Abstract: Disclosed is a method using a metallocene catalyst system so as to control the polymer structure of a diene-modified polypropylene through process simplification, thereby being capable of preparing a hyperbranched polypropylene resin having a low gel content and improved melt strength. The present invention provides a method using a catalyst so as to polymerize propylene and a diene compound, thereby preparing a diene-modified polypropylene resin having a branching index of 0.95 or less, a gel content of 3 wt % or less and an advanced rheometric expansion system (ARES) melt strength of 5 g or more.

Abstract: Disclosed are a polyolefin having a high molecular weight by using a novel metallocene catalyst; a method for preparing the polyolefin by using the same; and a method for preparing an ethylene-propylene random copolymer having high molecular weight, high syndiotacticity and small crystal size, thereby providing injection molded articles with improved transparency.

Abstract: Disclosed are a novel metallocene catalyst and a method for preparing a polyolefin having a high molecular weight and a low melt index by using the same. The present invention provides a transition metal compound represented by formula 1.

Abstract: The present invention relates to a high-melt-strength polypropylene resin, and a preparation method therefor. A method for preparing the high-melt-strength polypropylene resin, according to the present invention, comprises the steps of: creating a polypropylene by polymerizing propylene monomers in the presence of a metallocene catalyst; and putting a diene compound and a comonomer into the created polypropylene and unreacted propylene monomers and reacting same, thereby forming a C40 or greater long-chain branch on the main chain of the polypropylene.

Abstract: Disclosed are a novel metallocene catalyst and a method for preparing a polyolefin having a high molecular weight and a low melt index by using the same. The present invention provides a transition metal compound represented by formula 1.

Abstract: Disclosed is a method using a metallocene catalyst system so as to control the polymer structure of a diene-modified polypropylene through process simplification, thereby being capable of preparing a hyperbranched polypropylene resin having a low gel content and improved melt strength. The present invention provides a method using a catalyst so as to polymerize propylene and a diene compound, thereby preparing a diene-modified polypropylene resin having a branching index of 0.95 or less, a gel content of 3 wt % or less and an advanced rheometric expansion system (ARES) melt strength of 5 g or more.

Abstract: Disclosed is a propylene-diene copolymer resin having excellent melt tension, with improved melt strength, high molecular weight and broad molecular weight distribution by using a specific metallocene catalyst system. The present invention provides a propylene-diene copolymer resin produced by polymerizing propylene and a diene compound of C4-C20 by using a metallocene catalyst system, wherein the propylene-diene copolymer resin has the melt index (2.16 kg load at 230° C.) of 0.1-100 g/10 min and the melt tension (advanced rheometric expansion system (ARES)) of 5-100 g.

Abstract: Disclosed are a catalyst having a high molecular weight by using a novel metallocene catalyst; a method for preparing a polyolefin by using the same; and a method for preparing an ethylene-propylene random copolymer having a high molecular weight and ethylene syndiotactic index and having a small crystal size, thereby having improved transparency during injection. The present invention provides a transition metal compound represented by chemical formula 1.

Abstract: Disclosed is a propylene-diene copolymer resin having excellent melt tension, with improved melt strength, high molecular weight and broad molecular weight distribution by using a specific metallocene catalyst system. The present invention provides a propylene-diene copolymer resin produced by polymerizing propylene and a diene compound of C4-C20 by using a metallocene catalyst system, wherein the propylene-diene copolymer resin has the melt index (2.16 kg load at 230° C.) of 0.1-100 g/10 min and the melt tension (advanced rheometric expansion system (ARES)) of 5-100 g.

Abstract: A method of three-dimensional (3D) printing, the method including: heating a composition comprising a polymer base including atactic polypropylene having a weight average molecular weight of 50,000 to 1,000,000, a density of 0.8 to 0.9 g/ml, and isotacticity (Pentad I.I, mmmm) of 5 to 20%, wherein a melting index (210° C., 2.16 kg) of the polymer base is 0.5-30 g/10 minutes; extruding the composition as a filament; and applying the extruded filament in one or more layers, wherein a solidification rate (measuring melting indexes (MI, 150° C., 10 kg)) of the filament is less than or equal to 2 g/10 minutes and a melting rate (measuring melting indexes (MI, 180° C., 10 kg)) of the filament is greater than or equal to 10 g/10 minutes, and hardness of the polymer base is less than or equal to Shore A 90.

Abstract: A method of three-dimensional (3D) printing, the method including: heating a composition comprising a polymer base including atactic polypropylene having a weight average molecular weight of 50,000 to 1,000,000, a density of 0.8 to 0.9 g/ml, and isotacticity (Pentad I.I, mmmm) of 5 to 20%, wherein a melting index (210° C., 2.16 kg) of the polymer base is 0.5-30 g/10 minutes; extruding the composition as a filament; and applying the extruded filament in one or more layers, wherein a solidification rate (measuring melting indexes (MI, 150° C., 10 kg)) of the filament is less than or equal to 2 g/10 minutes and a melting rate (measuring melting indexes (MI, 180° C., 10 kg)) of the filament is greater than or equal to 10 g/10 minutes, and hardness of the polymer base is less than or equal to Shore A 90.

Abstract: Disclosed are a composition for 3D printer filaments satisfying requirements as a 3D printing material and a filament for a 3D printer manufactured using the same. A composition for 3D printer filaments including a polymer base containing atactic polypropylene having a weight average molecular weight of 50,000 to 1,000,000, a density of 0.8 to 0.9 g/ml, and isotacticity (Pentad I.I, mmmm) of 5 to 20%. The melting index (210° C., 2.16 kg) of the polymer base is 0.5-30 g/10 minutes, and a filament for a 3D printer manufactured using the same are provided.