Abstract: Methods of forming a metal silicide region in an integrated circuit are provided herein. In some embodiments, a method of forming a metal silicide region in an integrated circuit includes forming a silicide-resistive region in a first region of a substrate, the substrate having the first region and a second region, wherein a mask layer is deposited atop the substrate and patterned to expose the first region; removing the mask layer after the silicide-resistive region is formed in the first region of the substrate; depositing a metal-containing layer on a first surface of the first region and a second surface of the second region; and annealing the deposited metal-containing layer to form a first metal silicide region in the second region.

Abstract: Methods for forming a device on a substrate are provided herein. In some embodiments, a method of forming a device on a substrate may include providing a substrate having a partially fabricated first device disposed on the substrate, the first device including a first film stack comprising a first dielectric layer and a first high-k dielectric layer disposed atop the first dielectric layer; depositing a first metal layer atop the first film stack; and modifying a first upper surface of the first metal layer to adjust a first threshold voltage of the first device, wherein the modification of the first upper surface does not extend through to a first lower surface of the first metal layer.

Abstract: Methods of forming a metal silicide region in an integrated circuit are provided herein. In some embodiments, a method of forming a metal silicide region in an integrated circuit includes forming a silicide-resistive region in a first region of a substrate, the substrate having the first region and a second region, wherein a mask layer is deposited atop the substrate and patterned to expose the first region; removing the mask layer after the silicide-resistive region is formed in the first region of the substrate; depositing a metal-containing layer on a first surface of the first region and a second surface of the second region; and annealing the deposited metal-containing layer to form a first metal silicide region in the second region.

Abstract: Methods for forming a device on a substrate are provided herein. In some embodiments, a method of forming a device on a substrate may include providing a substrate having a partially fabricated first device disposed on the substrate, the first device including a first film stack comprising a first dielectric layer and a first high-k dielectric layer disposed atop the first dielectric layer; depositing a first metal layer atop the first film stack; and modifying a first upper surface of the first metal layer to adjust a first threshold voltage of the first device, wherein the modification of the first upper surface does not extend through to a first lower surface of the first metal layer.

Abstract: A novel design of an oxidation mask for improved control of birds beak and more specifically for tailoring and smoothing the field oxide isolation profile in the vicinity of the birds beak. The mask design is particularly advantageous for narrow field isolation spacings found in sub half-micron integrated circuit technology. The mask uses a thin silicon nitride foot along its lower edge to allow nominal expansion of the oxide during the early stages of oxidation, thereby permitting in-situ stress relief as well as a smoothing of the oxide profile. A cantilevered portion of a second, thicker silicon nitride layer suppresses the upward movement of the flexible foot during the later stages of the oxidation when the growth rate has slowed, thereby inhibiting the growth of the birds beak. Shear stresses responsible for dislocation generation are reduced as much as fifty fold. This stress reduction is accompanied by an improvement in surface topography as well as suppression of the narrow oxide thinning effect.

Abstract: A method for making self-aligned sub-micrometer bipolar transistors and FETs on a substrate for BiFET and BiCMOS circuits was achieved using a novel LOCOS structure as a self-aligned implant mask. This LOCOS structure uses a silicon nitride mask comprised of stripes with well defined widths and spacings to form a punchthrough oxide mask of varying thicknesses over the emitter, base, and collector of the bipolar transistor, while providing a thick field oxide elsewhere on the substrate. The oxide mask serves as a self-aligned implant mask for implanting the emitter, base, and collector of the bipolar transistor. The nitride mask can be patterned concurrently to form an implant mask for the FET. A series of ion implants is then used to form the emitter, base, and collector without requiring separate photoresist masks. An array of nitride stripes with well defined widths and spacings can be used to make larger transistors, such as bipolar power transistors.

Abstract: A novel design of an oxidation mask for improved control of birds beak and more specifically for tailoring and smoothing the field oxide isolation profile in the vicinity of the birds beak. The mask design is particularly advantageous for narrow field isolation spacings found in sub half-micron integrated circuit technology. The mask uses a thin tapered silicon nitride foot along its lower edge to allow nominal expansion of the oxide during the early stages of oxidation, thereby permitting in-situ stress relief as well as a smoothing of the oxide profile. The taper of the foot provides a gradual increase in mask stiffness as oxidation proceeds under the mask edge, allowing greatest flexibility during the early rapid growth period followed by increasing stiffness during the later stages when the growth rate has slowed, thereby inhibiting the penetration of birds beak. Shear stresses responsible for dislocation generation are reduced by as much as fifty fold.

Abstract: A novel design of an oxidation mask for improved control of birds beak and more specifically for tailoring and smoothing the field oxide isolation profile in the vicinity of the birds beak. The mask design is particularly advantageous for narrow field isolation spacings found in sub half-micron integrated circuit technology. The mask uses a thin tapered silicon nitride foot along its lower edge to allow nominal expansion of the oxide during the early stages of oxidation, thereby permitting in-situ stress relief as well as a smoothing of the oxide profile. The taper of the foot provides a gradual increase in mask stiffness as oxidation proceeds under the mask edge, allowing greatest flexibility during the early rapid growth period followed by increasing stiffness during the later stages when the growth rate has slowed, thereby inhibiting the penetration of birds beak. Shear stresses responsible for dislocation generation are reduced by as much as fifty fold.

