Abstract: A layered structure, a process of applying an image layer to a substrate, and a process of using a layered structure are disclosed. The layered structure having an image layer is applied to a substrate. The image layer is formed by a transfer foil process, a digital printing process, or a combination thereof. The image layer includes one or both of a radiation-cured coating and an amine-cured coating. The application process includes positioning a substrate, applying an image layer to the substrate, and applying a coating to the image layer. The process of using a layered structure includes positioning the layered structure in an exterior environment, applying an image to an image layer by a transfer foil process, a digital printing process, or a combination thereof, and applying the coating to the image layer, the coating being radiation-cured, amine-cured, or a combination thereof.