Abstract: Articles containing metal, hard metal, cermet or ceramic and coated with a hard material, and a method for producing same. The hard material layers can be used as anti-wear layers for cutting tools, as protective layers for turbine blades, or as diffusion barriers in microelectronics. The hard material layers exhibit a high hardness, high oxidation resistance, and excellent wear resistance. The articles are coated with a single- or multi-layer layer system by a thermal CVD method without plasma excitation, where the single- or multi-layer layer system includes at least one nanocomposite layer with a first nanocrystalline phase of cubic titanium oxycarbonitride and a second, amorphous phase of silicon oxycarbonitride or silicon oxycarbide.

Abstract: Articles containing metal, hard metal, cermet or ceramic and coated with a hard material, and a method for producing same. The hard material layers can be used as anti-wear layers for cutting tools, as protective layers for turbine blades, or as diffusion barriers in microelectronics. The hard material layers exhibit a high hardness, high oxidation resistance, and excellent wear resistance. The articles are coated with a single- or multi-layer layer system by a thermal CVD method without plasma excitation, where the single- or multi-layer layer system includes at least one nanocomposite layer with a first nanocrystalline phase of cubic titanium oxycarbonitride and a second, amorphous phase of silicon oxycarbonitride or silicon oxycarbide.

Abstract: Hard-material-coated bodies composed of metal, cemented hard material, cermet or ceramic, coated with a TiSiCN composite layer or with a multilayer layer system which contains at least one TiSiCN composite layer. The TiSiCN composite layer is a nanocomposite layer which has been produced by a thermal CVD process without additional plasma excitation and contains a nanocrystalline phase composed of TiCxN1-x having a crystallite size in the range from 5 nm to 150 nm and a second phase composed of amorphous SiCxNy. The layer is characterized by a high hardness, a high oxidation and heat resistance and a high adhesive strength.

Abstract: Bodies coated with a SiC layer or with a multilayer coating system that include at least a SiC hard material layer, wherein the SiC layer consists of halogen-containing nanocrystalline 3C—SiC or a mixed layer which consists of halogen-containing nanocrystalline 3C—SiC and amorphous SiC or halogen-containing nanocrystalline 3C—SiC and amorphous carbon.

Abstract: Hard-material-coated bodies composed of metal, cemented hard material, cermet or ceramic, coated with a TiSiCN composite layer or with a multilayer layer system which contains at least one TiSiCN composite layer. The TiSiCN composite layer is a nanocomposite layer which has been produced by a thermal CVD process without additional plasma excitation and contains a nanocrystalline phase composed of TiCxN1-x having a crystallite size in the range from 5 nm to 150 nm and a second phase composed of amorphous SiCxNy. The layer is characterized by a high hardness, a high oxidation and heat resistance and a high adhesive strength.

Abstract: The invention relates to coated bodies made of metal, hard metal, cermet or ceramic material, coated with a single- or multi-layer coating system containing at least one hard material composite coating, and to a method for coating such bodies. The aim of the invention is to develop a coating system for such bodies, which is single- or multi-layered and comprises at least one hard material composite coating, which contains cubic TiAlCN and hexagonal AlN as the main phases and is characterized by a composite structure having a smooth, homogeneous surface, high oxidation resistance and high hardness. The aim includes the development of a method for cost-effectively producing such coatings. The hard material composite coating according to the invention contains cubic TiAlCN and hexagonal AlN as main phases, wherein the cubic TiAlCN is microcrystalline fcc-Ti1-xAlxCyNz where x>0.75, y=0 to 0.25 and z=0.75 to 1 having a crystallite size of ?=0.

