Abstract: A separator for a lithium secondary battery, including: a porous polymer substrate; and a crosslinked porous coating layer on at least one surface of the porous polymer substrate. The crosslinked porous coating layer includes inorganic particles and a crosslinkable binder polymer crosslinked through urethane crosslinking. The separator has improved heat resistance as compared to the conventional separators and maintains adhesion to an electrode. A lithium secondary battery including the separator is also disclosed.

Abstract: A separator for a secondary battery, including: a porous polymer substrate having a plurality of pores; and a porous coating layer on at least one surface of the porous polymer substrate, the porous coating layer including a plurality of inorganic particles, a binder polymer and a urethane bond-containing crosslinked polymer. The binder polymer and the urethane bond-containing crosslinked polymer are on at least a part of the surface of the inorganic particles to connect and fix the inorganic particles with one another. The urethane bond-containing crosslinked polymer has a weight average molecular weight of 100,000-5,000,000, and the urethane bond-containing crosslinked polymer is present in an amount of 6 parts by weight to 60 parts by weight based on 100 parts by weight of the total weight of the binder polymer and the urethane bond-containing crosslinked polymer.

Abstract: A separator for a secondary battery comprising a porous polymer substrate; a first layer on at least one surface of the porous polymer substrate, wherein the first layer includes inorganic particles and a nonparticulate acrylic polymer having a glass transition temperature of 15° C. or less, wherein the nonparticulate acrylic polymer connects and fixes the inorganic particles; and a second layer on an upper surface of the first layer, wherein the second layer includes a particulate acrylic polymer having a glass transition temperature of 20°° C. to 50° C. The separator for a secondary battery has good adhesion with the electrode and can solve the resistance problem in the presence of the inorganic particles.

Abstract: A method for manufacturing a separator for an electrochemical device which uses polyvinyl pyrrolidone (PVP) as a dispersing agent, and provides high dispersibility of particles and prevents aggregation of particles, even when inorganic particles having a small particle diameter is used in slurry for forming a porous coating layer. Therefore, the inorganic particles are distributed homogeneously in the porous coating layer of a finished separator. In addition, since PVP is used with a fluorinated binder resin, the separator shows improved peel strength and adhesion to an electrode. Further, a non-solvent ingredient for the fluorinated binder resin is used as a solvent for PVP, and a non-solvent ingredient for PVP is used as a solvent for the fluorinated binder resin.

Abstract: The present disclosure relates to an all-solid lithium secondary battery and a preparation method thereof, wherein the all-solid lithium secondary battery includes a positive electrode active material layer, a negative electrode active material layer, and a solid electrolyte layer disposed between the positive electrode active material layer and the negative electrode active material layer, wherein the negative electrode active material layer includes platelet carbon nanofibers (Platelet Carbon Nano Fiber, PCNF) and silver nanoparticles.

Abstract: A separator for a secondary battery comprising a porous polymer substrate; a first layer on at least one surface of the porous polymer substrate, wherein the first layer includes inorganic particles and a nonparticulate acrylic polymer having a glass transition temperature of 15° C. or less, wherein the nonparticulate acrylic polymer connects and fixes the inorganic particles; and a second layer on an upper surface of the first layer, wherein the second layer includes a particulate acrylic polymer having a glass transition temperature of 20° C. to 50° C. The separator for a secondary battery has good adhesion with the electrode and can solve the resistance problem in the presence of the inorganic particles.

Abstract: The present invention relates to a tandem warhead including a precursor neutralizing an explosive reactive armor, which is an additional armor of tanks, without detonating it and a main warhead configured to destroy a main armor, and more particularly to a non-initiating tandem warhead with a precursor forming powder jet against the explosive reactive armor, the powder jet leaving behind no residue of the precursor jet to maximize the penetration capability of the main warhead jet.

Abstract: A separator for a lithium secondary battery, including: a porous polymer substrate; and a crosslinked porous coating layer on at least one surface of the porous polymer substrate. The crosslinked porous coating layer includes inorganic particles and a crosslinkable binder polymer crosslinked through urethane crosslinking. The separator has improved heat resistance as compared to the conventional separators and maintains adhesion to an electrode. A lithium secondary battery including the separator is also disclosed.

Abstract: A separator and an electrochemical device including the same. The separator includes an adhesive layer including first adhesive resin particles having an average particle diameter corresponding to 0.8-3 times of an average particle diameter of the inorganic particles and second adhesive resin particles having an average particle diameter corresponding to 0.2-0.6 times of the average particle diameter of the inorganic particles, wherein the first adhesive resin particles are present in an amount of 30-90 wt % based on a total weight of the first adhesive resin particles and the second adhesive resin particles. The separator shows improved adhesion to an electrode and provides an electrochemical device with decreased increment in resistance after lamination with an electrode.

