includes a core, a coil part, a diode holder, a component block, and a substantially rectangular parallelepiped shaped outer case for accommodating the coil part, the diode holder, and the component block. The coil part includes a coil bobbin into which the core is inserted, and windings wound around the coil bobbin. The diode block includes a plurality of diodes connected to the windings, and a member for holding the diodes. The component block includes electrical components connected to the windings, and a member on which the electrical components are fixedly arranged. The high-voltage transformer is low-profile and small in size.
    Type: Application
    Filed: April 17, 2007
    Publication date: April 16, 2009
    Inventors: Toshihiro Nakadai, Hisao Yamashita, Takaya Nagai
  • Publication number: 20090022642
    Abstract: An object of the present invention is to improve the decomposition at low temperatures of perfluorocompounds containing only fluorine as a halogen, such as CF4, C2F6 and the like. In the present invention, a perfluorocompound containing only fluorine as a halogen is brought into contact with a catalyst comprising Al, Ni and W as catalytically active ingredients and comprising a mixed oxide or complex oxide of Ni and Al and a mixed oxide or complex oxide of W and Ni, in the presence of steam or a combination of steam and air at a temperature of 500 to 800° C. to convert the fluorine in the perfluorocompound to hydrogen fluoride. Employment of the catalyst of the present invention improves the decomposition at low temperatures and hence makes it possible to decompose the perfluoro-compound at a high percentage of decomposition at a lower temperature.
    Type: Application
    Filed: September 8, 2008
    Publication date: January 22, 2009
    Inventors: Shuichi Kanno, Shin Tamata, Shinichi Ichikawa, Terufumi Kawasaki, Hisao Yamashita
  • Patent number: 7438866
    Abstract: A catalyst for use in purifying exhaust gas from an internal combustion engine. The active components of an exhaust gas purification catalyst for an internal combustion engine tend to be melted or softened and then to move outside the carrier, because the components become in contact with exhaust gas at a high temperature. Hence, anchoring materials are provided between carriers in order to suppress the moving of catalytically active components. Anchoring materials 22 do not form compounds with catalytically active components 24, and are selected from substances that do not melt even in contact with exhaust gas at a high temperature. When the active components contain sodium, potassium, cesium, lithium, strontium, barium, noble metals and the like, the best anchoring material is MgO. The anchoring material functions as a barrier that prevents the moving of active components.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: October 21, 2008
    Assignee: Hitachi, Ltd.
    Inventors: Hidehiro Iizuka, Mariko Okude, legal representative, Masato Kaneeda, Hisao Yamashita, Yuichi Kitahara, Osamu Kuroda, Kojiro Okude
  • Patent number: 7435394
    Abstract: An object of the present invention is to improve the decomposition at low temperatures of perfluorocompounds containing only fluorine as a halogen, such as CF4, C2F6 and the like. In the present invention, a perfluorocompound containing only fluorine as a halogen is brought into contact with a catalyst comprising Al, Ni and W as catalytically active ingredients and comprising a mixed oxide or complex oxide of Ni and Al and a mixed oxide or complex oxide of W and Ni, in the presence of steam or a combination of steam and air at a temperature of 500 to 800° C. to convert the fluorine in the perfluorocompound to hydrogen fluoride. Employment of the catalyst of the present invention improves the decomposition at low temperatures and hence makes it possible to decompose the perfluoro-compound at a high percentage of decomposition at a lower temperature.
    Type: Grant
    Filed: August 20, 2003
    Date of Patent: October 14, 2008
    Assignee: Hitachi, Ltd.
    Inventors: Shuichi Kanno, Shin Tamata, Shinichi Ichikawa, Terufumi Kawasaki, Hisao Yamashita
  • Patent number: 7347980
    Abstract: A gas stream containing at least one fluorine compound selected from the group consisting of compounds of carbon and fluorine, compounds of carbon, hydrogen and fluorine, compounds of sulfur and fluorine, compounds of nitrogen and fluorine and compounds of carbon, hydrogen, oxygen and fluorine is contacted with a catalyst comprising at least one of alumina, titania, zirconia and silica, preferably a catalyst comprising alumina and at least one of nickel oxide, zinc oxide and titania in the presence of steam, thereby hydrolyzing the fluorine compound at a relatively low temperature, e.g. 200°–800° C., to convert the fluorine of the fluorine compound to hydrogen fluoride.
    Type: Grant
    Filed: October 7, 2003
    Date of Patent: March 25, 2008
    Assignee: Hitachi, Ltd.