Abstract: The invention relates to bodies coated with a hard material, comprising a multi-layer coating system containing at least one Ti1-xAlxN hard material coating and to a multi-stage CVD method for producing the bodies. The aim of the invention is to achieve excellent adhesion of the Ti1-xAlxN hard material coating in bodies coated with a hard material comprising a multi-layer coating system containing at least one Ti1-xAlxN hard material coating and a high degree of wear resistance. According to the invention, the bodies coated with a hard material comprising a multi-layer coating system containing at least one Ti1-xAlxN hard material coating are characterized by the following features: the coating system consists of a) a bonding coating applied to the body, consisting of TiN, Ti(C,N) or TiC; b) a phase gradient coating that is applied to the bonding coating; and c) the single or multi-phase Ti1-xAlxN hard material coating or coatings applied to the phase gradient coating.

Abstract: The invention relates to coated bodies made of metal, hard metal, cermet or ceramic material, coated with a single- or multi-layer coating system containing at least one hard material composite coating, and to a method for coating such bodies. The aim of the invention is to develop a coating system for such bodies, which is single- or multi-layered and comprises at least one hard material composite coating, which contains cubic TiAlCN and hexagonal AlN as the main phases and is characterized by a composite structure having a smooth, homogeneous surface, high oxidation resistance and high hardness. The aim includes the development of a method for cost-effectively producing such coatings. The hard material composite coating according to the invention contains cubic TiAlCN and hexagonal AlN as main phases, wherein the cubic TiAlCN is microcrystalline fcc-Ti1-xAlxCyNz where x>0.75, y=0 to 0.25 and z=0.75 to 1 having a crystallite size of ?=0.

Abstract: Bodies coated with a SiC layer or with a multilayer coating system that include at least a SiC hard material layer, wherein the SiC layer consists of halogen-containing nanocrystalline 3C-SiC or a mixed layer which consists of halogen-containing nanocrystalline 3C-SiC and amorphous SiC or halogen-containing nanocrystalline 3C-SiC and amorphous carbon.

Abstract: The invention relates to bodies made of metal, hard metal, cermet, ceramic or semiconductor material, which are coated with an Al2O3-layer or a multi-layered layer system containing at least one Al2O3-layer, and to a method for coating the type of bodies. The aim of the invention is to coat bodies made of metal, cermet, ceramic or semiconductor material with one or more Al2O3-layers, the layers being very hard >27 GPa and having an improved resistance to wear compared to traditional Al2O3-layers and are economical to produce. In the claimed coated bodies, the Al2O3-layer comprises totally or mainly a phase mixture of ? (theta)-aluminum oxide and ? (gamma)-aluminum oxide. In order to produce this type of coated body, the invention proposes a method in which the bodies are coated at temperatures of between 700° C. and 1050° C. and pressures >0.2 kPa by means of a thermal CVD-process without plasma stimulation, and one or more aluminum halogenides are used as oxygen precursor N2O and as Al-precursors.

Abstract: The invention relates to bodies coated with a hard material, comprising a multi-layer coating system containing at least one Ti1-xAlxN hard material coating and to a multi-stage CVD method for producing the bodies. The aim of the invention is to achieve excellent adhesion of the Ti1-xAlxN hard material coating in bodies coated with a hard material comprising a multi-layer coating system containing at least one Ti1-xAlxN hard material coating and a high degree of wear resistance. According to the invention, the bodies coated with a hard material comprising a multi-layer coating system containing at least one Ti1-xAlxN hard material coating are characterized by the following features: the coating system consists of a) a bonding coating applied to the body, consisting of TiN, Ti(C,N) or TiC; b) a phase gradient coating that is applied to the bonding coating; and c) the single or multi-phase Ti1-xAlxN hard material coating or coatings applied to the phase gradient coating.

