Abstract: Proposed are a method and a system for separating a cathode material of a waste lithium secondary battery using an oxidation reaction of an anode material and a reduction reaction of the cathode material. When lithium is heated to a level where lithium can undergo an explosive reaction using the low-temperature pyrolysis system, the binder, the electrolyte, and the separator contained in the waste lithium secondary battery are gasified into syngas by the explosive reaction of lithium and the resulting syngas is removed. The reduction reaction of the cathode material and the oxidation reaction of the anode material are promoted by the continuous explosive reaction of lithium and the stirring action of the spiral. As a result, the black powder and the current collector mixture are extracted. Therefore, it is possible to improve the recovery rate of valuable metals to more than 97%, thereby improving recycling efficiency.

Abstract: Proposed is a separation method of black powder of an automotive waste secondary battery. More particularly, a method of separating a black powder (Ni, Co, Mn, Li C)+metal (Cu, Al) compound extracted from an automotive waste secondary battery through magnetic separation and particle separation is proposed. The separation method of black powder of an automotive waste secondary battery according to an embodiment of the present disclosure includes: (a) extracting black powder+metal compound from a waste secondary battery; (b) separating the black powder+metal compound into black powder and a metal compound through particle separation; and (c) separating Co and Ni, and non-extracted Mn, Li, and C by extracting Co and Ni from the black powder through gravity separation.