Abstract: A method for preparing a vapor sensitive sacrificial support material. The method may include decomposing a polycondensed PEO polymer with heat in the presence of a graphene-like material to release PEO polymer radicals from the polycondensed PEO polymer, such that at least a portion of the PEO polymer radicals become trapped on at least a portion of a surface of the graphene-like material to form a coated graphene-like material, which may be defined as a structural reinforcement material. The method may further include forming the vapor sensitive water-soluble thermoplastic polyethylene oxide graft polymer. The vapor sensitive water-soluble thermoplastic polyethylene oxide graft polymer may include a polyethylene oxide polymer backbone. The vapor sensitive water-soluble thermoplastic polyethylene oxide graft polymer may further include one or more nanoscopic particulate processing aids.

Abstract: A method for preparing a sacrificial support material for use in printing a three-dimensional (3D) article includes providing a water-soluble thermoplastic polymer composite including a water-soluble thermoplastic polyethylene oxide graft polymer having a polyethylene oxide polymer backbone, and from about 0.05% to about 10% by weight of the polyethylene oxide polymer backbone of at least one polar vinyl monomer grafted to the polyethylene oxide polymer backbone. One or more nanoscopic particulate processing aids may be uniformly dispersed in the graft polymer in an amount of from about 0.05% to about 10% by weight of the water-soluble thermoplastic polymer composite. The water-soluble thermoplastic polymer composite may have a viscosity in the range of about 100 to about 10,000 Pa-sec. The method may also include forming the water-soluble thermoplastic polymer composite into the 3D printable sacrificial support material.

Abstract: Electrically conductive thermoplastic polymer composites of particulate thermoplastic polyester polymers, electrically conductive components (carbon nanofibers, graphene nanoplatelets, and/or conductive metal nanoparticulates), processing aids such as plasticizers, thermal stabilizers, etc., as well as nanoscopic particulate fillers such as nanoscopic titanium dioxide, etc., the electrically conductive components being distributed substantially uniformly in the composite to form an electrically conductive network. Also, methods for preparing thermoplastic polymer composites, a system for collecting extruded filaments prepared from thermoplastic polymer composites as a coil of filament, as well as method for tempering articles formed from thermoplastic polymer composites to increase the degree of crystallinity of the thermoplastic polymers and thus their mechanical strength properties.

Abstract: A method for preparing a sacrificial support material for use in printing a three-dimensional (3D) article includes providing a water-soluble thermoplastic polymer composite including a water-soluble thermoplastic polyethylene oxide graft polymer having a polyethylene oxide polymer backbone, and from about 0.05% to about 10% by weight of the polyethylene oxide polymer backbone of at least one polar vinyl monomer grafted to the polyethylene oxide polymer backbone. One or more nanoscopic particulate processing aids may be uniformly dispersed in the graft polymer in an amount of from about 0.05% to about 10% by weight of the water-soluble thermoplastic polymer composite. The water-soluble thermoplastic polymer composite may have a viscosity in the range of about 100 to about 10,000 Pa-sec. The method may also include forming the water-soluble thermoplastic polymer composite into the 3D printable sacrificial support material.

Abstract: Water-soluble thermoplastic polymer composites of water-soluble thermoplastic polyethylene oxide graft polymers, and nanoscopic particulate processing aids such nanoscopic titanium dioxide powders, or water-soluble polyethylene oxide graft polymers, structural reinforcement materials such as carbon or glass fibers, and plasticizers. These water-soluble thermoplastic polymer composites may be useful in preparing, for example, three-dimensional (3D) sacrificial supports, vapor sensors, as well as other three-dimensional (3D) articles, objects, or parts.

Abstract: Electrochemical devices, such as batteries, supercapacitors, etc., which may be prepared from nanoscopic electrically conductive carbon materials, and optionally electrochemically active materials. Also, methods for preparing such electrochemical devices, including components, elements, etc., of such devices by using three-dimensional (3D) printing, fused deposition modeling (FDM), selective laser sintering (SLS), etc., techniques.

Abstract: Electrically conductive thermoplastic polymer composites of particulate thermoplastic polyester polymers, electrically conductive components (carbon nanofibers, graphene nanoplatelets, and/or conductive metal nanoparticulates), processing aids such as plasticizers, thermal stabilizers, etc., as well as nanoscopic particulate fillers such as nanoscopic titanium dioxide, etc., the electrically conductive components being distributed substantially uniformly in the composite to form an electrically conductive network. Also, methods for preparing thermoplastic polymer composites, a system for collecting extruded filaments prepared from thermoplastic polymer composites as a coil of filament, as well as method for tempering articles formed from thermoplastic polymer composites to increase the degree of crystallinity of the thermoplastic polymers and thus their mechanical strength properties.

Abstract: Water-soluble thermoplastic polymer composites of water-soluble thermoplastic polyethylene oxide graft polymers, and nanoscopic particulate processing aids such nanoscopic titanium dioxide powders, or water-soluble polyethylene oxide graft polymers, structural reinforcement materials such as carbon or glass fibers, and plasticizers. These water-soluble thermoplastic polymer composites may be useful in preparing, for example, three-dimensional (3D) sacrificial supports, vapor sensors, as well as other three-dimensional (3D) articles, objects, or parts.

Abstract: Electrochemical devices, such as batteries, supercapacitors, etc., which may be prepared from nanoscopic electrically conductive carbon materials, and optionally electrochemically active materials. Also, methods for preparing such electrochemical devices, including components, elements, etc., of such devices by using three-dimensional (3D) printing, fused deposition modeling (FDM), selective laser sintering (SLS), etc., techniques.

Abstract: A dispersion of nanoplatelet graphene-like material, such as graphene nanoplatelets, in a solid or liquid dispersion media wherein the nanoplatelet graphene-like material is dispersed substantially uniformly in the dispersion media with a graphene-like material dispersant. Such dispersions may be used to prepare articles by three-dimensional (3D) printing, as well as to provide electrically conductive inks and coatings, chemical sensors and biosensors, electrodes, energy storage devices, solar cells, etc. Liquid dispersions may be prepared, for example, by sonication of solutions of graphite flakes, dispersant, and liquid dispersion media, while solid dispersions may be prepared, for example, by combining the melted polymer with the liquid dispersion, dissolving the solid polymer in a miscible solvent and then blending with the liquid dispersion, dissolving the solid polymer in the liquid dispersion, or polymerizing one or more monomers in the liquid dispersion to form the solid polymer.