Abstract: The invention relates to hard-coated bodies with a single- or multi-layer system containing at least one Ti1-xAlxN hard layer and a method for production thereof. The aim of the invention is to achieve a significantly improved wear resistance and oxidation resistance for such hard-coated bodies. Said hard-coated bodies are characterised in that the bodies are coated with at least one Ti1-xAlxN hard layer, generated by CVD without plasma stimulation present as a single-phase layer with cubic NaCl structure with a stoichiometric coefficient x>0.75 to x=0.93 and a lattice constant afcc between 0.412 nm and 0.405 nm, or as a multi-phase layer, the main phase being Ti1-xAlxN with a cubic NaCl structure with a stoichiometric coefficient x>0.75 to x=0.93 and a lattice constant afcc between 0.412 nm and 0.405 nm, with Ti1-xAlxN with a wurtzite structure and/or as TiNx with NaCl structure as further phase. Another feature of said hard layer is that the chlorine content is in the range of only 0.05 to 0.9 atom %.

Abstract: The invention relates to hard-coated bodies with a single- or multi-layer system containing at least one Ti1-xAlxN hard layer and a method for production thereof. The aim of the invention is to achieve a significantly improved wear resistance and oxidation resistance for such hard-coated bodies. Said hard-coated bodies are characterised in that the bodies are coated with at least one Ti1-xAlxN hard layer, generated by CVD without plasma stimulation present as a single-phase layer with cubic NaCl structure with a stoichiometric coefficient x>0.75 to x=0.93 and a lattice constant afcc between 0.412 nm and 0.405 nm, or as a multi-phase layer, the main phase being Ti1-xAlxN with a cubic NaCl structure with a stoichiometric coefficient x>0.75 to x=0.93 and a lattice constant afcc between 0.412 nm and 0.405 nm, with Ti1-xAlxN with a wurtzite structure and/or as TiNx with NaCl structure as further phase. Another feature of said hard layer is that the chlorine content is in the range of only 0.05 to 0.9 atom %.

Abstract: The invention relates to a tool, especially a cutting insert for cutting metallic materials, which consist of a hard metal, cermet ceramics or steel base, especially of a high speed steel base, and at least one layer deposited thereon. The single layer, or in the case of several layers the outer layer or the layer underneath the outer layer, contains molybdenum sulfide. The aim of the invention is to improve the resistance to wear of the friction-reducing, molybdenum sulfide containing layer even at high pressures. To this end, the molybdenum sulfide containing layer consists of an alternating sequence of two layer that are different from one another. The first layer contains 51 to 100% by weight of metallic molybdenum and the second layer contains 21 to 100% by weight of MoS2 which substantially consists of hexagonal crystals that are at least substantially oriented in a plane parallel to the tool surface.

Abstract: The invention relates to a tool, especially a cutting insert for cutting metallic materials, consisting of a hard metal, cermet, ceramic or steel base body and at least one coating deposited thereon. This single coating or in the event that there are several layers, the outer layer or the layer below the outer layer, consists essentially of molybdenum sulphide. The invention also relates to a method for producing the molybdenum sulphide coating by chemical vapour deposition. According to the invention, the molybdenum sulphide coating contains a mixture of the sulphide phases MoS2 and Mo2S3 with an essentially random orientation (isotropic orientation) of the phase crystals. The coating is applied by means of a chemical vapour deposition procedure.

Abstract: A tool having a substrate and at least as a sole layer or the outermost layer, a coating of the molybdenum sulfide containing 0.5 to 6 atomic % chlorine.

Abstract: A method for depositing refractory alumina (A.sub.2 O.sub.3) thin layers on cutting tools made of cemented carbide, cermet, ceramics or high speed steel is disclosed. The present method is a Plasma Activated Chemical Vapor Deposition (PACVD) process in which the plasma is produced by applying a bipolar pulsed DC voltage across two electrodes to which the tool substrates to be coated are fixtured and electrically connected.In contrast to prior art methods, built-up electrical charge on non-conducting surfaces is suppressed and hence, no arcing occurs on said surfaces. This will permit stable, long-term processing,With the present method, high-quality coatings of either single phase gamma-Al.sub.2 O.sub.3 or of a mixture of gamma- and alpha-Al.sub.2 O.sub.3 phases can be deposited on cutting tools at deposition temperatures as low as 500.degree. C.