Abstract: The present application provides a process for the preparation of ?-methylene-?-butyrolactone, said process comprising the steps of: a) acetylating the C1-hydroxyl group of isoprenol to yield isoprenyl acetate; b) forming 4-acetoxy-2-methylene-butan-1-ol from said isoprenyl acetate by whole cell biotransformation, said step comprising: i) contacting a cell (CB) with a culture medium containing said isoprenyl acetate or with a culture medium contiguous with an organic phase containing said isoprenyl acetate under conditions that enable the cell to form 4-acetoxy-2-methylene-butan-1-ol from isoprenyl acetate; and, ii) optionally isolating the resultant 4-acetoxy-2-methylene-butan-1-ol, wherein said cell (CB) exhibits activity of at least one alkane monooxygenase enzyme which catalyzes the formation of 4-acetoxy-2-methylene-butan-1-ol from isoprenyl acetate; c) oxidizing said 4-acetoxy-2-methylene-butan-1-ol to yield 4-acetoxy-2-methylene butyric acid; and, d) converting said 4-acetoxy-2-methylene butyric

Abstract: The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.

Abstract: The present application is directed to a polythiol compound having the general Formula VI, wherein: m is an integer of from 4 to 600; n is an integer of from 4 to 400; R1 is a C1-C18 alkylene group, C2-C18 oxyalkylene group, C2-C18 thioalkylene group, C6-C18 arylene or C7-C18 aralkylene group; and, R2 is H or methyl.

Abstract: The present application is directed to a polythiol compound obtainable from at least one of serine (Ser) and tyrosine (Tyr) and having the general Formula VIA, VIB or VIC, wherein: R1 is a C1-C18 alkylene group, C2-C18 oxyalkylene group, C2-C18 thioalkylene group, C6-C18 arylene or C7-C18 aralkylene group; and, R2 is H or methyl.

Abstract: The present application is directed to a polythiol compound obtainable independently from a) eugenol, b) gallic acid, c) the adduct of guaiacol and vanillin or d) resveratrol and, respectively, having the general Formula VIA, VIB, VIC or VID, wherein: R1 is a C1-C18 alkylene group, C2-C18 oxyalkylene group, C2-C18 thioalkylene group, C6-C18 arylene or C7-C18 aralkylene group; and R2 is H or methyl.

Abstract: The present invention relates to a hot-melt adhesive composition comprising at least one polyester polyol based on Betulin and at least one NCO-terminated compound as well as a method for the production of a laminated article using the inventive hot-melt adhesive composition.

Abstract: The present invention pertains to reactive (moisture curing) plasticizers; adhesives and sealants containing the plasticizers and methods of bonding and sealing substrates with adhesives and sealants containing the plasticizers.

Abstract: The present invention relates to adhesives which contain a polyester polyol on the basis of furandicarboxylic acid obtained from renewable raw materials, and to a method for bonding substrates, in particular film-like substrates, using said adhesive.

Abstract: The present invention relates to amorphous polyesters on the basis of betulin, a method for producing them and their use.

Abstract: The present invention relates to a semi-crystalline mixture of polyester polyols which recrystallises upon melting and which can be obtained by polycondensing a reaction mixture comprising one or more dicarboxylic acids selected from saturated aliphatic dicarboxylic acids having an even number of at least 8 methylene groups, and one or more diols selected from aliphatic diols which have at least one ether function. The invention also relates to a polymeric material which is obtained from the chemical modification of the mixture of polyester polyols with organic compounds which contain at least one isocyonate group and/or epoxide group. The mixtures and materials according to the invention are characterised by relatively low melting enthalpies, while the melting temperature can be set in a range of ?30 to 60° C., meaning that it is possible to obtain easily fusible formulations containing the mixtures and materials according to the invention.

Abstract: The present invention relates to an epoxy composition comprising a) an epoxy resin; b) a curing agent; and c) a bio-based epoxy compound having a structure I: The composition according to the present invention can be used as a structural adhesive, a coating and a primer.

Abstract: The present invention relates to an epoxy composition comprising a) a cycloaliphatic epoxy resin; b) a curing agent; and c) a bio-based epoxy compound having a structure I: The composition according to the present invention can be used as a structural adhesive, a coating and a primer.

Abstract: The present invention relates to a pressure-sensitive adhesive composition containing at least one polymer and at least one polyester polyol based on betulin. The invention also relates to the use of the pressure-sensitive adhesive composition according to the invention, to a method for preparing the pressure-sensitive adhesive composition, and to a method for bonding at least two substrates. Finally, the invention relates to an article comprising the pressure-sensitive adhesive composition according to the invention.

Abstract: The present invention relates to a dimensionally stable adhesive compound which is formulated so as to be largely water- and solvent-free and can be brought into contact with the substrate to be bonded by being wiped on in the form of a thin adhesive film that is suitable in particular for bonding materials obtained from plant fibers. The organic constituent of the adhesive compound according to the invention consists predominantly of polyester polyurethanes, at least some of which are based on semi-crystalline polyester polyols. The invention also relates to a method for applying a tacky film to a planar substrate, preferably to paper, by wiping the adhesive compound onto the point of contact with the substrate.

Abstract: The present invention relates to a dimensionally stable adhesive compound which is formulated so as to be largely water- and solvent-free and can be brought into contact with the substrate to be bonded by being wiped on in the form of a thin adhesive film that is suitable in particular for bonding materials obtained from plant fibers. The organic constituent of the adhesive compound according to the invention consists predominantly of a mixture of polyether polyurethanes which are end-capped with at least two monohydric aliphatic alcohols of different chain lengths. The invention also relates to a method for applying a tacky film to a planar substrate, preferably to paper, by wiping the adhesive compound onto the point of contact with the substrate.

Abstract: The present invention relates to methods for producing at least one vinyl ether compound of formula (1) and to a vinyl ether compound of formula (1) preferably obtainable by the methods according to the invention. Furthermore, the present invention relates to a polymer obtainable by polymerizing the vinyl ether compound of formula (1) according to the invention, to an adhesive comprising the at least one polymer according to the invention and to the use of at least one vinyl ether compound of formula (I) according to the invention or at least one polymer according to the invention for the production of UV adhesives, cationic curings or 1-component or 2-component systems.

Abstract: The present invention relates to a bio-based acrylate monomer having a structure wherein R1 is H or —CH3, and wherein R2 is linear C1-C10 alkyl or branched C3-C10 alkyl.

Abstract: A specific polyamide polymer which is obtainable by two specific processes according to the invention. The invention further relates to the use of this polyamide polymer as a functional additive and to detergent compositions, cosmetic compositions, cleaning compositions and adhesive compositions including this polyamide polymer.

Abstract: The present invention refers to polyetherpolyols which are characterized by a low content of cyclic by-products as well as to a method for producing the polyetherpolyol and an adhesive composition comprising the same.

Abstract: The present invention refers to a polyesterpolyol which is obtained by reaction of at least one diol with at least one primary hydroxy group and at least one secondary hydroxy group with a saturated aliphatic dicarboxylic acid comprising a carbon chain of at least 12 carbon atoms. The invention further relates to an adhesive composition containing the polyesterpolyol, in particular a polyurethane adhesive composition.