Abstract: A grafted polymer, either polyolefin or polyester, containing monomers associated with sludge and varnish control as well as monomers associated with soot handling to provide a graft polymer exhibiting multiple performance attributes. Also described are methods for manufacturing these novel multiple-function graft polymers via solution and melt processes. Lubricating oil compositions containing these novel multiple-function polymers as an additive that display performance characteristics directed to good soot handling and sludge and varnish control as well as control of viscosity increase are described.

Abstract: A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of malcic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts.

Abstract: A polyalkene dispersant comprised of low MW polyalkene having an average molecular weight range of about 300 to about 10,000 and an ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomer and methods of making the same are disclosed. The monomers are formed by reacting an acylating agent with amines having one or more primary or secondary amine to form a reaction product. Graft polyalkene dispersants comprising such monomers are formed by grafting the reaction product to the polyalkene backbone. Also described is lubricating oil comprising base oil and the dispersant polyalkene as described above.

Abstract: The composition and preparation of multiple graft low molecular weight polymers useful as dispersants are described. The dispersants described are suitable for controlling sludge and varnish as well as soot. The product is useful as a lubricant additive and a fuel additive.

Abstract: A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of maleic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts.

Abstract: A polyalkene dispersant comprised of low MW polyalkene having an average molecular weight range of about 300 to about 10,000 and an ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomer and methods of making the same are disclosed. The monomers are formed by reacting an acylating agent with amines having one or more primary or secondary amine to form a reaction product. Graft polyalkene dispersants comprising such monomers are formed by grafting the reaction product to the polyalkene backbone. Also described is lubricating oil comprising base oil and the dispersant polyalkene as described above.

Abstract: A polyalkene dispersant comprised of low MW polyalkene having an average molecular weight range of about 300 to about 10,000 and an ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomer and methods of making the same are disclosed. The monomers are formed by reacting an acylating agent with amines having one or more primary or secondary amine to form a reaction product. Graft polyalkene dispersants comprising such monomers are formed by grafting the reaction product to the polyalkene backbone. Also described is lubricating oil comprising base oil and the dispersant polyalkene as described above.

Abstract: A polyalkene dispersant comprised of low MW polyalkene having an average molecular weight range of about 300 to about 10,000 and an ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomer and methods of making the same are disclosed. The monomers are formed by reacting an acylating agent with amines having one or more primary or secondary amine to form a reaction product. Graft polyalkene dispersants comprising such monomers are formed by grafting the reaction product to the polyalkene backbone. Also described is lubricating oil comprising base oil and the dispersant polyalkene as described above.

Abstract: A grafted polymer, either polyolefin or polyester, containing monomers associated with sludge and varnish control as well as monomers associated with soot handling to provide a graft polymer exhibiting multiple performance attributes. Also described are methods for manufacturing these novel multiple-function graft polymers via solution and melt processes. Lubricating oil compositions containing these novel multiple-function polymers as an additive that display performance characteristics directed to good soot handling and sludge and varnish control as well as control of viscosity increase are described.

Abstract: A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of maleic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts.

Abstract: A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of maleic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts.

Abstract: An emergency fuel for an internal combustion engine comprises a hydrocarbon solvent having a flash point of at least 100° F. (such as about 65-75% paraffins and about 25-35% naphthenes, or about 75-85% paraffins and about 15-25% of C7 or higher alcohols, or an aromatic solvent, or an naphthalene-depleted aromatic solvent) and a cold starting additive. The cold starting additive may be provided in an amount of less than 5,000 ppm, preferably between about 1 ppm and 150 ppm. The cold starting additive is preferably selected from peroxides, azo compounds, cyano compounds, cetane improvers, or combinations of these compounds. When the emergency fuel is added to a cold engine, including one substantially at room temperature, the engine may be easily started.

Abstract: Methods are disclosed for making graft copolymers. The methods comprise the steps of: (a) providing (i) an ethylene/propylene (EP) copolymer or other graftable polymer, (ii) an ethylenically unsaturated sulfur-, nitrogen- and/or oxygen-containing monomer, and (iii) an amount of an initiator sufficient to graft said monomer and EP copolymer or other graftable polymer, (b) introducing said EP copolymer or other graftable polymer into an extruder; (c) introducing said monomer into the extruder; (d) introducing said initiator into the extruder, wherein at least one of the above-identified reactants in (a) is introduced in the presence of a polar solvent; and (e) reacting said EP copolymer or other graftable polymer, monomer and initiator by operating said extruder, thereby forming the graft copolymer. This invention also relates to methods of making a dispersant viscosity index improver and methods for making a lubricating oil.

Abstract: A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of maleic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts.

