Abstract: Methods for cracking a hydrocarbon feed stream include contacting a hydrocarbon feed stream with a catalyst system in a catalytic cracking unit having a flowing gas stream to obtain a cracking product containing light olefins. The catalyst system includes at least a base catalyst. The base catalyst includes a pentasil zeolite. The pentasil zeolite includes from 0.01% to 5% by mass lithium atoms, as calculated on an oxide basis, based on the total mass of the pentasil zeolite. The flowing gas stream comprises hydrogen and, optionally, at least one additional carrier gas.

Abstract: A catalyst for dehydrogenation of hydrocarbons includes a support including zirconium oxide and Linde type L zeolite (L-zeolite). A concentration of the zirconium oxide in the catalyst is in a range of from 0.1 weight percent (wt. %) to 20 wt. %. The catalyst includes from 5 wt. % to 15 wt. % of an alkali metal or alkaline earth metal. The catalyst includes from 0.1 wt. % to 10 wt. % of tin. The catalyst includes from 0.1 wt. % to 8 wt. % of a platinum group metal. The alkali metal or alkaline earth metal, tin, and platinum group metal are disposed on the support.

Abstract: Methods for cracking a hydrocarbon feed stream include contacting a hydrocarbon feed stream with a catalyst system in a catalytic cracking unit having a flowing gas stream to obtain a cracking product containing light olefins. The catalyst system includes at least a base catalyst. The base catalyst includes a pentasil zeolite. The pentasil zeolite includes from 0.01% to 5% by mass lithium atoms, as calculated on an oxide basis, based on the total mass of the pentasil zeolite. The flowing gas stream comprises hydrogen and, optionally, at least one additional carrier gas.

Abstract: Systems and methods of enhancing oil recovery with an electrochemical apparatus include introducing the electrochemical apparatus into an injection well bore. The electrochemical apparatus includes an anode, a cathode and an interior wall, the interior wall defining an interior that contains both the anode and the cathode. The electrochemical apparatus is operated such that injection water of the injection well bore is introduced into the interior of the electrochemical apparatus. Electrical power is introduced to the electrochemical apparatus such that a portion of the injection water is converted into a product gas, the product gas including hydrogen gas and oxygen gas. The electrochemical apparatus is operated such that the product gas forms product gas bubbles and the product gas bubbles travel into a formation, where the product gas bubbles react with a reservoir hydrocarbon of the formation to form a production fluid that is produced through a production well bore.

Abstract: A catalyst for dehydrogenation of hydrocarbons includes a support including zirconium oxide and alumina. A concentration of the zirconium oxide in the catalyst is in a range of from 1 weight percent (wt. %) to 20 wt. %. The catalyst includes from 0.01 wt. % to 2 wt. % of an alkali metal or alkaline earth metal. The catalyst includes from 1 wt. % to 2 wt. % of tin. The catalyst includes from 0.1 wt. % to 2 wt. % of a platinum group metal. The alkali metal or alkaline earth metal, tin, and platinum group metal are disposed on the support.

Abstract: Olefins may be produced from C4-C6 saturated hydrocarbons by systems and methods comprising passing a feed comprising C4-C6 saturated hydrocarbons and hydrogen into a dehydrogenation unit to produce a dehydrogenation effluent, passing at least a portion of the dehydrogenation effluent into a hydrogenation unit to produce a hydrogenation effluent, and passing at least a portion of the hydrogenation effluent into a cracking unit to produce a cracking effluent comprising olefins. The dehydrogenation unit includes a dehydrogenation catalyst, the hydrogenation unit includes a hydrogenation catalyst, and the cracking unit includes a cracking catalyst.

Abstract: Olefins may be produced from C4-C6 saturated hydrocarbons by systems and methods comprising passing a feed comprising C4-C6 saturated hydrocarbons and hydrogen into a dehydrogenation unit to produce a dehydrogenation effluent, passing at least a portion of the dehydrogenation effluent into a hydrogenation unit to produce a hydrogenation effluent, and passing at least a portion of the hydrogenation effluent into a cracking unit to produce a cracking effluent comprising olefins. The dehydrogenation unit includes a dehydrogenation catalyst, the hydrogenation unit includes a hydrogenation catalyst, and the cracking unit includes a cracking catalyst.

