Patents by Inventor Ion C. Halalay
Ion C. Halalay has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20250108365Abstract: A functionalized polymeric separator membrane, including a polymer backbone chosen from an aramid-based polymer, a polyamide-based polymer, or a polyimide-based polymer, or combinations thereof; and further comprising one or more functional side groups (-FSG) capable of trapping transition metal ions and acidic species. The functionalized polymeric separator membrane may be a sulfonated polyaramid separator membrane. Sulfonation of polyaramid separators add functional groups that trap both acidic species and TM ions, thereby suppressing anode damage caused by TM deposition onto the anode by a two-step process. The functionalized polymer separator membranes may be used with Li-ion, Li-metal, or Sodium-ion batteries.Type: ApplicationFiled: July 22, 2023Publication date: April 3, 2025Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Xingcheng Xiao, Nathaniel Z. Hardin, Ion C. Halalay
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Publication number: 20230299359Abstract: An electrolyte composition for use in a battery system including a silicon-based negative electrode having active material particles is provided. The electrolyte composition includes a polar solvent selected from the group consisting of ethylene carbonate, propylene carbonate, sulfolane, ?-butyrolactone, and combinations thereof and at least one lithium salt dissolved in the polar solvent at a concentration of at least 2 moles of the at least one lithium salt per 1 liter of the polar solvent. The at least one lithium salt and the polar solvent add dipoles to the electrolyte composition configured for reducing an electric field present at a surface of each of the active material particles in the silicon-based negative electrode of the battery system.Type: ApplicationFiled: March 15, 2022Publication date: September 21, 2023Applicants: GM GLOBAL TECHNOLOGY OPERATIONS LLC, c/o Bar-Ilan UniversityInventors: Ion C. Halalay, Doron Aurbach, Shalom Luski, Michael P. Balogh, Nicole Ellison, Jiazhi Hu
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Patent number: 11581521Abstract: A lithium metal oxide (LMO) cathode includes a current collector having a length defining a first end and a second end, a width, and a first side and a second side, LMO active material applied to the first side and the second side of the current collector such that the LMO active material applied to each respective side of the current collector has an inner face contiguous with the current collector and an outer face, and a plurality of channels extending widthwise across the cathode within the LMO active material applied to the first and second sides. The LMO active material on each current collector side can have a thickness of about 100 ?m to about 400 ?m. The channels on the same side of the current collector can be spaced apart by 0.1 mm to 10 mm. The channels can have widths of 10 ?m to 60 ?m.Type: GrantFiled: June 24, 2020Date of Patent: February 14, 2023Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Meixian Wang, Raghunathan K, Niccolo Jimenez, Ion C. Halalay
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Patent number: 11575115Abstract: An electrode heat treatment device and associated method for fabricating an electrode are described, and include forming a workpiece, including coating a current collector with a slurry. The workpiece is placed on a first spool, and the first spool including the workpiece is placed in a sealable chamber, wherein the sealable chamber includes the first spool, a heat exchange work space, and a second spool. An inert environment is created in the sealable chamber. The workpiece is subjected to a multi-step continuous heat treatment operation in the inert environment, wherein the multi-step continuous heat treatment operation includes continuously transferring the workpiece through the heat exchange work space between the first spool and the second spool and controlling the heat exchange work space to an elevated temperature.Type: GrantFiled: July 15, 2019Date of Patent: February 7, 2023Assignee: GM Global Technology Operations LLCInventors: Ion C. Halalay, Kevin B. Rober, Niccolo Jimenez, Michael P. Balogh, Teresa U. Holiness-Stalling, Raghunathan K
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Patent number: 11349119Abstract: Electroactive materials having a nitrogen-containing carbon coating and composite materials for a high-energy-density lithium-based, as well as methods of formation relating thereto, are provided. The composite electrode material includes a silicon-containing electroactive material having a substantially continuous nitrogen-containing carbon coating formed thereon. The method includes contacting the silicon-containing electroactive material and one or more nitrogen-containing precursor materials and heating the mixture. The one or more nitrogen-containing precursor materials include one or more nitrogen-carbon bonds and during heating the nitrogen of the one or more nitrogen-carbon bonds with silicon in the silicon-containing electroactive material to form the nitrogen-containing carbon coating on exposed surfaces of the silicon-containing electroactive material.Type: GrantFiled: October 15, 2018Date of Patent: May 31, 2022Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Ion C. Halalay, Timothy J. Fuller, Michael P. Balogh
