Abstract: The invention relates to a process for preparing a polyurea or a polyurethane organopolysiloxane block copolymer having a silicone content of at least 90% in weight relative to the total weight of the organosiloxane block copolymer. The invention further relates to a a polyurea or a polyurethane organopolysiloxane block copolymer obtained according to this process and its use in a method for manufacturing a 3D article by an additive technique.

Abstract: The present invention relates to a powder of spherical crosslinkable polyamide particles, which is suitable for the selective laser sintering (SLS) technique, and also to a process for obtaining such a powder of spherical crosslinkable polyamide particles. The present invention also relates to the production of articles by SLS, followed by a crosslinking step, using said powder of spherical crosslinkable polyamide particles.

Abstract: The invention relates to a 3D printable powder composition comprising a polyamide and less than 5 wt % by weight of at least one filler. The invention also relates to the process for preparing the 3D printable powder, and its use for the preparation of a 3D printed article.

Abstract: The present disclosure describes methods and systems for making three-dimensional printed objects. In one example, a method of making a three-dimensional printed object can include iteratively applying individual particulate build material layers to a powder bed. The particulate build material can include polymer particles that include a polyolefin and first nanoparticles compounded nanoparticles compounded with the polyolefin such that the first nanoparticles are embedded nanoparticles are embedded within the polymer particles. Second nanoparticles can be dry blended with the polymer particles. The first nanoparticles and second nanoparticles can include metal or metal oxide. The first and second nanoparticles can have a higher thermal conductivity that the polyolefin. A fusing agent including water and an electromagnetic radiation absorber can be selectively jetted onto the individual particulate build material layers.

Abstract: The present invention relates to a powder composition I comprising nanoparticles A blended with a polyolefinic powder II, said polyolefinic powder II containing particles B embedded in a polyolefinic matrix C, nanoparticles A being metal or metal oxide nanoparticles and particles B being metal, nitride, carbide or metal oxide micro or nanoparticles, said powder composition I containing at least 90 wt % of polyolefinic matrix C relative to the total weight of the powder composition I. The invention further relates to the preparation of said powder composition I and its use in an additive process for the preparation of a 3D printed article.

Abstract: The invention relates to 3D printable powders comprising 75-98 wt% of a polymeric matrix containing at least 90 wt % of polyolefin(s) and 2-25 wt% of at least one olefinic thermoplastic elastomer chosen from ethylene acetate elastomers, ethylene acrylate elastomers, ethylene propylene elastomers and ethylene alpha-olefin elastomers. The invention further relates to the preparation of these 3D printable powders and to their use in an additive process.

Abstract: The invention relates to a process for preparing a polyurea or a polyurethane organopolysiloxane block copolymer having a silicone content of at least 90% in weight relative to the total weight of the organosiloxane block copolymer. The invention further relates to a polyurea or a polyurethane organopolysiloxane block copolymer obtained according to this process and its use in a method for manufacturing a 3D article by an additive technique.

Abstract: The present invention relates to a powder of spherical crosslinkable polyamide particles, which is suitable for the selective laser sintering (SLS) technique, and also to a process for obtaining such a powder of spherical crosslinkable polyamide particles. The present invention also relates to the production of articles by SLS, followed by a crosslinking step, using said powder of spherical crosslinkable polyamide particles.

Abstract: The present invention provides a powder of spherical particles of crosslinkable polyamide suitable for the technique of selective laser sintering (SLS), and also a process for the production of such a powder of spherical particles of crosslinkable polyamide. The present invention also provides the production of articles by SLS, followed by a crosslinking step, starting from said powder of spherical particles of crosslinkable polyamide.

Abstract: The present invention provides a powder of spherical particles of crosslinkable polyamide suitable for the technique of selective laser sintering (SLS), and also a process for the production of such a powder of spherical particles of crosslinkable polyamide. The present invention also provides the production of articles by SLS, followed by a crosslinking step, starting from said powder of spherical particles of crosslinkable polyamide.

Abstract: The present invention relates to a method for manufacturing thermoplastic polyurethane pellets by means of reactive extrusion of: a long macrodiol with a molecular weight of 500 to 3000 g/mol; a diisocyanate; at least one chain extender comprising a dianhydrohexitol; and a polymerization catalyst. The invention also relates to the resulting thermoplastic polyurethane pellets.

Abstract: The object of the invention is a method for preparing a polyamide from one or several monomers adapted for the preparation of polyamide characterized in that the selected monomer(s), is(are) introduced without any preliminary reaction and without any preliminary preparation of the corresponding salt, in an extruder including at least two conveying screws rotating co-rotatively and in that all the reaction and polycondensation steps, initially starting from the selected monomer(s), and giving the possibility of ending up with the desired polyamide, are conducted in an extruder including at least two conveying screws rotating co-rotatively, and polycondensation is achieved by carrying out at least two operations for discharging the by-product(s) formed by the polycondensation reaction.