Abstract: A catalyst for dehydrogenation of hydrocarbons includes a support including zirconium oxide and Linde type L zeolite (L-zeolite). A concentration of the zirconium oxide in the catalyst is in a range of from 0.1 weight percent (wt. %) to 20 wt. %. The catalyst includes from 5 wt. % to 15 wt. % of an alkali metal or alkaline earth metal. The catalyst includes from 0.1 wt. % to 10 wt. % of tin. The catalyst includes from 0.1 wt. % to 8 wt. % of a platinum group metal. The alkali metal or alkaline earth metal, tin, and platinum group metal are disposed on the support.

Abstract: Systems and methods of enhancing oil recovery with an electrochemical apparatus include introducing the electrochemical apparatus into an injection well bore. The electrochemical apparatus includes an anode, a cathode and an interior wall, the interior wall defining an interior that contains both the anode and the cathode. The electrochemical apparatus is operated such that injection water of the injection well bore is introduced into the interior of the electrochemical apparatus. Electrical power is introduced to the electrochemical apparatus such that a portion of the injection water is converted into a product gas, the product gas including hydrogen gas and oxygen gas. The electrochemical apparatus is operated such that the product gas forms product gas bubbles and the product gas bubbles travel into a formation, where the product gas bubbles react with a reservoir hydrocarbon of the formation to form a production fluid that is produced through a production well bore.

Abstract: A catalyst for dehydrogenation of hydrocarbons includes a support including zirconium oxide and Linde type L zeolite (L-zeolite). A concentration of the zirconium oxide in the catalyst is in a range of from 0.1 weight percent (wt. %) to 20 wt. %. The catalyst includes from 5 wt. % to 15 wt. % of an alkali metal or alkaline earth metal. The catalyst includes from 0.1 wt. % to 10 wt. % of tin. The catalyst includes from 0.1 wt. % to 8 wt. % of a platinum group metal. The alkali metal or alkaline earth metal, tin, and platinum group metal are disposed on the support.

Abstract: Systems and methods of enhancing oil recovery with an electrochemical apparatus include introducing the electrochemical apparatus into an injection well bore. The electrochemical apparatus includes an anode, a cathode and an interior wall, the interior wall defining an interior that contains both the anode and the cathode. The electrochemical apparatus is operated such that injection water of the injection well bore is introduced into the interior of the electrochemical apparatus. Electrical power is introduced to the electrochemical apparatus such that a portion of the injection water is converted into a product gas, the product gas including hydrogen gas and oxygen gas. The electrochemical apparatus is operated such that the product gas forms product gas bubbles and the product gas bubbles travel into a formation, where the product gas bubbles react with a reservoir hydrocarbon of the formation to form a production fluid that is produced through a production well bore.

Abstract: A catalyst for dehydrogenation of hydrocarbons includes a support including zirconium oxide and alumina. A concentration of the zirconium oxide in the catalyst is in a range of from 1 weight percent (wt. %) to 20 wt. %. The catalyst includes from 0.01 wt. % to 2 wt. % of an alkali metal or alkaline earth metal. The catalyst includes from 1 wt. % to 2 wt. % of tin. The catalyst includes from 0.1 wt. % to 2 wt. % of a platinum group metal. The alkali metal or alkaline earth metal, tin, and platinum group metal are disposed on the support.

Abstract: A catalyst for dehydrogenation of hydrocarbons includes a support including zirconium oxide and Linde type L zeolite (L-zeolite). A concentration of the zirconium oxide in the catalyst is in a range of from 0.1 weight percent (wt. %) to 20 wt. %. The catalyst includes from 5 wt. % to 15 wt. % of an alkali metal or alkaline earth metal. The catalyst includes from 0.1 wt. % to 10 wt. % of tin. The catalyst includes from 0.1 wt. % to 8 wt. % of a platinum group metal. The alkali metal or alkaline earth metal, tin, and platinum group metal are disposed on the support.

Abstract: Systems and methods of enhancing oil recovery with an electrochemical apparatus include introducing the electrochemical apparatus into an injection well bore. The electrochemical apparatus includes an anode, a cathode and an interior wall, the interior wall defining an interior that contains both the anode and the cathode. The electrochemical apparatus is operated such that injection water of the injection well bore is introduced into the interior of the electrochemical apparatus. Electrical power is introduced to the electrochemical apparatus such that a portion of the injection water is converted into a product gas, the product gas including hydrogen gas and oxygen gas. The electrochemical apparatus is operated such that the product gas forms product gas bubbles and the product gas bubbles travel into a formation, where the product gas bubbles react with a reservoir hydrocarbon of the formation to form a production fluid that is produced through a production well bore.