Patents by Inventor Hisashi Kozuka

Hisashi Kozuka has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230212021
    Abstract: A lanthanum molybdenum composite oxide is provided. The lanthanum molybdenum composite oxide has a primary crystal phase formed of La2Mo2O9. The lanthanum molybdenum composite oxide also has a secondary crystal phase formed of a lanthanum molybdenum composite oxide species other than La2Mo2O9. The secondary crystal phase may contain at least one species selected from a group consisting of La2Mo3O12, La6MoO12, La7Mo7O30, La2Mo4O15, La2MoO6, La4MoO9, and LaMo2O5.
    Type: Application
    Filed: June 22, 2021
    Publication date: July 6, 2023
    Inventors: Akira NAKAJIMA, Takumi MATSUMOTO, Mao SHOJI, Hisashi KOZUKA
  • Publication number: 20220059263
    Abstract: The iron loss of a dust core is reduced. A dust core (1) includes soft magnetic metal particles (3) having an average particle size of 5 ?m or more and 30 ?m or less, and a particle boundary phase (6). The particle boundary phase (6) includes a polycrystalline compound containing Al (aluminum). When a sectional structure of the dust core (1) is observed, an area percentage of ?-Al2O3 in the particle boundary phase (6) is 75% or less. An average thickness Ta of the particle boundary phase (6) is 10 nm or more and 300 nm or less. According to the present invention, the iron loss is reduced.
    Type: Application
    Filed: March 11, 2020
    Publication date: February 24, 2022
    Inventors: Hiroshi WATANABE, Satoshi MORI, Manami FUJII, Katsuya TAKAOKA, Hiroki TAKEUCHI, Hisashi KOZUKA
  • Patent number: 10883192
    Abstract: A sintered electrically conductive oxide for an oxygen sensor electrode includes a crystal phase formed of a perovskite-type electrically conductive oxide containing at least La, Fe and Ni. The oxide has an absolute value of thermoelectromotive force at 770° C. of 21.0 ?V/K or less.
    Type: Grant
    Filed: May 12, 2016
    Date of Patent: January 5, 2021
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi Kozuka, Yasuyuki Okimura, Kazushige Ohbayashi
  • Patent number: 10629322
    Abstract: An electrically conductive oxide sintered compact according to one embodiment of the present invention includes a crystal phase that has a perovskite oxide crystal structure represented by the composition formula: REaCobCucNidOx where RE is a rare-earth element; a+b+c+d=1; and 1.25?x?1.75, wherein the values of a, b, c and d respectively satisfy the following conditions: 0.474?a?0.512; 0.050?b?0.350; 0?c?0.250; and 0.050?d?0.350.
    Type: Grant
    Filed: December 7, 2015
    Date of Patent: April 21, 2020
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi Kozuka, Yasuyuki Okimura, Kazushige Ohbayashi
  • Patent number: 10379076
    Abstract: A gas sensor, characterized by having an electrode formed of a conductive oxide sintered body which contains a primary phase formed of a perovskite oxide containing at least La, Fe, and Ni; and a secondary phase formed of an La4M3O10 phase or an La3M2O7 phase (M=Co, Fe, Ni), wherein the conductive oxide sintered body has a conductivity of 300 S/cm or higher at room temperature.
    Type: Grant
    Filed: March 28, 2016
    Date of Patent: August 13, 2019
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi Kozuka, Mina Sato, Yasuyuki Okimura, Kazushige Ohbayashi
  • Patent number: 10352893
    Abstract: A gas sensor control apparatus including a gas sensor element, a heater for heating the gas sensor element, and heater energization control means for feedback controlling the supply of electric current to the heater such that the internal resistance of the gas sensor element coincides with a target resistance. The gas sensor element has a solid electrolyte member and an electrode portion including an outside electrode and an inside electrode. At least a portion of the electrode portion is formed of an electrically conductive oxide whose main component is (i) a first perovskite phase which is represented by a composition formula of LaCo1?xNixO3±d (0.300?x?0.600, 0?d?0.4) and has a perovskite-type crystal structure, or (ii) a second perovskite phase which is represented by a composition formula of LaFe1?yNiyO3±d (0.450?y?0.700, 0?d?0.4) and has a perovskite-type crystal structure.
