Patents by Inventor Istvan T. Horvath
Istvan T. Horvath has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 9617359Abstract: Perfluoro-t-butoxyallyl ether and perfluoro-t-butoxypropargyl ether and methods for their synthesis are disclosed. Also disclosed are methods for making polymers from the perfluoro-t-butoxyallyl ether and perfluoro-t-butoxypropargyl ether.Type: GrantFiled: April 24, 2014Date of Patent: April 11, 2017Assignee: City University of Hong KongInventors: Istvan T. Horvath, K. C. Lau, Matthew Y. Lui, Edwin Law, Kwun Chung Paul Wong
-
Publication number: 20140323672Abstract: Perfluoro-t-butoxyallyl ether and perfluoro-t-butoxypropargyl ether and methods for their synthesis are disclosed. Also disclosed are methods for making polymers from the perfluoro-t-butoxyallyl ether and perfluoro-t-butoxypropargyl ether.Type: ApplicationFiled: April 24, 2014Publication date: October 30, 2014Inventors: Istvan T. HORVATH, K. C. Lau, Matthew Y. Lui, Edwin Law, Kwun Chung Paul Wong
-
Patent number: 5919869Abstract: A polymer having a terminal hydroxyl, aldehyde or alkylamino substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a polyene (diene, e.g.), monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical. Preferably, the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.Type: GrantFiled: March 6, 1998Date of Patent: July 6, 1999Assignee: Exxon Chemical Patents, Inc.Inventors: Warren A. Thaler, Jacob I. Emert, Istvan T. Horvath, Richard H. Schlosberg, David A. Young, Stephen Zushma
-
Patent number: 5880219Abstract: A polymer having a terminal hydroxyl, aldehyde or alkylamino substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a polyene (diene, e.g.), monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical. Preferably, the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.Type: GrantFiled: April 8, 1997Date of Patent: March 9, 1999Assignee: Exxon Chemical Patents Inc.Inventors: Warren A. Thaler, Jacob I. Emert, Istvan T. Horvath, Richard H. Schlosberg, David A. Young, Stephen Zushma
-
Patent number: 5780554Abstract: A saturated polymer having a terminal aldehyde or hydroxy substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the saturated polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.Type: GrantFiled: November 1, 1996Date of Patent: July 14, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Jacob Emert, Istvan T. Horvath, Richard H. Schlosberg, Warren A. Thaler, David A. Young, Stephen Zushma
-
Patent number: 5777041Abstract: A saturated polymer having a terminal aldehyde or hydroxy substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the saturated polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula H.sub.2 C=CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.Type: GrantFiled: January 22, 1997Date of Patent: July 7, 1998Assignee: Exxon Chemical Patents IncInventors: Jacob Emert, Istvan T. Horvath, Richard H. Schlosberg, Warren A. Thaler, David A. Young, Stephen Zushma
-
Patent number: 5691422Abstract: A saturated polymer having a terminal aldehyde or hydroxy substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the saturated polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.Type: GrantFiled: June 12, 1996Date of Patent: November 25, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Jacob Emert, Istvan T. Horvath, Richard H. Schlosberg, Warren A. Thaler, David A. Young, Stephen Zushma
-
Patent number: 5675041Abstract: The invention is a process for production of C.sub.3 to C.sub.6 aldehydes by hydroformylating a mixture containing: (a) C.sub.2 to C.sub.5 olefins and mixtures thereof, and (b) (i) C.sub.2 to C.sub.5 alkynes and mixtures thereof or (ii) C.sub.3 to C.sub.5 cumulated dienes and mixtures thereof or (iii) mixtures of (i) and (ii), with CO, H.sub.2 and a solution of a rhodium complex catalyst produced by complexing Rh and an organophosphorus compound at a concentration of Rh in solution from 1 to 1000 ppm by weight. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio of at least 30. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio greater than the value R.sub.L defined by the formula: ##EQU1## in which R.sub.B is the P/Rh ratio sufficient for a catalytically active Rh complex, pKa.sub.TPP is the pKa value for triphenylphosphine, pKa.sub.L is the pKa value for the triorganophosphorus compound, R is the gas constant, and .DELTA.S.sub.Type: GrantFiled: December 15, 1995Date of Patent: October 7, 1997Assignee: Exxon Research & Engineering CompanyInventors: Gabor Kiss, Frank Hershkowitz, Harry W. Deckman, Michael Gerard Matturro, Istvan T. Horvath, Anthony M. Dean, Raymond A. Cook
-
Patent number: 5674950Abstract: A polymer having a terminal hydroxyl, aldehyde or alkylamino substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a polyene (diene, e.g.), monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical. Preferably, the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.Type: GrantFiled: February 27, 1995Date of Patent: October 7, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Warren A. Thaler, Jacob I. Emert, Istvan T. Horvath, Richard H. Schlosberg, David A. Young, Stephen Zushma
-
