Abstract: A flexible, metallized, polyurethane foam has, incorporated therein, particles selected from copper and copper oxide in an amount, based on metallic copper, of at least 1% by weight of the total weight of the metallized foam. The copper can be incorporated into the foam by (a) mixing the particles with a polyol and reacting the polyol with a polyisocyanate in the presence of a foaming agent to form the flexible polyurethane foam, whereby the particles are incorporated in-situ within the foam; or (b) forming a slurry of the particles in a polymer latex medium and treating the foam with the said slurry to allow impregnation of the particles into the foam. An article for alleviation of discomfort from an ailment associated with a joint, limb or muscle contains the flexible polyurethane foam covered by a fabric.