Abstract: The object of the invention is a method for preparing a polyamide from one or several monomers adapted for the preparation of polyamide characterized in that the selected monomer(s), is(are) introduced without any preliminary reaction and without any preliminary preparation of the corresponding salt, in an extruder including at least two conveying screws rotating co-rotatively and in that all the reaction and polycondensation steps, initially starting from the selected monomer(s), and giving the possibility of ending up with the desired polyamide, are conducted in an extruder including at least two conveying screws rotating co-rotatively, and polycondensation is achieved by carrying out at least two operations for discharging the by-product(s) formed by the polycondensation reaction.

Abstract: A novel starch-based composition includes: (a) at least 45% by weight of at least one soluble starch, (b) at most 55% by weight of at least one non-biodegradable, non-amylaceous polymer, and (c) a bonding agent carrying at least two functional groups capable of reacting with molecules carrying functions including an active hydrogen, these amounts being expressed with respect to solids and relative to the sum of (a) and (b). A method for preparing such a starch-based composition and a thermoplastic composition prepared by heating such a composition are also described.

Abstract: Process for preparing a composition based on a synthetic polymer includes: introducing, into a reactor containing a softened or molten synthetic polymer, a non-plasticized starchy component and a plasticizer of the latter; and kneading the mixture obtained under conditions sufficient to obtain the plasticization of the starchy component by the plasticizer, and a homogeneous mixture of the synthetic polymer and of the plasticized starchy component. The reactor may especially be a co-rotating or counter-rotating single-screw or twin-screw extruder, for example a co-rotating twin-screw extruder. The synthetic polymer may advantageously be chosen from the group including polyethylenes (PE) and polypropylenes (PP), which are functionalized or unfunctionalized, polyamides (PA), thermoplastic polyurethanes (TPU), styrene-ethylene-butylene-styrene (SEBS) copolymers, preferably that are functionalized, amorphous polyethylene terephthalates (PETG) and blends thereof.

Abstract: The present invention relates to a method for preparing novel thermoplastic amylaceous compositions, as well as to such thermoplastic amylaceous compositions.

Abstract: Process for preparing a composition based on a synthetic polymer includes: introducing, into a reactor containing a softened or molten synthetic polymer, a non-plasticized starchy component and a plasticizer of the latter; and kneading the mixture obtained under conditions sufficient to obtain the plasticization of the starchy component by the plasticizer, and a homogeneous mixture of the synthetic polymer and of the plasticized starchy component. The reactor may especially be a co-rotating or counter-rotating single-screw or twin-screw extruder, for example a co-rotating twin-screw extruder. The synthetic polymer may advantageously be chosen from the group including polyethylenes (PE) and polypropylenes (PP), which are functionalized or unfunctionalized, polyamides (PA), thermoplastic polyurethanes (TPU), styrene-ethylene-butylene-styrene (SEBS) copolymers, preferably that are functionalized, amorphous polyethylene terephthalates (PETG) and blends thereof.

Abstract: A thermoplastic and/or elastomer composition includes: at least 50 wt % and 99.95 wt % at most of a starchy composition (a) including at least one starch; at least 0.05 wt % and 50 wt % at most of a nanometric product (b) including particles having at least one dimension of 0.1 to 500 nanometers and selected from mixed products containing at least one lamellar clay and at least one cationic oligomer or cationic synthetic polymer, organic, mineral or mixed nanotubes, organic, mineral or mixed nanocrystals and nanocrystallites, organic, mineral or mixed nanobeads and nanospheres customized into clusters or agglomerated, and mixtures of these nanometric products, the percentage being expressed in dry weight and added to the sum in dry weight of (a) and (b); and at least one non-starchy polymer (c).

Abstract: A method for preparing a starch-based thermoplastic composition, includes the following steps: (a) selecting at least one granular starch and at least one organic plasticizer for this starch, (b) preparing a plasticized composition by thermomechanically mixing this starch and this plasticizer, (c) optionally incorporating at least one functional substance carrying functions including an active hydrogen, (d) incorporating at least one bonding agent carrying at least two functional groups capable of reacting with molecules carrying functions including an active hydrogen, and optionally (e) heating the mixture to a temperature sufficient to cause the bonding agent to react with the plasticizer and with the starch and/or the functional substance, it being possible for steps (d) and (e) to be carried out simultaneously, and also a starch-based thermoplastic composition that can be obtained by this method.

Abstract: A starch-based composition includes: (a) at least 51% by weight of a plasticized amylaceous composition including starch and a plasticizer for the starch, obtained by thermomechanically mixing granular starch and a plasticizer for the starch, (b) at most 49% by weight of at least one non-amylaceous polymer, and (c) a bonding agent having a molecular mass of less than 5000, including at least two functions, at least one which is capable of reacting with the plasticizer and at least another of which is capable of reacting with the starch and/or the non-amylaceous polymer, these amounts being expressed with respect to solids and relative to the sum of (a) and (b), a method for preparing such a composition and a thermoplastic composition obtained by heating such a composition.