Abstract: The present invention relates to a selective method for carrying out the Buchwald-Hartwig coupling of biphenyl derivatives.

Abstract: The present invention relates to a selective method for carrying out the Buchwald-Hartwig coupling of biphenyl derivatives.

Abstract: The invention relates to a process for preparing aryl- and heteroarylacetic acids and derivatives thereof by reaction of aryl or heteroaryl halides with malonic diesters in the presence of a palladium catalyst, of one or more bases and optionally of a phase transfer catalyst. This process enables the preparation of a multitude of functionalized aryl- and heteroarylacetic acids and derivatives thereof, especially also the preparation of arylacetic acids with sterically demanding substituents.

Abstract: The invention relates to a process for preparing aryl- and heteroarylacetic acids and derivatives thereof by reaction of aryl or heteroaryl halides with malonic diesters in the presence of a palladium catalyst, of one or more bases and optionally of a phase transfer catalyst. This process enables the preparation of a multitude of functionalized aryl- and heteroarylacetic acids and derivatives thereof, especially also the preparation of arylacetic acids with sterically demanding substituents.

Abstract: The invention relates to a process for preparing a propiolic acid or a derivative thereof by reacting a terminal alkyne with carbon dioxide, which comprises performing the reaction in the presence of a base and a copper complex, especially a copper (I) complex having at least one ligand, at least one of the ligands of the copper complex being selected from monodentate ligands which have an aminic or iminic nitrogen atom capable of coordination with copper, and polydentate ligands having at least two atoms or atom groups which are capable of simultaneous coordination with copper and are selected from nitrogen, oxygen, sulfur, phosphorus and carbene carbon.

Abstract: The invention relates to a process for preparing aryl- and heteroarylacetic acids and derivatives thereof by reaction of aryl or heteroaryl halides with malonic diesters in the presence of a palladium catalyst, of one or more bases and optionally of a phase transfer catalyst. This process enables the preparation of a multitude of functionalized aryl- and heteroarylacetic acids and derivatives thereof, especially also the preparation of arylacetic acids with sterically demanding substituents.

Abstract: The invention relates to a method for producing acetylenedicarboxylic acid by reaction of acetylene with carbon dioxide, wherein the reaction is carried out in the presence of a silver or copper salt and an amine base.

Abstract: The invention relates to a method for producing compositions containing unsaturated compounds, wherein (A) one or more unsaturated monocarboxylic acids having 10 to 24 C-atoms or esters of said monocarboxylic acids and optionally (B) one or more compounds having at least one C?C double bond (wherein the compounds (B) are different from the compounds (A)) are subjected to a tandem isomerization/metathesis reaction sequence in the presence of a palladium catalyst and a ruthenium catalyst, providing that the palladium catalysts used are compounds that contain at least one structural element Pd—P(R1R2R3), wherein the radicals R1 to R3, independently of one another, each comprise 2 to 10 C-atoms, which may be aliphatic, alicyclic, aromatic or heterocyclic respectively, providing that at least one of the radicals R1 to R3 contains a beta-hydrogen, wherein the palladium catalyst is used as such or is produced in situ, providing that the method is carried out in the absence of substances that have a pKa value of 3 or

Abstract: The invention relates to a process for preparing a propiolic acid or a derivative thereof by reacting a terminal alkyne with carbon dioxide, which comprises performing the reaction in the presence of a base and a copper complex, especially a copper (I) complex having at least one ligand, at least one of the ligands of the copper complex being selected from monodentate ligands which have an aminic or iminic nitrogen atom capable of coordination with copper, and polydentate ligands having at least two atoms or atom groups which are capable of simultaneous coordination with copper and are selected from nitrogen, oxygen, sulfur, phosphorus and carbene carbon.

Abstract: Aspects of the present invention relate to processes for preparing compositions comprising unsaturated compounds, wherein (A) one or more unsaturated monocarboxylic acids having 10-24 carbon atoms or esters of these monocarboxylic acids and (B) one or more unsaturated dicarboxylic acids having 4 to 20 carbon atoms or esters thereof are subjected to a tandem isomerization/metathesis reaction in the presence of a palladium catalyst and of a ruthenium catalyst, with the proviso that the palladium catalysts used are compounds which contain at least one structural element Pd—P(R1R2R3) where the R1-R3 radicals each independently have 2-10 carbon atoms, each of which may be aliphatic, alicyclic, aromatic or heterocyclic, with the proviso at least one of the R1-R3 radicals contains a beta-hydrogen, the palladium catalyst being used as such or generated in situ, with the proviso the process is performed in the absence of substances having a pKa of 3 or less.

Abstract: The invention pertains to a new route to prepare ?-functionalized carboxylic acid esters in a one-pot reaction, by reacting an olefinic acid ester in the presence of a catalyst system, comprising a Rh(I)-complex, together with an aryl boron or a diamine as nucleophilic compounds, and under oxygen-free conditions and elevated temperatures.

