Abstract: Described herein is a method of producing a perovskite material on a substrate by LEP printing comprising: printing a composition comprising a salt AX and a resin in a carrier liquid; printing a composition comprising a salt selected from BX2 and in BX4 and a resin in a carrier liquid; and heat treating the printed compositions; or printing a composition comprising a material with a perovskite structure and a resin in a carrier liquid; wherein the resin comprises a copolymer of an alkylene monomer and a monomer having acidic side groups; and/or a copolymer of an alkylene monomer and an ethylenically unsaturated monomer comprising an epoxide; and/or a copolymer of an alkylene monomer, an ethylenically unsaturated monomer comprising an epoxide, and a monomer selected from a monomer having acidic side groups, a monomer having ester side groups and a mixture thereof. Also described is an ink set and a printed substrate.

Abstract: Described herein is a printed photovoltaic cell comprising an anode; an LEP printed cathode; and an LEP printed photovoltaic layer disposed between the anode and the cathode. The photovoltaic layer comprises a material with a perovskite structure having a chemical formula selected from ABX3 and A2BX6 and a thermoplastic resin comprising a copolymer of an alkylene monomer and a monomer having acidic side groups; and/or a copolymer of an alkylene monomer and an ethylenically unsaturated monomer comprising an epoxide; and/or a copolymer of an alkylene monomer, an ethylenically unsaturated monomer comprising an epoxide, and a monomer selected from a monomer having acidic side groups, a monomer having ester side groups and a mixture thereof. The printed cathode comprises: a thermoplastic resin; and electrically conductive metal particles. Also described herein is a method of producing the printed photovoltaic cell and an ink set for use in the method.

Abstract: Described herein is a liquid electrophotographic photovoltaic ink composition comprising: a dispersion of a material with a perovskite structure, a thermoplastic resin and conductive particles in a carrier liquid; wherein the material with a perovskite structure has a chemical formula selected from ABX3 and A2BX6; wherein A is a cation, B is a cation and X is an anion; and wherein the thermoplastic resin comprises: a copolymer of an alkylene monomer and a monomer having acidic side groups; and/or a copolymer of an alkylene monomer and an ethylenically unsaturated monomer comprising an epoxide; and/or a copolymer of an alkylene monomer, an ethylenically unsaturated monomer comprising an epoxide, and a monomer selected from a monomer having acidic side groups, a monomer having ester side groups and a mixture thereof. Also described is a method of producing a photovoltaic cell using the LEP ink and the printed cell produced by the method.

Abstract: Described herein is a liquid electrophotographic photovoltaic ink composition comprising: a dispersion of a material with a perovskite structure, a thermoplastic resin and conductive particles in a carrier liquid; wherein the material with a perovskite structure has a chemical formula selected from ABX3 and A2BX6; wherein A is a cation, B is a cation and X is an anion; and wherein the thermoplastic resin comprises: a copolymer of an alkylene monomer and a monomer having acidic side groups; and/or a copolymer of an alkylene monomer and an ethylenically unsaturated monomer comprising an epoxide; and/or a copolymer of an alkylene monomer, an ethylenically unsaturated monomer comprising an epoxide, and a monomer selected from a monomer having acidic side groups, a monomer having ester side groups and a mixture thereof. Also described is a method of producing a photovoltaic cell using the LEP ink and the printed cell produced by the method.

Abstract: Described herein is a printed photovoltaic cell comprising an anode; an LEP printed cathode; and an LEP printed photovoltaic layer disposed between the anode and the cathode. The photovoltaic layer comprises a material with a perovskite structure having a chemical formula selected from ABX3 and A2BX6 and a thermoplastic resin comprising a copolymer of an alkylene monomer and a monomer having acidic side groups; and/or a copolymer of an alkylene monomer and an ethylenically unsaturated monomer comprising an epoxide; and/or a copolymer of an alkylene monomer, an ethylenically unsaturated monomer comprising an epoxide, and a monomer selected from a monomer having acidic side groups, a monomer having ester side groups and a mixture thereof. The printed cathode comprises: a thermoplastic resin; and electrically conductive metal particles. Also described herein is a method of producing the printed photovoltaic cell and an ink set for use in the method.

Abstract: A method of producing a material with a perovskite structure on a substrate by liquid electrophotographic printing comprises: either liquid electrophotographically printing onto the substrate a composition comprising a dispersion of a salt AX and a thermoplastic resin in a carrier liquid; liquid electrophotographically printing onto the substrate a composition comprising a dispersion of a salt selected from BX2 and BX4 and a thermoplastic resin in a carrier liquid; and heat treating the printed compositions to form the material with a perovskite structure; or liquid electrophotographically printing onto the substrate a composition comprising a dispersion of a material with a perovskite structure and a thermoplastic resin in a carrier liquid to form the material with a perovskite structure; wherein A is a cation, B is a cation and X is an anion; wherein the thermoplastic resin comprises a copolymer of an alkylene monomer and a monomer having acidic side groups.

Abstract: Described herein is a yellow liquid electrophotographic ink composition comprising: a thermoplastic resin comprising a polymer having acidic side groups; and a colorant comprising a yellow pigment, wherein the yellow pigment comprises a hydrazone compound. Also described herein is a method of producing a printed substrate using the yellow liquid electrophotographic ink composition and a printed substrate produced therefrom.

Abstract: Herein are describes liquid electrophotographic ink compositions and methods for producing liquid electrophotographic ink composition. The liquid electrophotographic ink compositions may be producing using a method comprising: grinding a resin and a pigment to form a paste; reacting an aluminium C12-24 carboxylate and a molecule having a molecular weight (Mw) of less than about 1000 and comprising a functional group selected from an amide, an ester, a carboxylic acid, an amine, an imide and combinations thereof to form a charge promoting component; and combining the paste and the charge promoting component to form a liquid electrophotographic ink.