    Inventors: Shuichi Kanno, Toshiaki Arato, Shinzo Ikeda, Ken Yasuda, Hisao Yamashita, Shigeru Azuhata, Shin Tamata, Kazuyoshi Irie
  • Patent number: 7294315
    Abstract: Fluorine compounds such as C2F6, CF4, CHF3, SF6 and NF3, are made in contact with a fluorine compound decomposition catalyst and a catalyst the decomposition oft least one of CO, SO2F2 and N2O in the presence of water or in the presence of water and oxygen. The catalyst the decomposition oft least one of CO, SO2F2 and N2O preferably contains at least one selected from Pd, Pt, Cu, Mn, Fe, Co, Rh, Ir and Au in the form of a metal or an oxide. According to the invention, the fluorine compound can be converted to HF, which is liable to be absorbed by water or an alkaline aqueous solution, and a substance, such as CO, SO2F2 and N2O, formed by decomposition of the fluorine compound can also be decomposed.
    Type: Grant
    Filed: June 9, 1999
    Date of Patent: November 13, 2007
    Assignee: Hitachi, Ltd.
    Inventors: Shuichi Kanno, Akio Honji, Hisao Yamashita, Shigeru Azuhata, Shin Tamata, Kazuyoshi Irie
  • Patent number: 7285250
    Abstract: In order to prevent exhaust pipe for exhausting perfluorocompound (PFC) decomposition gas after washing from corrosion, a mist separating apparatus is provided at a rear stage of the washing tower for washing the PFC decomposition gas. The corrosion of the exhaust pipe can be prevented by removing the mist from the washed gas.
    Type: Grant
    Filed: May 3, 2002
    Date of Patent: October 23, 2007
    Assignee: Hitachi, Ltd.
    Inventors: Shuichi Kanno, Hisao Yamashita, Tomohiko Miyamoto, Shin Tamata, Yoshiki Shibano, Takeo Komuro, Tsugihiro Yukitake, Terufumi Kawasaki
  • Publication number: 20070204595
    Abstract: An exhaust gas purification apparatus for use in an internal combustion engine comprises an exhaust gas duct connected to the engine through which exhaust gas containing NOx gas passes, and a catalyst disposed in the exhaust gas duct such that it contacts the exhaust gas. The catalyst chemically adsorbs NOx when a stoichiometric amount of a gaseous oxidizing agent present in the exhaust gas is larger than that of a gaseous reducing agent present in the exhaust gas for reducing NOx, adsorbed NOx is catalytically reduced in the presence of a reducing agent when the stoichiometric amount of the oxidizing agent is not larger that of the reducing agent.
    Type: Application
    Filed: May 9, 2007
    Publication date: September 6, 2007
    Applicants: HITACHI, LTD., HONDA MOTOR CO., LTD.
    Inventors: Hiroshi HANAOKA, Osamu Kuroda, Ryouta Doi, Hidehiro Iizuka, Toshio Ogawa, Hisao Yamashita, Shigeru Azuhata, Yuichi Kitahara, Toshifumi Hiratsuka, Kojiro Okude, Norihiro Shinotsuka, Toshio Manaka
  • Patent number: 7261868
    Abstract: Fluorine compounds such as C2F6, CF4, CHF3, SF6 and NF3, are made to contact with a fluorine compound decomposition catalyst and a catalyst for the decomposition of at least one of CO, SO2F2 and N2O in the presence of water or in the presence of water and oxygen. The catalyst for the decomposition of at least one of CO, SO2F2 and N2O preferably contains at least one selected from Pd, Pt, Cu, Mn, Fe, Co, Rh, Ir and Au in the form of a metal or an oxide. According to the invention, the fluorine compound can be converted to HF, which can be absorbed by water or an alkaline aqueous solution. Furthermore, a substance such as CO, SO2F2 and N2O which is formed by decomposition of the fluorine compound can also be decomposed.
    Type: Grant
    Filed: November 15, 2004
    Date of Patent: August 28, 2007
    Assignee: Hitachi, Ltd.
    Inventors: Shuichi Kanno, Akio Honji, Hisao Yamashita, Shigeru Azuhata, Shin Tamata, Kazuyoshi Irie
  • Patent number: 7093432
    Abstract: An exhaust gas purification apparatus for use in an internal combustion engine comprises an exhaust gas duct connected to the engine through which the exhaust gas containing NOx gas passes and a catalyst so disposed in the exhaust gas duct that it contacts with the exhaust gas. The catalyst chemically adsorbs NOx under the condition that a stoichiometric amount of a gaseous oxidizing agent present in the exhaust gas is larger than that of a gaseous reducing agent present in the exhaust gas for reducing NOx, while NOx being adsorbed is catalytically reduced in the presence of the reducing agent under the condition that the stoichiometric amount of the oxidizing agent is not larger that of the reducing agent. Thereby, NOx, the lean burn exhaust gas in the engine can be effectively made harmlessly.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: August 22, 2006
    Assignees: Hitachi, Ltd., Honda Motor Co., Ltd.
    Inventors: Hiroshi Hanaoka, Osamu Kuroda, Ryouta Doi, Hidehiro Iizuka, Toshio Ogawa, Hisao Yamashita, Shigeru Azuhata, Yuichi Kitahara, Toshifumi Hiratsuka, Kojiro Okude, Norihiro Shinotsuka, Toshio Manaka