Abstract: A grafted polyolefin containing one or more of N-vinylimidazole, 4-vinylpyridine, or other ethylenically-unsaturated nitrogen-containing or oxygen-containing graftable monomers grafted to a polyolefin copolymer is disclosed. The grafted polyolefin preferably has a weight average molecular weight of from about 20,000 to about 500,000, a polydispersity of less than about 10, and an ADT value of at least about 8. The grafted polyolefin can be defined as containing more than about 1.2% by weight of grafted monomer on a polyolefin, or as containing at least about 13 moles of graftable monomers per mole of polyolefin, or as having an asphaltene dispersancy test (ADT) value of at least about 8. Also described is a lubricating oil comprising a lubricant base oil and a grafted polyolefin as described above. Also described is a method of making a dispersant viscosity index improver.

Abstract: An emergency fuel for an internal combustion engine comprises a hydrocarbon solvent having a flash point of at least 100° F. (such as about 65-75% paraffins and about 25-35% naphthenes, or about 75-85% paraffins and about 15-25% of C7 or higher alcohols, or an aromatic solvent, or an naphthalene-depleted aromatic solvent) and a cold starting additive. The cold starting additive may be provided in an amount of less than 5,000 ppm, preferably between about 1 ppm and 150 ppm. The cold starting additive is preferably selected from peroxides, azo compounds, cyano compounds, cetane improvers, or combinations of these compounds. When the emergency fuel is added to a cold engine, including one substantially at room temperature, the engine may be easily started.

Abstract: An emergency fuel for an internal combustion engine comprises a hydrocarbon solvent having a flash point of at least 100° F. (such as about 65-75% paraffins and about 25-35% naphthenes, or about 75-85% paraffins and about 15-25% of C7 or higher alcohols, or an aromatic solvent, or an naphthalene-depleted aromatic solvent) and a cold starting additive. The cold starting additive may be provided in an amount of less than 5,000 ppm, preferably between about 1 ppm and 150 ppm. The cold starting additive is preferably selected from peroxides, azo compounds, cyano compounds, cetane improvers, or combinations of these compounds. When the emergency fuel is added to a cold engine, including one substantially at room temperature, the engine may be easily started.

Abstract: Methods are disclosed for making graft copolymers. The methods comprise the steps of: (a) providing (i) an ethylene/propylene (EP) copolymer or other graftable polymer, (ii) an ethylenically unsaturated sulfur-, nitrogen- and/or oxygen-containing monomer, and (iii) an amount of an initiator sufficient to graft said monomer and EP copolymer or other graftable polymer, (b) introducing said EP copolymer or other graftable polymer into an extruder; (c) introducing said monomer into the extruder; (d) introducing said initiator into the extruder, wherein at least one of the above-identified reactants in (a) is introduced in the presence of a polar solvent; and (e) reacting said EP copolymer or other graftable polymer, monomer and initiator by operating said extruder, thereby forming the graft copolymer. This invention also relates to methods of making a dispersant viscosity index improver and methods for making a lubricating oil.

Abstract: Methods for making graft copolymers include (a) providing (i) an ethylene/propylene 9EP) copolymer or other graftable polymer, (ii) an ethylenically unsaturated sulfur-, nitrogen- and/or oxygen-containing monomer, and (iii) an amount of an initiator sufficient to graft said monomer and EP copolymer or other graftable polymer, (b) introducing the EP copolymer or other graftable polymer into an extruder, (c) introducing the monomer into the extruder, (d) introducing the initiator into the extruder, wherein at least one of the reactants employed in step (a) is introduced in the presence of a polar solvent, and (e) reacting the EP copolymer or other graftable polymer, monomer and initiator by operating the extruder, thereby forming the graft copolymer. Methods of making dispersant viscosity index improver and methods for making a lubricating oil, as well as graft copolymers, viscosity index improvers and lubricating oils made by such methods are also contemplated.

Abstract: A grafted polyolefin containing one or more of N-vinylimidazole, 4-vinylpyridine, or other ethylenically-unsaturated nitrogen-containing or oxygen-containing graftable monomers grafted to a polyolefin copolymer is disclosed. The grafted polyolefin preferably has a weight average molecular weight of from about 20,000 to about 500,000, a polydispersity of less than about 10, and an ADT value of at least about 8. The grafted polyolefin can be defined as containing more than about 1.2% by weight of grafted monomer on a polyolefin, or as containing at least about 13 moles of graftable monomers per mole of polyolefin, or as having an asphaltene dispersancy test (ADT) value of at least about 8. Also described is a lubricating oil comprising a lubricant base oil and a grafted polyolefin as described above. Also described is a method of making a dispersant viscosity index improver.