Abstract: A computer, for planning moves of freight automatically receives a plan containing a number of trips to be performed to move freight using vehicles, and partially releases only a portion of the plan for execution instead of releasing the entire plan. The plan portion that is released includes a subset of trips that are selected by the computer from among all trips in the entire plan. Thereafter, the computer simply repeats the just-described acts. Iteratively releasing portions of a plan allows the computer to be instructed to release early certain trips that are satisfactory. Trips that are sub-optimal are re-generated in a next version of the plan, based on changes in orders in the interim. The computer may also be instructed to release a trip even if sub-optimal, if its time-to-departure becomes less than an advance notice needed by a truckload service that is to execute the trip.

Abstract: A method and computer-executable instructions for performing a method of providing and selecting two or more objects on a display. The method utilizes a computer system having a graphical user interface including the display and a user interface selection device. The method displays a first of the two or more objects on the display, displays a second of the two or more objects on the display such that the second object overlaps and underlays the first object, blends the first and second object such that the portion of the second object which overlaps the first object is at least partially visible to a user, receives a user selection signal indicative of the user interface selection pointing device pointing to the overlapping portion of the first and second object, and processes the user selection as indicative of a selection of the underlying portion of the second object.

Abstract: A CPU module includes a host element configured to perform a high-level host-related task, and one or more data-generating processing elements configured to perform a data-generating task associated with the high-level host-related task. Each data-generating processing element includes logic configured to receive input data, and logic configured to process the input data to produce output data.

Abstract: A CPU module includes a host element configured to perform a high-level host-related task, and one or more data-generating processing elements configured to perform a data-generating task associated with the high-level host-related task. Each data-generating processing element includes logic configured to receive input data, and logic configured to process the input data to produce output data. The amount of output data is greater than an amount of input data, and the ratio of the amount of input data to the amount of output data defines a decompression ratio. In one implementation, the high-level host-related task performed by the host element pertains to a high-level graphics processing task, and the data-generating task pertains to the generation of geometry data (such as triangle vertices) for use within the high-level graphics processing task. The CPU module can transfer the output data to a GPU module via at least one locked set of a cache memory.

Abstract: A system and method provides a high level of system functionality in a multimedia console through the use of system applications, while reducing any corresponding lack of control that multimedia applications will have while running on the console. A predetermined amount of hardware resources of the multimedia console is reserved. The system application is executed substantially using the predetermined amount of reserved hardware resources and the multimedia application is executed substantially within the remaining unreserved hardware resources.

Abstract: The present invention provides a method and apparatus for rendering images on a computer screen. Under the invention, a portion of a base image is described using a path. The path is then transformed using a non-affine transform to produce a transformed path. The transformed path is then rendered onto the computer screen. Another aspect of the present invention is a method and apparatus for rendering curves of any order and any dimension. In particular, the present invention provides a means for converting a function of any order and any dimension that describes one segment of a curve into a function that describes a different sized segment or an adjoining segment.

Abstract: A CPU module includes a host element configured to perform a high-level host-related task, and one or more data-generating processing elements configured to perform a data-generating task associated with the high-level host-related task. Each data-generating processing element includes logic configured to receive input data, and logic configured to process the input data to produce output data. The amount of output data is greater than an amount of input data, and the ratio of the amount of input data to the amount of output data defines a decompression ratio. In one implementation, the high-level host-related task performed by the host element pertains to a high-level graphics processing task, and the data-generating task pertains to the generation of geometry data (such as triangle vertices) for use within the high-level graphics processing task. The CPU module can transfer the output data to a GPU module via at least one locked set of a cache memory.

Abstract: An image passthrough extension structure and method facilitating the transfer of compressed data image files from a software application to a device via the computer system operating system. The application determines whether the device is capable of decoding the specific compressed data file by polling the device driver. If the driver returns a “no support” message, the application processes the compressed data file in a conventional manner. If the driver returns a “support” message, the application transfers the compressed data file, along with the additional processing information, to the device driver utilizing the conventional file transfer operating system data structures modified to incorporate the compressed data file passthrough function.

Abstract: Methods, devices and systems for assigning a value associated with a manufacturing or service-related transaction to a task within an organizational logical structure includes a step of retrieving attributes of the transaction, such attributes including, for example, an identification of the item, whether the item was procured, the PO number, the category of the item and/or an identification of the sub-inventory, in the case of a material transaction. A plurality of predefined task assignment rules are then searched for a matching rule that includes respective criteria corresponding to each retrieved attribute. Each of the plurality of task assignment rules includes an identification of a task within the organizational logical structure. The value associated with the transaction may then be assigned to the task identified in the matching rule. The assigned value may include the cost associated with the transaction.