Abstract: The present invention relates to a process for the preparation of a solution comprising a first peroxy acid comprising performic acid and a second peroxy acid, said process comprising forming a carboxylic acid solution comprising a first carboxylic acid comprising formic acid, a second carboxylic acid and hydrogen peroxide, wherein the amount of formic acid is from 0.5 to 20% by weight of the amount of the second carboxylic acid, and allowing the components to react to form a solution comprising performic acid and said second peroxy acid, the amount of peroxy acids being at least 5% by weight. The invention also relates to a storable solution comprising performic acid and said second peroxy acid. The solution can be used as a disinfecting agent for controlling micro-organisms.

Abstract: The invention relates to a stabilizing composition comprising following components (A) a polymer having the following formula: wherein R1 is a hydrogen atom or an alkyl group containing 1 to 12 carbon atoms, R2 is —COOM or —CH2COOM, M is a hydrogen atom, an alkali metal ion, an alkaline earth metal ion, an ammonium ion or a mixture thereof, n, m and k are molar ratios of corresponding monomers, wherein n is 0 to 0.95, m is 0.05 to 0.9, and k is 0 to 0.8, and (n+m+k) equals 1, and the weight average molecular weight is between 500 and 20,000,000 g/mol, (B) a chelating agent, (C) a poly-alpha-hydroxyacrylic acid or an alkaline salt thereof or the corresponding polylactone thereof, and (D) optionally a polycarboxylic acid polymer or an alkaline salt thereof. The invention also relates to a process for the treatment of a fiber material.

Abstract: The present invention relates to a stabilizing composition comprising following components (A) a polymer having following formula wherein R1 is a hydrogen atom or an alkyl group containing 1 to 12 carbon atoms, R2 is —COOM or —CH2COOM, M is a hydrogen atom, an alkali metal ion, an alkaline earth metal ion, an ammonium ion or a mixture thereof, n, m and k are molar ratios of corresponding monomers, wherein n is 0 to 0.95, m is 0.05 to 0.9, and k is 0 to 0.8, and (n+m+k) equals 1, and the weight average molecular weight is between 500 and 20,000,000 g/mol, (B) a chelating agent, and (C) an alkaline earth metal compound. The invention also relates to a process for the treatment of a fiber material.

Abstract: The invention relates to a process for the treatment of a fibre material comprising the step of contacting the fibre material in an aqueous medium with a chelating agent and a polymer having following general formula wherein R1 is a hydrogen atom or an alkyl group containing 1 to 12 carbon atoms, R2 is —COOM or —CH2COOM, M is a hydrogen atom, an alkali metal ion, an alkaline earth metal ion, an ammonium ion or a mixture thereof, n, m and k are molar ratios of corresponding monomers, wherein n is 0 to 0.95, m is 0.05 to 0.9, and k is 0 to 0.8, and (n+m+k) equals 1, and the weight average molecular weight is between 500 and 20,000,000 g/mol. The invention also relates to a composition comprising a chelating agent and the above polymer.

Abstract: The present invention relates to a polymer composition for peroxide bleaching of a cellulosic fiber material, said composition being in the form of a stable aqueous polymer solution obtained by bringing in an aqueous medium a first polymer (A) comprising a partly or totally acidic homopolymer of acrylic acid, methacrylic acid or maleic acid, or a copolymer of acrylic acid and/or methacrylic acid with an unsaturated dicarboxylic acid, into contact with a second polymer (B) comprising a polylactone of a poly-alfa-hydroxyacrylic acid in solid form or as a moist powder or as a slurry, said polymer solution having a pH of at most 5. The invention also relates to peroxide bleaching processes.

Abstract: The present invention relates to a process for bleaching a cellulosic fibre material with a peroxide compound in an aqueous alkaline medium, comprising a bleaching step wherein: a) a first polymer (A) comprising a homopolymer of acrylic acid, methacrylic acid or maleic acid, or a copolymer of acrylic acid and/or methacrylic acid with an unsaturated dicarboxylic acid, and a solution of a second polymer (B) comprising a poly-alpha-hydroxyacrylic acid or a salt thereof, are added to a cellulosic fibre material, and b) thereafter adding a peroxide compound and an alkaline substance and carrying out the bleaching.