    Type: Grant
    Filed: August 29, 2016
    Date of Patent: July 16, 2019
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Keisuke Nakagawa, Shigehiro Ohtsuka, Hisashi Kozuka, Kazuma Ito, Ippei Kato
  • Patent number: 10347817
    Abstract: A lead-free piezoelectric ceramic composition including an alkali niobate/tantalate perovskite oxide main phase having piezoelectric properties and a different metal oxide. The mole ratio (Na/K) between Na (sodium) and K (potassium) in the main phase is 0.40<(Na/K)<3.0. The main phase has a crystal structure in which (i) first spots corresponding to a primitive lattice period and (ii) second spots corresponding to the lattice period two times the primitive lattice period and being weaker than the first spots appear in an electron beam diffraction image entering from the <100> direction with the main phase represented as a pseudo-cubic crystal system. Also, the area ratio of a crystal phase reflecting the second spots in the main phase is 33% or less, and the maximum grain size of crystals reflecting the second spots in the main phase is 25 nm or less.
    Type: Grant
    Filed: March 5, 2015
    Date of Patent: July 9, 2019
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi Kozuka, Hideto Yamada, Takayuki Matsuoka, Kazuaki Kitamura, Masato Yamazaki, Toshiaki Kurahashi, Takashi Kasashima, Yasuyuki Okimura, Kazushige Ohbayashi
  • Patent number: 10340441
    Abstract: A lead-free piezoelectric ceramic composition including an alkali niobate/tantalate perovskite oxide main phase having piezoelectric properties and a different metal oxide subphase. The mole ratio (Na/K) between Na (sodium) and K (potassium) in the main phase assumes a value in a range represented by 0.40<(Na/K)<3.0. The main phase has a crystal structure in which (i) first spots corresponding to a primitive lattice period and (ii) second spots corresponding to the lattice period two times the primitive lattice period and being weaker than the first spots appear in an electron beam diffraction image entering from the <100> direction with the main phase represented as a pseudo-cubic crystal system.
    Type: Grant
    Filed: March 5, 2015
    Date of Patent: July 2, 2019
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi Kozuka, Hideto Yamada, Takayuki Matsuoka, Kazuaki Kitamura, Masato Yamazaki, Toshiaki Kurahashi, Takashi Kasashima, Yasuyuki Okimura, Kazushige Ohbayashi
  • Patent number: 10302589
    Abstract: A gas sensor including a conductive oxide sintered body, the sintered body including a crystal phase having a perovskite-type oxide crystal structure represented by a compositional formula: REaCubFecNidOx wherein RE represents a rare earth element, wherein the following conditions: a+b+c+d=1 and 1.25?x?1.75 are satisfied, and wherein a, b, c, and d satisfy the following conditions: 0.375?a?0.524; 0.050<b?0.200; 0.025?c?0.250; and 0.150?d?0.350. Also disclosed is a conductive oxide sintered body, a wiring board including a conductor layer formed of the conductive oxide sintered body and a gas sensor including an electrode formed of the conductive oxide sintered body.
    Type: Grant
    Filed: August 7, 2017
    Date of Patent: May 28, 2019
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Mina Sato, Yoshinobu Hirose, Akira Seike, Hisashi Kozuka, Yasuyuki Okimura, Kazushige Ohbayashi
  • Publication number: 20180330843
    Abstract: An electrically conductive oxide sintered compact according to one embodiment of the present invention includes a crystal phase that has a perovskite oxide crystal structure represented by the composition formula: REaCobCucNidOx where RE is a rare-earth element; a+b+c+d=1; and 1.25?x?1.75, wherein the values of a, b, c and d respectively satisfy the following conditions: 0.474?a?0.512; 0.050?b?0.350; 0?c?0.250; and 0.050?d?0.350.
