Abstract: .alpha.-Substituted acrylic acid esters, their polymers and adhesives therefrom, and methods of synthesizing these compounds. The compounds of the invention are useful as intermediates in the synthesis of isocyanato esters and can be polymerized to form an effective, non-toxic adhesive. The method of the invention encompasses utilizing the adhesive composition in biomedical applications, such as joining live animal tissue. Other adhesive applications are contemplated for living tissue and inanimate objects. The compounds are also used as monomers which can be polymerized, used in conjunction with other monomers as adhesive compositions, cross-linking agents, dye acceptor additives to vinylic polymers and useful chemical intermediates. The method of the invention encompasses synthesizing the aforementioned monomers and intermediates. Methyl .alpha.-(ethoxycarbonamido)acrylate is synthesized from either DL-serine or methyl pyruvate.

Abstract: .alpha.-Substituted acrylic acid esters, their polymers and adhesives therefrom, and methods of synthesizing these compounds. The compounds of the invention are useful as intermediates in the synthesis of isocyanato esters and can be polymerized to form an effective, non-toxic adhesive. The method of the invention encompasses utilizing the adhesive composition in biomedical applications, such as joining live animal tissue. Other adhesive applications are contemplated for living tissue and inanimate objects. The compounds are also used as monomers which can be polymerized, used in conjunction with other monomers as adhesive compositions, cross-linking agents, dye acceptor additives to vinylic polymers and useful chemical intermediates. The method of the invention encompasses synthesizing the aformentioned monomers and intermediates. Methyl .alpha.-(ethoxycarbonamido)acrylate is synthesized from either DL-serine or methyl pyruvate.

Abstract: A novel coating for crop seeds is disclosed which serves to delay germination of the seeds after planting thereof for significant periods of time (such as over the winter months), and thereafter allows germination and plant development in the normal manner. The preferred seed coatings include a relatively rigid, dried residue of a synthetic resin (e.g., an epoxide) which is filled with a material such as a hydrate former which slowly reacts with moisture from the earth and expands, so that the resin coating will rupture and allow seed germination when soil and climatic conditions are conducive to plant growth. It has also been discovered that a preferred precoating comprising methyl cellulose serves to enhance plant growth and hardiness, particularly in the period shortly after emergence.

Abstract: A device for applying mastic material to the weld bead area of longitudinally welded pipe is the subject of this application. An extruder is mounted on a framework and receives mastic material in rope form from a bulk spool positioned above the extruder. The extruder incorporates heating elements to raise the temperature of the mastic. The extruder is provided with dual orifices for depositing a layer of the mastic material on either side of the weld bead of the pipe. A doctor blade is mounted to move along the pipe extending from the weld bead to a point on the pipe surface to smooth the mastic material which has been deposited. The doctor blade smooths the material evenly and causes it to form a bridge between the apex of the weld bead and a point on the pipe surface adjacent the base of the weld bead.

Abstract: A device and method for applying mastic material to the weld bead area of longitudinally welded pipe is the subject of this application. An extruder is mounted on a framework and receives mastic material in rope form from a bulk spool positioned above the extruder. The extruder incorporates heating elements to raise the temperature of the mastic. The extruder is provided with dual orifices for depositing a layer of the mastic material on either side of the weld bead of the pipe. A doctor blade is mounted to move along the pipe extending from the weld bead to a point on the pipe surface to smooth the mastic material which has been deposited. The doctor blade smooths the material evenly and causes it to form a bridge between the apex of the weld bead and a point on the pipe surface adjacent the base of the weld bead.