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Patent number: 11316142Abstract: Methods for fabricating electrodes include coating a current collector with a slurry to form a coated current collector. The slurry includes a dry fraction, including silicon particles, polymeric binders, and one or more types of naturally occurring carbonaceous filaments, and one or more solvents. The coated current collector is heat treated to produce the electrode having a layer of silicon-based host material. The one or more naturally occurring carbonaceous filaments can include animal fibers, chitin, alginate, cellulose, keratin, and chitosan, and can have an average length of 1 ?m to 50 ?m and an average diameter of 1 nm to 500 nm. The dry fraction can include 5 wt. % to 95 wt. % silicon particles, 0.1 wt. % to 15 wt. % polymeric binders, and 1 wt. % to 20 wt. % naturally occurring carbonaceous filaments. The method can include assembling a battery cell by disposing the electrode and a positive electrode in electrolyte.Type: GrantFiled: September 17, 2019Date of Patent: April 26, 2022Assignee: GM Global Technology Operations LLCInventors: Meng Jiang, Raghunathan K, Ion C. Halalay, Mark W. Verbrugge
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Publication number: 20210408518Abstract: A lithium metal oxide (LMO) cathode includes a current collector having a length defining a first end and a second end, a width, and a first side and a second side, LMO active material applied to the first side and the second side of the current collector such that the LMO active material applied to each respective side of the current collector has an inner face contiguous with the current collector and an outer face, and a plurality of channels extending widthwise across the cathode within the LMO active material applied to the first and second sides. The LMO active material on each current collector side can have a thickness of about 100 ?m to about 400 ?m. The channels on the same side of the current collector can be spaced apart by 0.1 mm to 10 mm. The channels can have widths of 10 ?m to 60 ?m.Type: ApplicationFiled: June 24, 2020Publication date: December 30, 2021Inventors: Meixian Wang, Raghunathan K, MI Jimenez, Ion C. Halalay
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Publication number: 20210151761Abstract: An electrode for a lithium-ion electrochemical cell includes a current collector and a first layer formed from a first electrode composition disposed on the current collector. The first electrode composition includes a binder component; a conductive filler component dispersed within the binder component; and an active material component dispersed within the binder component and the conductive filler component. The first electrode composition has a first surface and a second surface spaced apart from and parallel to the first surface. The first electrode composition defines a plurality of pores between the first surface and the second surface having a tailored pore size distribution that includes at least a first pore size and a second pore size that is greater than the first pore size. The first electrode composition has a first porosity of at least 60%.Type: ApplicationFiled: November 18, 2019Publication date: May 20, 2021Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Niccolo Jimenez, Ion C. Halalay, Michael P. Balogh, Raghunathan K
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Publication number: 20210083264Abstract: Methods for fabricating electrodes include coating a current collector with a slurry to form a coated current collector. The slurry includes a dry fraction, including silicon particles, polymeric binders, and one or more types of naturally occurring carbonaceous filaments, and one or more solvents. The coated current collector is heat treated to produce the electrode having a layer of silicon-based host material. The one or more naturally occurring carbonaceous filaments can include animal fibers, chitin, alginate, cellulose, keratin, and chitosan, and can have an average length of 1 ?m to 50 ?m and an average diameter of 1 nm to 500 nm. The dry fraction can include 5 wt. % to 95 wt. % silicon particles, 0.1 wt. % to 15 wt. % polymeric binders, and 1 wt. % to 20 wt. % naturally occurring carbonaceous filaments. The method can include assembling a battery cell by disposing the electrode and a positive electrode in electrolyte.Type: ApplicationFiled: September 17, 2019Publication date: March 18, 2021Inventors: Meng Jiang, Raghunathan K, Ion C. Halalay, Mark W. Verbrugge
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Publication number: 20210020899Abstract: An electrode heat treatment device and associated method for fabricating an electrode are described, and include forming a workpiece, including coating a current collector with a slurry. The workpiece is placed on a first spool, and the first spool including the workpiece is placed in a sealable chamber, wherein the sealable chamber includes the first spool, a heat exchange work space, and a second spool. An inert environment is created in the sealable chamber. The workpiece is subjected to a multi-step continuous heat treatment operation in the inert environment, wherein the multi-step continuous heat treatment operation includes continuously transferring the workpiece through the heat exchange work space between the first spool and the second spool and controlling the heat exchange work space to an elevated temperature.Type: ApplicationFiled: July 15, 2019Publication date: January 21, 2021Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Ion C. Halalay, Kevin B. Rober, Niccolo Jimenez, Michael P. Balogh, Teresa U. Holiness-Stalling, Raghunathan K
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Patent number: 10892481Abstract: Methods for pre-lithiating an electroactive material including a Group III element, Group IV element, a Group V element, or a combination thereof for an electrode for an electrochemical cell are provided as well as electrodes including the pre-lithiated electroactive material. The methods include reacting a lithiating agent including LiH or Li3N with the electroactive material to form a pre-lithiated electroactive material.Type: GrantFiled: February 13, 2019Date of Patent: January 12, 2021Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Michael P. Balogh, Ion C. Halalay
