Abstract: A process for alunite ore treatment which comprises roasting alunite in the presence of oxygen at a temperature of from 580.degree. to 620.degree. C. for 1 to 3 hours, decomposing the roasted alunite by exposure to reducing agents at a temperature of from 580.degree. to 620.degree. C., subjecting the reduced alunite to hydrochemical treatment by use of a sodium hydroxide solution of concentration from 100 to 150 g/lit in terms of Na.sub.2 O, decomposing the resultant aluminate liquor, with the aluminum hydroxide component precipitating out, and finally, washing and baking the aluminum hydroxide precipitate to obtain same as an end product. The invention provides a comprehensive method of treatment of alunite ores the associated rock whereof comprises silica in the form of opal and chalcedony earlier believed to be refractory to comprehensive treatment by alkaline methods.