Abstract: A method for forming a sub-quarter micron MOSFET having an LDD structure is described. An active area is provided in a semiconductor substrate separated from other active areas by isolation regions. Ions are implanted into the semiconductor substrate in the active area wherein a heavily doped region is formed adjacent to the surface of the semiconductor substrate and wherein a lightly doped region is formed underlying the heavily doped region. A first dielectric layer is deposited overlying the semiconductor substrate in the active area. The first dielectric layer is etched away to form an opening to the semiconductor substrate. The semiconductor substrate within the opening is etched through to form a partial trench in the semiconductor substrate. Spacers are formed on the sidewalls of the first dielectric layer within the opening. A layer of conducting material is deposited over the first dielectric layer and the spacers and within the opening.

Abstract: A method for making self-aligned sub-micrometer bipolar transistors and FETs on a substrate for BiFET and BiCMOS circuits was achieved using a novel LOCOS structure as a self-aligned implant mask. This LOCOS structure uses a silicon nitride mask comprised of stripes with well defined widths and spacings to form a punchthrough oxide mask of varying thicknesses over the emitter, base, and collector of the bipolar transistor, while providing a thick field oxide elsewhere on the substrate. The oxide mask serves as a self-aligned implant mask for implanting the emitter, base, and collector of the bipolar transistor. The nitride mask can be patterned concurrently to form an implant mask for the FET. A series of ion implants is then used to form the emitter, base, and collector without requiring separate photoresist masks. An array of nitride stripes with well defined widths and spacings can be used to make larger transistors, such as bipolar power transistors.

Abstract: A method to form shallow trench isolation structures with improved isolation fill and surface planarity is described. A pad oxide layer is provided over the surface of a semiconductor substrate. A silicon nitride layer is deposited overlying the pad oxide layer. A thin oxide layer is deposited overlying the silicon nitride layer. An isolation trench is etched through the thin oxide layer, the nitride layer, and the pad oxide layer and into the substrate. The silicon nitride layer exposed within the trench is etched to form a lateral undercut leaving a projection of the thin oxide layer and exposing a portion of the underlying pad oxide layer. The thin oxide layer and the exposed portion of the pad oxide layer are etched away thereby exposing portions of the surface of the substrate. A liner oxide is grown on the exposed portions of the semiconductor substrate within the isolation trench and on the surface of the substrate.

Abstract: A method for making self-aligned sub-micrometer bipolar transistors and FETs on a substrate for BiFET and BiCMOS circuits was achieved using a novel LOCOS structure as a self-aligned implant mask. This LOCOS structure uses a silicon nitride mask comprised of stripes with well defined widths and spacings to form a punchthrough oxide mask of varying thicknesses over the emitter, base, and collector of the bipolar transistor, while providing a thick field oxide elsewhere on the substrate. The oxide mask serves as a self-aligned implant mask for implanting the emitter, base, and collector of the bipolar transistor. The nitride mask can be patterned concurrently to form an implant mask for the FET. A series of ion implants is then used to form the emitter, base, and collector without requiring separate photoresist masks. An array of nitride stripes with well defined widths and spacings can be used to make larger transistors, such as bipolar power transistors.

Abstract: A method for making self-aligned sub-micrometer bipolar transistors and FETs on a substrate for BiFET and BiCMOS circuits was achieved using a novel LOCOS structure as a self-aligned implant mask. This LOCOS structure uses a silicon nitride mask comprised of stripes with well defined widths and spacings to form a punchthrough oxide mask of varying thicknesses over the emitter, base, and collector of the bipolar transistor, while providing a thick field oxide elsewhere on the substrate. The oxide mask serves as a self-aligned implant mask for implanting the emitter, base, and collector of the bipolar transistor. The nitride mask can be patterned concurrently to form an implant mask for the FET. A series of ion implants is then used to form the emitter, base, and collector without requiring separate photoresist masks. An array of nitride stripes with well defined widths and spacings can be used to make larger transistors, such as bipolar power transistors.

Abstract: A method is described for forming MOSFETs with shallow trench isolation wherein the abrupt corners introduced by anisotropically etching the silicon trenches are modified by an oxidation step which rounds off the corners and also reduces the effect of tensile stresses caused by the densified trench filler material. The method selectively exposes the corner regions to an oxidation whereby the formation of an oxide birdsbeak modulates the corners and introduces a compressive stress component in the corner region. Several variations of the procedure are disclosed, including embodiments wherein birdsbeaks extending in both a vertical and horizontal directions from the corners are employed. The channel and gate oxide edges of MOSFETs extend to these corners. By attenuating the abrupt corners and reducing the mechanical stresses, gate oxide integrity is improved and anomalous sub-threshold currents of MOSFETs formed are abated.