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Patent number: 10854882Abstract: A method of forming an electrode includes attaching a tab to a collector to form a pre-tabbed current collector; disposing the pre-tabbed current collector onto a non-stick substrate to form a workpiece; and casting a slurry onto the workpiece to form a film. The slurry includes an active material component, one or more carbon additives, and at least one of a filamentary copper additive and a dendritic copper additive. The method includes drying the film at a first temperature to form a dried film; curing the dried film under pressure at a second higher temperature to form a cured film; removing the cured film from the non-stick substrate to form a precursor film; and carbonizing and annealing the precursor film at a third higher temperature. Carbonizing forms a three-dimensional electrically-conductive network and annealing forms a second contiguous network of copper connected to the active material component to form the electrode.Type: GrantFiled: October 19, 2018Date of Patent: December 1, 2020Assignee: GM Global Technology Operations LLCInventors: Ion C. Halalay, Raghunathan K
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Publication number: 20200350558Abstract: Methods for fabricating electrodes include coating a current collector with a slurry and pyrolyzing the coated current collector to produce the electrode with a layer of silicon-based host material. The slurry can include one or more solvents and a dry fraction having silicon particles, one or more polymeric binders, and carbon fibers. Pyrolyzing includes heating at a first temperature, and subsequently heating at a second temperature higher than the first temperature. The silicon particles include single-phase silicon and/or Li2Si, have an average particle diameter of less than 10 ?m, and can be 70% of the dry fraction. The polymeric binders can be only polyacrylonitrile, or optionally one or more fluorinated polymers. The carbon fibers have an average diameter of at least about 50 nm, an average length of at least about 1 ?m, and can be up to 15 wt. % of the dry fraction.Type: ApplicationFiled: May 2, 2019Publication date: November 5, 2020Inventors: Niccolo Jimenez, Michael P. Balogh, Ion C. Halalay, Raghunathan K
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Patent number: 10741812Abstract: Methods of scavenging acid in a lithium-ion electrochemical cell are provided. An electrolyte solution that contains an acid or is capable of forming the acid is contacted with a polymer comprising a nitrogen-containing acid-trapping moiety selected from the group consisting of: an amine group, a pyridine group, and combinations thereof. The nitrogen-containing acid-trapping moiety scavenges acidic species present in the electrolyte solution by participating in a Lewis acid-base neutralization reaction. The electrolyte solution comprises a lithium salt and one or more solvents and is contained in the electrochemical cell that further comprises a first electrode, a second electrode having an opposite polarity from the first electrode, and a porous separator. Lithium ions can be cycled through the separator and electrolyte solution from the first electrode to the second electrode, where acid generated during the cycling is scavenged by the polymer comprising a nitrogen-containing acid-trapping moiety.Type: GrantFiled: June 19, 2017Date of Patent: August 11, 2020Assignees: GM GLOBAL TECHNOLOGY OPERATIONS LLC, BAR-ILAN UNIVERSITYInventors: Shalom Luski, Doron Aurbach, Timothy J. Fuller, Ion C. Halalay, Anjan Banerjee, Baruch Ziv, Raghunathan K
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Publication number: 20200127292Abstract: A method of forming an electrode includes attaching a tab to a collector to form a pre-tabbed current collector; disposing the pre-tabbed current collector onto a non-stick substrate to form a workpiece; and casting a slurry onto the workpiece to form a film. The slurry includes an active material component, one or more carbon additives, and at least one of a filamentary copper additive and a dendritic copper additive. The method includes drying the film at a first temperature to form a dried film; curing the dried film under pressure at a second higher temperature to form a cured film; removing the cured film from the non-stick substrate to form a precursor film; and carbonizing and annealing the precursor film at a third higher temperature. Carbonizing forms a three-dimensional electrically-conductive network and annealing forms a second contiguous network of copper connected to the active material component to form the electrode.Type: ApplicationFiled: October 19, 2018Publication date: April 23, 2020Applicant: GM Global Technology Operations LLCInventors: Ion C. Halalay, Raghunathan K
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Patent number: 10581119Abstract: Electrochemical cells that cycle lithium ions and methods for suppressing or minimizing dendrite formation are provided. The electrochemical cells include a positive electrode, a negative electrode, and a separator disposed therebetween. At least one transition metal ion-trapping moiety, including one or more polymers functionalized with one or more trapping groups, may be included within the electrochemical cell as a coating, pore filler, substitute pendant group, or binder. The one or more trapping groups may be selected from the group consisting of: crown ethers, siderophores, bactins, ortho-phenanthroline, iminodiacetic acid dilithium salt, oxalates malonates, fumarates, succinates, itaconates, phosphonates, and combinations thereof, and may bind to metal ions found within the electrochemical cell to minimize or suppress formation of dendrite protrusions on the negative electrode.Type: GrantFiled: July 7, 2017Date of Patent: March 3, 2020Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Ion C. Halalay, Zicheng Li, Timothy J. Fuller, Bob R. Powell, Jr.