Abstract: The invention relates to a stabilizing composition comprising following components (A) a polymer having following formula wherein R1 is a hydrogen atom or an alkyl group containing 1 to 12 carbon atoms, R2 is —COOM or —CH2COOM, M is a hydrogen atom, an alkali metal ion, an alkaline earth metal ion, an ammonium ion or a mixture thereof, n, m and k are molar ratios of corresponding monomers, wherein n is 0 to 0.95, m is 0.05 to 0.9, and k is 0 to 0.8, and (n+m+k) equals 1, and the weight average molecular weight is between 500 and 20,000,000 g/mol, (B) a chelating agent, (C) a poly-alpha-hydroxyacrylic acid or an alkaline salt thereof or the corresponding polylactone thereof, and (D) optionally a polycarboxylic acid polymer or an alkaline salt thereof. The invention also relates to a process for the treatment of a fiber material.

Abstract: The present invention relates to a polymer composition for peroxide bleaching of a cellulosic fibre material, said composition being in the form of a stable aqueous polymer solution obtained by bringing in an aqueous medium a first polymer (A) comprising a partly or totally acidic homopolymer of acrylic acid, methacrylic acid or maleic acid, or a copolymer of acrylic acid and/or methacrylic acid with an unsaturated dicarboxylic acid, into contact with a second polymer (B) comprising a polylactone of a poly-alfa-hydroxyacrylic acid in solid form or as a moist powder or as a slurry, said polymer solution having a pH of at most 5. The invention also relates to peroxide bleaching processes.

Abstract: The present invention relates to a polymer composition for peroxide bleaching of a cellulosic fiber material, said composition being in the form of a stable aqueous polymer solution obtained by bringing in an aqueous medium a first polymer (A) comprising a partly or totally acidic homopolymer of acrylic acid, methacrylic acid or maleic acid, or a copolymer of acrylic acid and/or methacrylic acid with an unsaturated dicarboxylic acid, into contact with a second polymer (B) comprising a polylactone of a poly-alfa-hydroxyacrylic acid in solid form or as a moist powder or as a slurry, said polymer solution having a pH of at most 8, The invention also relates to peroxide bleaching processes.

Abstract: The present invention relates to a stabilizing composition comprising following components (A) a polymer having following formula wherein R1 is a hydrogen atom or an alkyl group containing 1 to 12 carbon atoms, R2 is —COOM or —CH2COOM, M is a hydrogen atom, an alkali metal ion, an alkaline earth metal ion, an ammonium ion or a mixture thereof, n, m and k are molar ratios of corresponding monomers, wherein n is 0 to 0.95, m is 0.05 to 0.9, and k is 0 to 0.8, and (n+m+k) equals 1, and the weight average molecular weight is between 500 and 20,000,000 g/mol, (B) a chelating agent, and (C) an alkaline earth metal compound. The invention also relates to a process for the treatment of a fibre material.

Abstract: The present invention relates to a process for bleaching a cellulosic fibre material with a peroxide compound in an aqueous alkaline medium, comprising a bleaching step wherein: a) a first polymer (A) comprising a homopolymer of acrylic acid, methacrylic acid or maleic acid, or a copolymer of acrylic acid and/or methacrylic acid with an unsaturated dicarboxylic acid, and a solution of a second polymer (B) comprising a poly-alfa-hydroxyacrylic acid or a salt thereof, are added to a cellulosic fibre material, and b) thereafter adding a peroxide compound and an alkaline substance and carrying out the bleaching.

Abstract: The present invention relates to a polymer composition for peroxide bleaching of a cellulosic fibre material, said composition being in the form of a stable aqueous polymer solution obtained by bringing in an aqueous medium a first polymer (A) comprising a partly or totally acidic homopolymer of acrylic acid, methacrylic acid or maleic acid, or a copolymer of acrylic acid and/or methacrylic acid with an unsaturated dicarboxylic acid, into contact with a second polymer (B) comprising a po9lylactone of a poly-alfa-hydroxyacrylic acid in solid form or as a moist powder or as a slurry, said polymer solution having a pH of at most 8, The invention also relates to peroxide bleaching processes.

