Abstract: We have discovered that exposure of a photoresist on a photomask substrate to a vacuum after the photoresist has been exposed to imaging radiation results in improved critical dimension uniformity of the developed photoresist. Exposure of the imaged photoresist to vacuum is performed for a period of time sufficient to allow pattern critical dimensions to reach equilibrium across the photoresist. The vacuum treatment process of the invention is typically performed prior to the performance of a post-exposure bake process and prior to development of the photoresist. We have also discovered that exposure of a photoresist on a photomask substrate to a vacuum after the photoresist has been developed results in an improvement in the line edge roughness of pattern openings that have been formed through the photoresist layer thickness.