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Patent number: 10581117Abstract: Electrochemical cells that cycle lithium ions and methods for suppressing or minimizing deposition of transition metal ions at negative electrodes are provided. The electrochemical cells include a positive electrode, a negative electrode, a separator disposed therebetween, and an electrolyte system including one or more lithium salts, one or more solvents, and at least one additive complexing compound. The at least one additive complexing compound includes an alkyl group having greater than or equal to 4 carbon atoms and less than or equal to 22 carbon atoms and a transition metal ion trapping group. The at least one additive compound associates with a surface of the separator via van der Waal's interactive forces and is further capable of complexing with transition metal ion within the electrochemical cell to sequester or tether the ions generated by contaminants to minimize or suppress the deposition of transition metal cations on the negative electrode.Type: GrantFiled: July 7, 2017Date of Patent: March 3, 2020Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Ion C. Halalay, Timothy J. Fuller, Bob R. Powell, Jr.
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Patent number: 10418668Abstract: Electrochemical cells that cycle lithium ions and methods for suppressing or minimizing dendrite formation are provided. The electrochemical cells include a positive electrode, a negative electrode, and a separator sandwiched therebetween. The positive and negative electrodes and separator may each include an electrolyte system comprising one or more lithium salts, one or more solvents, and one or more complexing agents. The one or more complexing agents binds to metal contaminants found within the electrochemical cell to form metal ion complex compounds that minimize or suppress formation of dendrite protrusions on the negative electrode at least by increasing the horizontal area (e.g., decreasing the height) of any dendrite formation.Type: GrantFiled: July 7, 2017Date of Patent: September 17, 2019Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Qiang Wu, Zhiqiang Yu, Haijing Liu, Honggu Pan, Ion C. Halalay
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Patent number: 10243241Abstract: A lithium ion battery is provided that includes: a positive electrode; a negative electrode; a microporous polymer separator soaked in an electrolyte solution, the microporous polymer separator disposed between the positive electrode and the negative electrode; and a transition metal cation trap which is i) incorporated as a binder in any of the positive electrode or the negative electrode, ii) deposited onto a surface of any of the positive electrode or the negative electrode, iii) incorporated into the microporous polymer separator, iv) deposited onto a surface of the microporous polymer separator, or v) included as an additive in the electrolyte solution. The transition metal cation trap is a siderophore.Type: GrantFiled: December 1, 2015Date of Patent: March 26, 2019Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Ion C. Halalay, Timothy J. Fuller, Zicheng Li, Mark W. Verbrugge
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Publication number: 20190013548Abstract: Electrochemical cells that cycle lithium ions and methods for suppressing or minimizing deposition of transition metal ions at negative electrodes are provided. The electrochemical cells include a positive electrode, a negative electrode, a separator disposed therebetween, and an electrolyte system including one or more lithium salts, one or more solvents, and at least one additive complexing compound. The at least one additive complexing compound includes an alkyl group having greater than or equal to 4 carbon atoms and less than or equal to 22 carbon atoms and a transition metal ion trapping group. The at least one additive compound associates with a surface of the separator via van der Waal's interactive forces and is further capable of complexing with transition metal ion within the electrochemical cell to sequester or tether the ions generated by contaminants to minimize or suppress the deposition of transition metal cations on the negative electrode.Type: ApplicationFiled: July 7, 2017Publication date: January 10, 2019Inventors: Ion C. Halalay, Timothy J. Fuller, Bob R. Powell, JR.