Abstract: A method for forming a sub-quarter micron MOSFET having an LDD structure is described. An active area is provided in a semiconductor substrate separated from other active areas by isolation regions. Ions are implanted into the semiconductor substrate in the active area wherein a heavily doped region is formed adjacent to the surface of the semiconductor substrate and wherein a lightly doped region is formed underlying the heavily doped region. A first dielectric layer is deposited overlying the semiconductor substrate in the active area. The first dielectric layer is etched away to form an opening to the semiconductor substrate. The semiconductor substrate within the opening is etched through to form a partial trench in the semiconductor substrate. Spacers are formed on the sidewalls of the first dielectric layer within the opening. A layer of conducting material is deposited over the first dielectric layer and the spacers and within the opening.

Abstract: The invention is an improved process for forming isolations of uniform thickness in narrow and wide trenches. The process begins by forming a pad layer on a semiconductor substrate. A first barrier layer is formed on the pad layer. The first barrier layer and pad layer are patterned forming openings, thereby exposing the substrate surface. The substrate is then etched through the openings to form shallow trenches in the substrate. The trenches generally falling into two ranges of width: narrow trenches having widths in the range between 0.3 .mu.m and 1.0 .mu.m; and wide trenches having widths greater than 1.0 .mu.m. A thin oxide film is grown on the sidewalls and bottoms of the trenches. A gap-fill dielectric layer is formed on the thin oxide film. A polysilicon layer is grown on the gap-fill dielectric layer. The polysilicon layer acts as a stop during CMP, providing additional protection of the gap-fill dielectric layer in the wide trenches. A planarizing material layer is formed on the polysilicon layer.

Abstract: A novel design of an oxidation mask for improved control of birds beak and more specifically for tailoring and smoothing the field oxide isolation profile in the vicinity of the birds beak. The mask design is particularly advantageous for narrow field isolation spacings found in sub half-micron integrated circuit technology. The mask uses a thin silicon nitride foot along its lower edge to allow nominal expansion of the oxide during the early stages of oxidation, thereby permitting in-situ stress relief as well as a smoothing of the oxide profile. A cantilevered portion of a second, thicker silicon nitride layer suppresses the upward movement of the flexible foot during the later stages of the oxidation when the growth rate has slowed, thereby inhibiting the growth of the birds beak. Shear stresses responsible for dislocation generation are reduced as much as fifty fold. This stress reduction is accompanied by an improvement in surface topography as well as suppression of the narrow oxide thinning effect.

Abstract: A method for making self-aligned sub-micrometer bipolar transistors and FETs on a substrate for BiFET and BiCMOS circuits was achieved using a novel LOCOS structure as a self-aligned implant mask. This LOCOS structure uses a silicon nitride mask comprised of stripes with well defined widths and spacings to form a punchthrough oxide mask of varying thicknesses over the emitter, base, and collector of the bipolar transistor, while providing a thick field oxide elsewhere on the substrate. The oxide mask serves as a self-aligned implant mask for implanting the emitter, base, and collector of the bipolar transistor. The nitride mask can be patterned concurrently to form an implant mask for the FET. A series of ion implants is then used to form the emitter, base, and collector without requiring separate photoresist masks. An array of nitride stripes with well defined widths and spacings can be used to make larger transistors, such as bipolar power transistors.

Abstract: The present invention provides a method of fabricating a field oxide layer having a reduced bird's beak using a nitride foot 70 and a first field oxide region 80A as a N.sub.2 implant mask. The N.sub.2 implant suppresses oxide growth around the perimeter of the field oxide and reduces the bird's beak. A pad oxide layer 20 and a first nitride layer 30 are formed over a substrate. The first nitride layer is partially etched back forming a residual first nitride layer in the areas where the field oxide will be formed. A polysilicon spacer is formed on the sidewalls of the first nitride layer and over a portion of the residual first nitride layer. The residual first nitride layer 31 is etched using the spacer 60 as an etch mask forming a nitride foot 70. The substrate is thermally oxidized in the field oxide area using the first nitride layer and the foot 60 as an oxidation barrier forming a first field oxide layer 80A having a bird's beak 85.

Abstract: The invention is a process for filling narrow isolation trenches with thermal oxide using a nitride spacer and a second trench etch. The method begins by providing forming a pad oxide layer 20 and a first nitride layer 30 over a substrate. A first opening is formed in the pad oxide layer 20 and first nitride layer 30. The substrate is then etched through the first opening forming a first trench 40 in the substrate. A thin oxide film 50 is then grown over the substrate in the bottom and sidewalls of the first trench 40. Nitride spacers 60 are grown over the sidewalls of the first trench and over the thin oxide layer 40 on the sidewalls of the trench. A portion of the thin oxide film 50 on the bottom of the trench is etched. The substrate in the bottom of the first trench is etched forming a second trench 70. The etch exposes portions of the substrate on the bottom of the deeper second trench.