    Type: Application
    Filed: December 7, 2015
    Publication date: November 15, 2018
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi KOZUKA, Yasuyuki OKIMURA, Kazushige OHBAYASHI
  • Patent number: 10090646
    Abstract: Disclosed is a spark plug capable of suppressing high-frequency noise by improving the material of an electrical connection part between a center electrode and a metal terminal within an axial hole of an insulator. A spark plug has an electrical connection part arranged in an axial hole of an insulator to establish electrical connection between a center electrode and a metal terminal. The electrical connection part includes a conductor having a first crystal phase formed of a Fe-containing oxide and a second crystal phase formed of a conductive metal oxide of perovskite crystal structure.
    Type: Grant
    Filed: June 2, 2015
    Date of Patent: October 2, 2018
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Katsuya Takaoka, Kazuhiro Kurosawa, Kuniharu Tanaka, Hisashi Kozuka, Toshitaka Honda, Hirokazu Kurono, Haruki Yoshida, Hironori Uegaki
  • Publication number: 20180106754
    Abstract: A gas sensor, characterized by having an electrode formed of a conductive oxide sintered body which contains a primary phase formed of a perovskite oxide containing at least La, Fe, and Ni; and a secondary phase formed of an La4M3O10 phase or an La3M2O7 phase (M=Co, Fe, Ni), wherein the conductive oxide sintered body has a conductivity of 300 S/cm or higher at room temperature.
    Type: Application
    Filed: March 28, 2016
    Publication date: April 19, 2018
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi KOZUKA, Mina SATO, Yasuyuki OKIMURA, Kazushige OHBAYASHI
  • Patent number: 9938197
    Abstract: A lead-free piezoelectric ceramic composition includes a first crystal phase made of an alkali niobate/tantalate type perovskite oxide having piezoelectric properties, and a second crystal phase made of an M-Ti—O spinel compound (where the element M is a monovalent to quadrivalent element).
    Type: Grant
    Filed: March 11, 2014
    Date of Patent: April 10, 2018
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Masato Yamazaki, Takayuki Matsuoka, Kazuaki Kitamura, Hisashi Kozuka, Hideto Yamada, Toshiaki Kurahashi, Yasuyuki Okimura, Kazushige Ohbayashi, Takashi Kasashima
  • Publication number: 20180045673
    Abstract: A gas sensor including a conductive oxide sintered body, the sintered body including a crystal phase having a perovskite-type oxide crystal structure represented by a compositional formula: REaCubFecNidOx wherein RE represents a rare earth element, wherein the following conditions: a+b+c+d=1 and 1.25?x?1.75 are satisfied, and wherein a, b, c, and d satisfy the following conditions: 0.375?a?0.524; 0.050<b?0.200; 0.025?c?0.250; and 0.150?d?0.350. Also disclosed is a conductive oxide sintered body, a wiring board including a conductor layer formed of the conductive oxide sintered body and a gas sensor including an electrode formed of the conductive oxide sintered body.
    Type: Application
    Filed: August 7, 2017
    Publication date: February 15, 2018
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Mina SATO, Yoshinobu HIROSE, Akira SEIKE, Hisashi KOZUKA, Yasuyuki OKIMURA, Kazushige OHBAYASHI
  • Patent number: 9871187
    Abstract: A lead-free piezo-electric porcelain composition which contains a main phase having voids and which is formed of a first crystal phase composed of an alkali niobate/tantalate-based perovskite oxide having piezo-electric characteristics; and a sub-phase containing a second crystal phase composed of an A2B6O13-based compound (where the element A is a monovalent element and the element B is one or more divalent to hexavalent elements). The sub-phase fills voids present in the main phase.
    Type: Grant
    Filed: April 9, 2015
    Date of Patent: January 16, 2018
    Assignee: NGK SPARK PLUG CO., LTD.
    Inventors: Masato Yamazaki, Takayuki Matsuoka, Yoshiteru Honda, Kazuaki Kitamura, Hisashi Kozuka, Toshiaki Kurahashi, Yasuyuki Okimura, Hideto Yamada, Kazushige Ohbayashi
  • Publication number: 20170214219
    Abstract: Disclosed is a spark plug capable of suppressing high-frequency noise by improving the material of an electrical connection part between a center electrode and a metal terminal within an axial hole of an insulator. A spark plug has an electrical connection part arranged in an axial hole of an insulator to establish electrical connection between a center electrode and a metal terminal. The electrical connection part includes a conductor having a first crystal phase formed of a Fe-containing oxide and a second crystal phase formed of a conductive metal oxide of perovskite crystal structure.