Abstract: Methods for the preparation of an N-alkyl-N-bis-(2-( 1,2-dicarboxy-ethoxy)-ethyl)-amine derivative are described, products of the methods as well as uses of the products. The derivative is prepared by reacting an alkali or earth alkali metal salt of maleic acid with an N-substituted diethanolamine, the reaction taking place with the two ethanol groups of the diamine while the substituent group bound to the N atom remains unaffected, or alternatively by first reacting diethanolamine with an alkali or earth alkali metal salt of maleic acid to yield N-bis-(2-(1,2-dicarboxy-ethoxy)-ethyl)-amine, which is then reacted with a substitution reagent to obtain the final product. The derivative is useful as chelating agents, e.g., in the bleaching of chemical or mechanical pulp or in textile bleaches containing hydrogen peroxide or a peracid, or as a calcium binder in detergents and cleaning agents.

Abstract: The invention relates to a process for the bleaching of chemical pulp, wherein the pulp is delignified and/or bleached with chlorine dioxide or with a combination of chlorine dioxide and a per-compound, and additionally the pulp is chelated in order to bind heavy metals, such as Fe, Mn and/or Cu, to a chelate complex. The chelate complex is selected from the group made up of N-bis-[(1,2-dicarboxylethoxy)-ethyl]-amine, N-bis[(1,2-dicarboxylethoxy)-ethyl]-aspartic acid and N-tris-[(1,2-dicarboxylethoxy)-ethyl]-amine, and the alkali metal and earth-alkali metal salts of these, and the chelating treatments are carried out simultaneously by combining the chelating chemical with the pulp in the same bleaching stage as chlorine dioxide.

Abstract: A process for the preparation of a stabilized sodium carbonate peroxyhydrate, in which an aqueous solution of sodium sulphate and a chelating agent is applied to granules of sodium carbonate peroxyhydrate, and the solution is allowed to dry, forming coated granules having a coating layer of sodium sulphate and the chelating agent on the granules. The chelating agent is selected from the group consisting of (poly)aminophosphonic acid derivatives, (poly)aminocarboxylic acid derivatives, and N-bis- and tris-[(1,2-dicarboxy-ethoxy)ethyl]amine derivatives. The stabilized sodium carbonate peroxyhydrate may be prepared by spraying the aqueous solution of sodium sulphate and the chelating agent onto granules of sodium carbonate peroxyhydrate in a fluidized bed.

Abstract: A process for the bleaching of chemical pulp, in which process the pulp is delignified with a peracid and additionally the pulp is chelated in order to bind heavy metals, such as Fe, Mn and/or Cu, into a chelate complex. According to the invention, the chelating is carried out using a chemical which has been selected from a group consisting of N-bis-((1,2-dicarboxy-ethoxy)-ethyl)-amine, N-bis-((1,2-dicarboxy-ethoxy)-ethyl)-aspartic acid and N-tris-((1,2-dicarboxy-ethoxy)-ethyl)-amine, as well as the alkali metal and earth-alkali metal salts thereof, and the peracid and chelating treatments are carried out simultaneously by combining the peracid and the said chelating chemical in the same solution phase. In the bleaching sequence the treatment according to the invention may follow, for example, an ozone delignification and precede an alkaline peroxide step, and in the latter case a magnesium compound, such as MgSO4, may be added to the pulp before the alkali step.

Abstract: The invention relates to a stable sodium carbonate peroxyhydrate which is suited for use together with crystalline synthetic silicate-based detergents and is coated with an alkali metal sulfate and a copolymer or terpolymer of vinyl pyrrolidone.

Abstract: The invention relates to N-bis- or N-tris-[(1,2-dicarboxy-ethoxy)-ethyl]-amine derivatives having the formula (I) ##STR1## and R.sub.2 is hydrogen, an alkali metal or an earth-alkali metal. The invention also relates to a method for preparing the same and their use as chelating agents.

Abstract: Furfuryl acetate is reacted at 0.degree.-20.degree. C with a mixture containing strong nitric acid and less than 7 mole, preferably less than 5 mole, acetic anhydride per 1 mole furfuryl acetate, in order to produce an intermediate of nitration, whereafter water is added and the aqueous solution is neutralized to a pH of 4.7-6.5 and finally the mixture is heated to 40.degree.-60.degree. C.

Abstract: Furfuryl alcohol is esterified by means of an aliphatic anhydride or its halogen derivative using aliphatic, tertiary amines as catalysts.