Patent number: 5600017Abstract: The invention is a process for hydroformylating multicomponent syngas feed streams containing CO, H.sub.2, C.sub.2 to C.sub.5 olefins and mixtures thereof and C.sub.2 to C.sub.5 alkynes and mixtures thereof by contacting the multicomponent syngas feed stream with a solution of an oil soluble rhodium complex catalyst produced by complexing in solution a low valence Rh and an oil soluble triorganophoshorous compound wherein the catalyst has a P/Rh ratio of at least 30, a concentration of Rh in solution from about 1 to about 1000 ppm by weight, a total concentration of coordinatively active P of at least about 0.01 mol/l, and a ratio of [P]/p.sub.co of at least 0.1 mmol/l/kPa, wherein [P] is the total concentration of coordinatively active phosphorous in the solution, and p.sub.co is the partial pressure of CO, to produce the corresponding C.sub.3 to C.sub.6 aldehydes. The process has utility for the hydroformylation of streams that contain olefins and alkynes.Type: GrantFiled: November 28, 1995Date of Patent: February 4, 1997Assignee: Exxon Research and Engineering CompanyInventors: Gabor Kiss, Michael G. Matturro, Harry W. Deckman, Istvan T. Horvath, Anthony M. Dean, Frank Hershkowitz, Raymond A. Cook
-
Patent number: 5463082Abstract: Stoichiometric and catalytic chemical transformations may be carried out in solution using novel fluorous multiphase systems (FMS). The term "fluorous" is defined as a carbon-fluorine bond rich organic molecule. The FMS consists of a fluorous phase containing a fluorous solvent, typically a fluorocarbon or a fluorohydrocarbon and a reagent or a catalyst containing a sufficient number of fluorous moieties to render it preferentially soluble in the fluorous solvent without impairing the ability of the catalyst or reagent to be effective in the reaction and while maintaining the reaction in a liquid or fluid phase. The nonfluorous solvent may be any suitable organic or nonorganic solvent(s) with limited or no solubility in the fluorous solvent that is effective for dissolving the reactant(s) and most desirably, for separating the resulting product(s). Typically, such solvents have a Hildebrand solubility parameter of at least about 18.0 MPa1/2.Type: GrantFiled: July 8, 1993Date of Patent: October 31, 1995Assignee: Exxon Research and Engineering CompanyInventors: Istvan T. Horvath, Jozsef Rabai
-
Patent number: 5354916Abstract: The invention relates to a process for selectively producing alkyl halides from alkanes, such as methane and ethane at low temperatures and low pressures. Optional hydrolysis to the corresponding alcohols may follow. The process involves adding an alkane and an added halogen source to an aqueous solution in a homogeneous system in the presence of a transition metal halide containing complex, for a time, under conditions and in effective amounts that will permit the formation of alkyl monohalides.Type: GrantFiled: January 24, 1994Date of Patent: October 11, 1994Assignee: Exxon Research and Engineering CompanyInventors: Istvan T. Horvath, John M. Millar, Raymond A. Cook
-
Patent number: 5276226Abstract: The invention relates to a process for selectively producing alkyl halides from alkanes, such as methane and ethane at relatively mild temperatures and pressures in an organic liquid phase in the presence of halogen and transition metal complex. The alkane may be neat if in a liquid form, or may be solubilized with a suitable organic solvent, if the alkane not a liquid at reaction conditions. The reaction is for a time, under conditions of temperature and pressure and in effective amounts that will permit the formation of alkyl halides. Optional hydrolysis to the corresponding alcohols may follow. The alkyl halides have utility as precursors for alternative fuels, such as methanol.Type: GrantFiled: October 5, 1992Date of Patent: January 4, 1994Assignee: Exxon Research & Engineering CompanyInventors: Istvan T. Horvath, Raymond A. Cook, Gabor Kiss
-
Patent number: 5171910Abstract: The present invention provides a catalyst for hydrogenation of aromatic compounds, which comprises a hydrophilic support material; and a stationary aqueous acid phase supported by the hydrophilic support material, the aqueous acid having a transition metal catalyst dissolved therein, Preferably, the solid hydrophilic support material is an acidic material, such as an acid-treated clay.The foregoing catalyst is particularly useful in hydrogenating aromatic hydrocarbons.Type: GrantFiled: October 11, 1991Date of Patent: December 15, 1992Assignee: Exxon Research and Engineering CompanyInventors: Istvan T. Horvath, Raymond A. Cook
-
Patent number: 5100851Abstract: The present invention provides a catalyst for hydrogenation of aromatic compounds, which comprises a hydrophilic support material; and a stationary aqueous acid phase supported by the hydrophilic support material, the aqueous acid having a transition metal catalyst dissolved therein. Preferably, the solid hydrophilic support material is an acidic material, such as an acid-treated clay. The foregoing catalyst is particularly useful in hydrogenating aromatic hydrocarbons.Type: GrantFiled: September 4, 1990Date of Patent: March 31, 1992Assignee: Exxon Research and Engineering CompanyInventors: Istvan T. Horvath, Raymond A. Cook