Patents by Inventor Hisaya Ushiyama

Hisaya Ushiyama has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20220289922
    Abstract: The present invention relates to a fiber-reinforced epoxy resin composite sheet comprising an epoxy resin film and reinforcing fibers laminated on one or both surfaces of the epoxy resin film, wherein in the reinforcing fibers, opened fibers are oriented in a predetermined direction, and a volume content Vf of the reinforcing fiber is 5 to 70%.
    Type: Application
    Filed: June 8, 2020
    Publication date: September 15, 2022
    Applicants: FUKUVI CHEMICAL INDUSTRY CO., LTD., MITSUBISHI CHEMICAL CORPORATION
    Inventors: Munetake TAJIMA, Naoaki KANAMORI, Hisaya USHIYAMA, Yusuke WATANABE
  • Publication number: 20210403701
    Abstract: A curable resin composition including components (A), (B), (C) and (D) below: component (A): a bisphenol epoxy resin with a softening point of 80° C. or more, component (B): a bisphenol epoxy resin which is liquid at 25° C., component (C): a bi- or more-functional (meth)acrylate compound, and component (D): a curing agent.
    Type: Application
    Filed: September 9, 2021
    Publication date: December 30, 2021
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hisaya USHIYAMA, Nao DEGUCHI, Kenichi WATANABE, Juichi FUJIMOTO
  • Patent number: 11161975
    Abstract: A curable resin composition including components (A), (B), (C) and (D) below: component (A): a bisphenol epoxy resin with a softening point of 80° C. or more, component (B): a bisphenol epoxy resin which is liquid at 25° C., component (C): a bi- or more-functional (meth)acrylate compound, and component (D): a curing agent.
    Type: Grant
    Filed: June 20, 2019
    Date of Patent: November 2, 2021
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hisaya Ushiyama, Nao Deguchi, Kenichi Watanabe, Juichi Fujimoto
  • Publication number: 20210253808
    Abstract: A heat-curable epoxy resin composition is a mixture in which an epoxy compound represented by formula (al), a polyisocyanate, a bisphenol type liquid epoxy resin and an epoxy resin curing agent are blended. An amount of the epoxy compound, per 100 parts by mass of all the epoxy resin blended in the heat-curable epoxy resin composition, is 5 parts by mass or more.
    Type: Application
    Filed: April 29, 2021
    Publication date: August 19, 2021
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hisaya USHIYAMA, Yusuke Watanabe, Natsumi Mukouzaka, Hayato Ogasawara, Akira Ota
  • Patent number: 10513577
    Abstract: An epoxy resin composition includes an organic phosphinic acid metal salt; an epoxy resin; dicyandiamide or a derivative thereof; a curing accelerator having a dimethylureido group; and an imidazole-based curing accelerator having a curing initiation temperature of 100° C. or higher. The curing initiation temperature is measured by a method includes preparing a sample resin composition by adding 10 parts by mass of an imidazole-based curing accelerator to 100 parts by mass of a bisphenol A type epoxy resin having an epoxy equivalent of 180 to 220, and mixing the components; measuring a calorific value of the sample resin composition using a differential scanning calorimeter at a rate of temperature increase of 10° C./min, and designating a temperature at the intersection point of the tangent line at the inflection point of the DSC curve thus obtained and the baseline as the curing initiation temperature.
    Type: Grant
    Filed: June 9, 2016
    Date of Patent: December 24, 2019
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hisaya Ushiyama, Kenichi Watanabe
  • Publication number: 20190330464
    Abstract: A curable resin composition including components (A), (B), (C) and (D) below: component (A): a bisphenol epoxy resin with a softening point of 80° C. or more, component (B): a bisphenol epoxy resin which is liquid at 25° C., component (C): a bi- or more-functional (meth)acrylate compound, and component (D): a curing agent.
    Type: Application
    Filed: June 20, 2019
    Publication date: October 31, 2019
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hisaya USHIYAMA, Nao DEGUCHI, Kenichi WATANABE, Juichi FUJIMOTO
  • Patent number: 10227476
    Abstract: The present invention pertains to a prepreg containing reinforcing fibers and an epoxy resin composition. Said prepreg is sandwiched between dies preheated to 140.degree.C. and pressurized to MPa and held for five minutes at this temperature to obtain a cured article having a G?Tg of at least 150.degree.C. The present invention also pertains to a fiber-reinforced composite material and a method for producing same. According to this invention, it is possible to provide a prepreg which is well suited to press-molding, particularly to high-cycle press-molding. It is also possible to provide a fiber-reinforced composite material which can be heat-cured at a lower temperature and over a shorter time than conventional methods, with which it is possible to minimize excessive flow of resin in hot-press curing, and which is resistant to performance defects such as fiber meandering and defects in surface appearance. A method for producing the same can also be provided.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: March 12, 2019
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yasuhiro Fukuhara, Hisaya Ushiyama, Manabu Kaneko
  • Patent number: 9994697
    Abstract: The present invention is an epoxy resin composition characterized by containing component A (epoxy resin containing sulfur atoms in the molecule thereof); and component B (an epoxy resin composition containing an imidazole compound represented by formula (1), and at least one of the following components: component C (an imidazole compound represented by formula (2) below) or component D (an epoxy resin composition having at least one sulfur atom in the molecule. According to the present invention, it is possible to provide an epoxy resin composition which has outstanding stability when stored at room temperature, and which can be heat-cured at a relatively low temperature and over a short time, to give a resin with a high heat resistance when cured. (In formula (1), R1 represents a straight-chain or branched-chain alkyl group having 1 to 5 carbon atoms, or a hydroxymethyl group, R2 represents a straight-chain or branched-chain alkyl group having 1 to 5 carbon atoms, or a hydrogen atom.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: June 12, 2018
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yasuhiro Fukuhara, Hisaya Ushiyama, Manabu Kaneko
  • Publication number: 20180155489
    Abstract: An epoxy resin composition comprising the following Component (A), Component (B), Component (C), and Component (D): Component (A): an organic phosphinic acid metal salt; Component (B): an epoxy resin; Component (C): dicyandiamide or a derivative thereof; and Component (D): a curing accelerator having a dimethylureido group. The epoxy resin composition described above, further comprising the Component (E) which is an imidazole-based curing accelerator having a curing initiation temperature of 100° C. or higher as measured by the following method. Measurement method of a curing initiation temperature: a sample resin composition is prepared by adding 10 parts by mass of an imidazole-based curing accelerator to 100 parts by mass of a bisphenol A type epoxy resin having an epoxy equivalent of 180 to 220, and mixing the components. For this sample resin composition, the calorific value is measured using a differential scanning calorimeter (DSC) at a rate of temperature increase of 10° C.