    Type: Application
    Filed: June 2, 2015
    Publication date: July 27, 2017
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Katsuya TAKAOKA, Kazuhiro KUROSAWA, Kuniharu TANAKA, Hisashi KOZUKA, Toshitaka HONDA, Hirokazu KURONO, Haruki YOSHIDA, Hironori UEGAKI
  • Publication number: 20170141293
    Abstract: A lead-free piezoelectric ceramic composition including an alkali niobate/tantalate perovskite oxide main phase having piezoelectric properties and a different metal oxide. The mole ratio (Na/K) between Na (sodium) and K (potassium) in the main phase is 0.40<(Na/K)<3.0. The main phase has a crystal structure in which (i) first spots corresponding to a primitive lattice period and (ii) second spots corresponding to the lattice period two times the primitive lattice period and being weaker than the first spots appear in an electron beam diffraction image entering from the <100> direction with the main phase represented as a pseudo-cubic crystal system. Also, the area ratio of a crystal phase reflecting the second spots in the main phase is 33% or less, and the maximum grain size of crystals reflecting the second spots in the main phase is 25 nm or less.
    Type: Application
    Filed: March 5, 2015
    Publication date: May 18, 2017
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi KOZUKA, Hideto YAMADA, Takayuki MATSUOKA, Kazuaki KITAMURA, Masato YAMAZAKI, Toshiaki KURAHASHI, Takashi KASASHIMA, Yasuyuki OKIMURA, Kazushige OHBAYASHI
  • Publication number: 20170141292
    Abstract: A lead-free piezoelectric ceramic composition including an alkali niobate/tantalate perovskite oxide main phase having piezoelectric properties and a different metal oxide subphase. The mole ratio (Na/K) between Na (sodium) and K (potassium) in the main phase assumes a value in a range represented by 0.40<(Na/K)<3.0. The main phase has a crystal structure in which (i) first spots corresponding to a primitive lattice period and (ii) second spots corresponding to the lattice period two times the primitive lattice period and being weaker than the first spots appear in an electron beam diffraction image entering from the <100> direction with the main phase represented as a pseudo-cubic crystal system.
    Type: Application
    Filed: March 5, 2015
    Publication date: May 18, 2017
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi KOZUKA, Hideto YAMADA, Takayuki MATSUOKA, Kazuaki KITAMURA, Masato YAMAZAKI, Toshiaki KURAHASHI, Takashi KASASHIMA, Yasuyuki OKIMURA, Kazushige OHBAYASHI
  • Publication number: 20170059511
    Abstract: A gas sensor control apparatus including a gas sensor element, a heater for heating the gas sensor element, and heater energization control means for feedback controlling the supply of electric current to the heater such that the internal resistance of the gas sensor element coincides with a target resistance. The gas sensor element has a solid electrolyte member and an electrode portion including an outside electrode and an inside electrode. At least a portion of the electrode portion is formed of an electrically conductive oxide whose main component is (i) a first perovskite phase which is represented by a composition formula of LaCo1-xNixO3±d (0.300?x?0.600, 0?d?0.4) and has a perovskite-type crystal structure, or (ii) a second perovskite phase which is represented by a composition formula of LaFe1-yNiyO3±d (0.450?y?0.700, 0?d?0.4) and has a perovskite-type crystal structure.
    Type: Application
    Filed: August 29, 2016
    Publication date: March 2, 2017
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Keisuke NAKAGAWA, Shigehiro OHTSUKA, Hisashi KOZUKA, Kazuma ITO, Ippei KATO
  • Publication number: 20160334361
    Abstract: A sintered electrically conductive oxide for an oxygen sensor electrode includes a crystal phase formed of a perovskite-type electrically conductive oxide containing at least La, Fe and Ni. The oxide has an absolute value of thermoelectromotive force at 770° C. of 21.0 ?V/K or less.
    Type: Application
    Filed: May 12, 2016
    Publication date: November 17, 2016
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Hisashi KOZUKA, Yasuyuki OKIMURA, Kazushige OHBAYASHI