Abstract: A method of electrochemical redox refrigeration includes inducing a flow of an electrochemical refrigerant that is in contact with a first electrode to a second electrode; applying an electrical potential difference between the first electrode and the second electrode, wherein the electrochemical refrigerant is oxidized at one of the first electrode and second electrode and reduced at another of the first electrode and second electrode; wherein the first electrode is at least partially thermally isolated from Joule heating in the electrochemical refrigerant and from activation losses in the second electrode by an action of the flow of the electrochemical refrigerant.

Abstract: Systems, methods, and apparatus configured for the mitigation of hydrogen accumulation within electrochemical systems are generally described. The systems, methods, and apparatus described herein can be, according to certain embodiments, configured to be part of an electrochemical system in which hydrogen is generated (e.g., as a reaction byproduct).

Abstract: A method of electrochemical redox refrigeration includes inducing a flow of an electrochemical refrigerant that is in contact with a first electrode to a second electrode; applying an electrical potential difference between the first electrode and the second electrode, wherein the electrochemical refrigerant is oxidized at one of the first electrode and second electrode and reduced at another of the first electrode and second electrode; wherein the first electrode is at least partially thermally isolated from Joule heating in the electrochemical refrigerant and from activation losses in the second electrode by an action of the flow of the electrochemical refrigerant.

Abstract: A direct thermoelectrochemical heat-to-electricity converter includes two electrochemical cells at hot and cold temperatures, each having a gas-impermeable, electron-blocking membrane capable of transporting an ion I, and a pair of electrodes on opposite sides of the membrane. Two closed-circuit chambers A and B each includes a working fluid, a pump, and a counter-flow heat exchanger. The chambers are connected to opposite sides of the electrochemical cells and carry their respective working fluids between the two cells. The working fluids are each capable of undergoing a reversible redox half-reaction of the general form R?O+I+e?, where R is a reduced form of an active species in a working fluid and O is the oxidized forms of the active species. One of the first pair of electrodes is electrically connected to one the second pair of electrodes via an electrical load to produce electricity.

Abstract: Waste management in electrochemical systems, such as electrochemical systems in which an electrochemically active material comprising aluminum is employed, is generally described.

Abstract: A method for collecting aluminate waste. The method includes transporting a super-saturated aqueous aluminate stream through a non-electrode open cell foam such that aluminum hydroxide that is the product of an electricity-generating electrochemical reaction between aluminum and water is precipitated on the non-electrode open cell foam, wherein at least 50% wt of the precipitation occurs within the non-electrode open cell foam instead of on an electrode.

Abstract: Waste management in electrochemical systems, such as electrochemical systems in which an electrochemically active material comprising aluminum is employed, is generally described.

Abstract: Waste management in electrochemical systems, such as electrochemical systems in which an electrochemically active material comprising aluminum is employed, is generally described.

Abstract: Waste management in electrochemical systems, such as electrochemical systems in which an electrochemically active material comprising aluminum is employed, is generally described.

Abstract: Waste management in electrochemical systems, such as electrochemical systems in which an electrochemically active material comprising aluminum is employed, is generally described.

Abstract: A direct thermoelectrochemical heat-to-electricity converter includes two electrochemical cells at hot and cold temperatures, each having a gas-impermeable, electron-blocking membrane capable of transporting an ion I, and a pair of electrodes on opposite sides of the membrane. Two closed-circuit chambers A and B each includes a working fluid, a pump, and a counter-flow heat exchanger. The chambers are connected to opposite sides of the electrochemical cells and carry their respective working fluids between the two cells. The working fluids are each capable of undergoing a reversible redox half-reaction of the general form R?O+I+e?, where R is a reduced form of an active species in a working fluid and O is the oxidized forms of the active species. One of the first pair of electrodes is electrically connected to one the second pair of electrodes via an electrical load to produce electricity.

Abstract: Systems, methods, and apparatus configured for the mitigation of hydrogen accumulation within electrochemical systems are generally described. The systems, methods, and apparatus described herein can be, according to certain embodiments, configured to be part of an electrochemical system in which hydrogen is generated (e.g., as a reaction byproduct).

Abstract: Aluminum may be used as a fuel source to power small vehicles, unmanned vehicles or underwater vehicles, other small robotics, backup or regular underwater power sources (e.g., for oil rigs), or as an emergency power source in flooded or disaster areas. Reactors are described that harvest energy produced by the exothermic oxidative reaction of aluminum or an aluminum alloy with water, with the assistance of liquid gallium as a depassivating agent.