    Type: Application
    Filed: June 9, 2016
    Publication date: June 7, 2018
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hisaya USHIYAMA, Kenichi WATANABE
  • Patent number: 9212295
    Abstract: Provided is a method for producing a good epoxy resin composition for obtaining fiber-reinforced plastics. A production method for obtaining a fiber-reinforced composite material by impregnating a fiber assembly with an epoxy resin composition and then curing the epoxy resin composition, wherein the epoxy resin composition contains a component [A], a component [B] and a component [C] respectively satisfying the conditions described below. When the blending amount of the component [B] is set to b parts by mass and the blending amount of the component [C] is set to c parts by mass relative to 100 parts by mass of the component [A] contained in the epoxy resin composition, formula (2) is satisfied within the range of formula (1), formula (4) is satisfied within the range of formula (3), and formula (6) is satisfied within the range of formula (5).
    Type: Grant
    Filed: February 16, 2012
    Date of Patent: December 15, 2015
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Hisaya Ushiyama, Yasuhiro Fukuhara, Kazuki Koga, Tomoo Sano, Kazutami Mitani
  • Publication number: 20140273693
    Abstract: The present invention pertains to a prepreg containing reinforcing fibers and an epoxy resin composition. Said prepreg is sandwiched between dies preheated to 140.degree.C and pressurized to MPa and held for five minutes at this temperature to obtain a cured article having a G?Tg of at least 150.degree.C. The present invention also pertains to a fiber-reinforced composite material and a method for producing same. According to this invention, it is possible to provide a prepreg which is well suited to press-molding, particularly to high-cycle press-molding. It is also possible to provide a fiber-reinforced composite material which can be heat-cured at a lower temperature and over a shorter time than conventional methods, with which it is possible to minimize excessive flow of resin in hot-press curing, and which is resistant to performance defects such as fiber meandering and defects in surface appearance. A method for producing the same can also be provided.
    Type: Application
    Filed: November 29, 2012
    Publication date: September 18, 2014
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Yasuhiro Fukuhara, Hisaya Ushiyama, Manabu Kaneko
  • Publication number: 20140235757
    Abstract: The present invention is an epoxy resin composition characterized by containing component A (epoxy resin containing sulfur atoms in the molecule thereof); and component B (an epoxy resin composition containing an imidazole compound represented by formula (1), and at least one of the following components: component C (an imidazole compound represented by formula (2) below) or component D (an epoxy resin composition having at least one sulfur atom in the molecule. According to the present invention, it is possible to provide an epoxy resin composition which has outstanding stability when stored at room temperature, and which can be heat-cured at a relatively low temperature and over a short time, to give a resin with a high heat resistance when cured. (In formula (1), R1 represents a straight-chain or branched-chain alkyl group having 1 to 5 carbon atoms, or a hydroxymethyl group, R2 represents a straight-chain or branched-chain alkyl group having 1 to 5 carbon atoms, or a hydrogen atom.
    Type: Application
    Filed: November 29, 2012
    Publication date: August 21, 2014
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Yasuhiro Fukuhara, Hisaya Ushiyama, Manabu Kaneko
  • Publication number: 20130330478
    Abstract: Provided is a method for producing a good epoxy resin composition for obtaining fiber-reinforced plastics. A production method for obtaining a fiber-reinforced composite material by impregnating a fiber assembly with an epoxy resin composition and then curing the epoxy resin composition, wherein the epoxy resin composition contains a component [A], a component [B] and a component [C] respectively satisfying the conditions described below. When the blending amount of the component [B] is set to b parts by mass and the blending amount of the component [C] is set to c parts by mass relative to 100 parts by mass of the component [A] contained in the epoxy resin composition, formula (2) is satisfied within the range of formula (1), formula (4) is satisfied within the range of formula (3), and formula (6) is satisfied within the range of formula (5).
    Type: Application
    Filed: February 16, 2012
    Publication date: December 12, 2013
    Applicant: MITSUBISHI RAYON CO., LTD.
    Inventors: Hisaya Ushiyama, Yasuhiro Fukuhara, Kazuki Koga, Tomoo Sano, Kazutami Mitani