Abstract: A separator for an electrochemical device. The separator includes a porous coating layer formed from an acid, which is crosslinkable. As a result, the separator has increased heat resistance, safety and physical strength, shows improved peel strength between the porous substrate and the porous coating layer, and prevents separation of the inorganic particles from the porous coating layer. In addition, the separator shows an improved crosslinking degree so that the added amount of a crosslinkable binder resin may be reduced. Thus, it is possible to increase the added amount of a non-crosslinkable resin, inorganic particles, or both. Even when using a small amount of a crosslinkable binder resin, it is possible to provide both an effect of improving heat resistance and an effect of improving adhesion.

Abstract: A separator for an electrochemical device and an electrochemical device comprising the same. The separator comprises a porous polymer substrate and a heat resistant coating layer on at least one surface of the porous polymer substrate. The heat resistant coating layer is a porous polymer layer having pores, and comprises a polyvinyl pyrrolidone-based polymer and a polyvinylidene fluoride (PVDF)-based polymer.

Abstract: A separator with improved heat resistance and low resistance as well as Lami Strength that is equal or similar to that of the existing separator by using a predetermined amount of polyvinylpyrrolidone binder polymer relative to a polyvinylidene fluoride-based binder polymer, and a manufacturing method thereof.

Abstract: A separator for an electrochemical device, including: a porous polymer substrate having a plurality of pores; and a porous coating layer on at least one surface of the porous polymer substrate, wherein the porous coating layer comprises boehmite particles and a binder polymer, wherein the binder polymer is positioned on at least a part of the surface of the boehmite particles and connects and fixes the boehmite particles with one another. The boehmite particles have an average particle diameter of 2.0 ?m to 3.5 ?m and a specific surface area of 4.0 m2/g to 4.5 m2/g, and one side of the porous coating layer has a thickness of 2 ?m to 10 ?m.

Abstract: A separator including: a porous polymer substrate having a plurality of pores; and a porous coating layer on at least one surface of the porous polymer substrate. The porous coating layer comprises inorganic particles, core-shell type polymer particles having a core portion and a shell portion surrounding the core portion, and a binder polymer positioned on the whole or a part of the surface of the inorganic particles and core-shell type polymer particles to connect and fix the inorganic particles and core-shell type polymer particles with one another. The core portion has a glass transition temperature, Tg, higher than the shell portion in the core-shell type polymer particles. The ratio of the average diameter of the core-shell type polymer particles to the average diameter of the inorganic particles is 80% to 200%.

Abstract: The present disclosure relates to a separator for a secondary battery comprising a porous polymer substrate; a first layer formed on at least one surface of the porous polymer substrate, and comprising inorganic particles and a nonparticulate acrylic polymer having a glass transition temperature of 15° C. or less, wherein the nonparticulate acrylic polymer connects and fixes the inorganic particles; and a second layer formed on an upper surface of the first layer, and comprising a particulate acrylic polymer having a glass transition temperature of 20° C. to 50° C. The separator for a secondary battery according to the present disclosure has good adhesion with electrode and can solve the resistance problem in the presence of the inorganic particles.

Abstract: The present disclosure relates to an all-solid lithium secondary battery and a preparation method thereof, wherein the all-solid lithium secondary battery includes a positive electrode active material layer, a negative electrode active material layer, and a solid electrolyte layer disposed between the positive electrode active material layer and the negative electrode active material layer, wherein the negative electrode active material layer includes a carbon structure and silver nanoparticles, the carbon structure includes a structure in which a plurality of graphene sheets are connected to each other, and the plurality of graphene sheets include two or more graphene sheets having different plane directions.

Abstract: The present disclosure relates to an all-solid lithium secondary battery and a preparation method thereof, wherein the all-solid lithium secondary battery includes a positive electrode active material layer, a negative electrode active material layer, and a solid electrolyte layer disposed between the positive electrode active material layer and the negative electrode active material layer, wherein the negative electrode active material layer includes a carbon structure and silver nanoparticles, the carbon structure includes at least one hollow-type particle, and the hollow-type particle includes a hollow and a carbonaceous shell surrounding the hollow.

Abstract: An all-solid lithium secondary battery and a preparation method thereof are proved. The all-solid lithium secondary battery comprises a positive electrode active material layer, a negative electrode active material layer including graphitized platelet carbon nanofibers and silver nanoparticles, and a solid electrolyte layer between the positive electrode active material layer and the negative electrode active material layer.

Abstract: A separator for a lithium secondary battery, a method for manufacturing the same, and a secondary battery including the same. The separator includes a porous coating layer including a top layer, an intermediate layer, and a bottom layer. An amount of a particle-type binder polymer present in the top layer is larger than an amount of the particle-type binder polymer present in the bottom layer. The porous coating layer also includes a dispersant having a carboxyl group and a glycol group.

Abstract: A separator for a secondary battery, including: a porous polymer substrate having a plurality of pores; and a porous coating layer on at least one surface of the porous polymer substrate. The porous coating layer includes a plurality of inorganic particles and a urethane bond-containing crosslinked polymer. The urethane bond-containing crosslinked polymer is present partially or totally on surfaces of the inorganic particles wherein the inorganic particles are interconnected and fixed. The urethane bond-containing crosslinked polymer has a glass transition temperature (Tg) of ?15 to 32° C. A secondary battery including the separator is also disclosed.