Abstract: The present invention relates to polymerizable compositions which contain components that can be crosslinked both via isocyanurate bonds and by a radical reaction mechanism. The invention further relates to methods by way of which polymers can be produced from said compositions.

Abstract: The present invention relates to polymerizable compositions which contain components that can be crosslinked both via isocyanurate bonds and by a radical reaction mechanism. The invention further relates to methods by way of which polymers can be produced from said compositions.

Abstract: A process for producing an object from a precursor comprises the steps of: I) depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; II) depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; III) repeating step II) until the precursor is formed; wherein the depositing of a free-radically crosslinked resin at least in step II) is effected by exposure and/or irradiation of a selected region of a free-radically crosslinkable resin corresponding to the respectively selected cross section of the object and wherein the free-radically crosslinkable resin has a viscosity (23° C., DIN EN ISO 2884-1) of ?5 mPas to ?100000 mPas.

Abstract: A process for producing an object from a precursor comprises the steps of: depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; repeating step II) until the precursor is formed; wherein the depositing of a free-radically crosslinked resin at least in step II) is effected by exposure and/or irradiation of a selected region of a free-radically crosslinkable resin corresponding to the respectively selected cross section of the object and wherein the free-radically crosslinkable resin has a viscosity (23° C., DIN EN ISO 2884-1) of ?5 mPas to ?100000 mPas.

Abstract: A method for producing an article in which a layer with a radically cross-linkable resin is selectively crosslinked at least partially. This takes place according to a selected cross section of the article to be formed by means of selective application of a radical initiator. The at least partially crosslinked material is added on layer by layer to a carrier or to previous layers bonded to the carrier. A system that is suitable for carrying out the method according to the invention has a substrate, a control unit, an application unit for applying the resin to the substrate, an application unit for applying an initiator to the resin, an energy exposure unit and a contacting unit.

Abstract: The invention relates to a process for producing polyisocyanurate plastics having a functionalized surface, comprising the following steps: a) providing a polyisocyanate composition A) containing monomeric and/or oligomeric polyisocyanates; b) catalytically trimerizing the polyisocyanate composition A) so as to obtain a bulk polyisocyanurate material as intermediate; c) surface functionalizing the intermediate by contacting at least one surface of the intermediate with at least one functionalizing reagent D); d) continuing the catalytic trimerization. The invention further relates to a polyisocyanurate plastic having a functionalized surface obtainable from the process of the invention.

Abstract: A process for producing an object from a precursor comprises the steps of: depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; repeating step II) until the precursor is formed; wherein the depositing of a free-radically crosslinked resin at least in step II) is effected by exposure and/or irradiation of a selected region of a free-radically crosslinkable resin corresponding to the respectively selected cross section of the object and wherein the free-radically crosslinkable resin has a viscosity (23° C., DIN EN ISO 2884-1) of ?5 mPas to ?100000 mPas.

Abstract: The present invention relates to a method for adhesively bonding substrates, said method comprising the following steps: I) at least one adhesive component (a) and at least one isocyanate component (b) are applied between at least two substrates; II) the substrates are pressed together. The method is characterized in that in step I), the adhesive component and the isocyanate component are applied separately to the substrate. The invention further relates to a composite obtained according to said method. In a preferred embodiment, an aqueous polyurethane dispersion or a polyurethane solution in organic solvents is used as the adhesive component.

Abstract: A process for in-mold coating and a mold is disclosed. The process entails (i) obtaining a mold having at least two cavities, (ii) molding a thermoplastic substrate in a first cavity, (iii) introducing the substrate into a second cavity, and (iv) coating said substrate with lacquer, the coating being carried out under enhanced pressure.

Abstract: The invention relates to hybrid dispersions comprising nitrocellulose-polyurethanepolyurea particles (NC-PU dispersions) with accelerated drying behavior as compared with the known systems, and also to their use in coating materials.

Abstract: The present invention relates to two-component compositions containing A) hydroxyl-containing polydimethylsiloxanes having number average molecular weights of 400 to 3000 and an average OH functionality of ?1.8, and containing at least one structural unit of formula I) wherein R is an aliphatic, linear or branched C1 to C20 radical, R1 is a linear or branched hydroxyalkyl radical having 2 to 10 carbon atoms and R2 is either hydrogen or a linear or branched hydroxyalkyl radical having 2 to 10 carbon atoms, B) polyhydroxyl compounds other than A) or polyamines, and C) polyisocyanates. The present invention also relates to coatings, adhesives or sealants obtained from these compositions.

Abstract: Binder combinations containing polyisocyanates, special lactone-based polyols and polyester polyols and to their use for producing coatings, preferably on plastics.

Abstract: High-solids binder combinations comprising polyisocyanates, special lactone-based polyols and polyacrylate-polyols, a process for preparing such binders, and their use for producing coatings. The lactone-based polyols include ?-caprolactone-based polyols having an average hydroxy functionality ?2 and a number-average molecular weight of from 119 to 2000 g/mol. The polyacrylate resins are prepared by copolymerizing optionally functional polybutadienes, aromatic monomers, hydroxyalkyl esters of acrylic or methacrylic acid having primary hydroxyl groups, aliphatic esters of acrylic or methacrylic acid and C1 to C8 monoalcohols, ?,?-unsaturated C3–C7 monocarboxylic or dicarboxylic acids or of one or more monoesters of maleic acid or fumaric acid and C1 to C14 monoalchols.

Abstract: The present invention relates to a process for producing an aliphatic oligocarbonate diol comprising a) reacting an aliphatic diol with dimethyl carbonate at an elevated pressure in a reaction mixture, and b) subsequently removing unreacted methanol and dimethyl carbonate under a reduced pressure to uncap the terminal OH groups.

Abstract: The present invention provides polyamines which contain urea groups, a process for the preparation thereof and their use to produce adhesives, sealants, embedding compounds, moulded items or coatings.

Abstract: The invention relates to new blocked polyurethane prepolymers, a process for their production and reactive systems produced therefrom that harden at room temperature, and their use.

Abstract: The present invention relates to novel solventless reactive systems curable at room temperature, based on blocked polyisocyanates, primary amines, compounds with oxirane groups, and 2,3-dimethyl-3,4,5,6-tetrahydropyrimidine, and to processes for the preparation of these solventless reactive systems curable at room temperature.

Abstract: The present invention relates to aliphatic oligocarbonate polyols prepared by the transesterification of organic carbonates with aliphatic polyols in the presence of at least one catalyst which contains i) at least one rare earth metal or compounds thereof or ii) at least one metal of group III B of the periodic table of the elements or compounds thereof or iii) mixtures of i) and ii) and to a process for preparing the same.

Abstract: A process for the production of aliphatic oligocarbonate diols is disclosed. The optionally catalyzed high yield process entails the multistage transesterification of aliphatic diols with dimethyl carbonate. In the process DMC-methanol mixtures that have been distilled off are recycled to the reaction solution with further conversion and depletion of the contained DMC in the same or in a following reaction batch.

Abstract: The present invention relates to a process for producing an aliphatic oligocarbonate diol comprising a) reacting an aliphatic diol with dimethyl carbonate at an elevated pressure in a reaction mixture, and b) subsequently removing unreacted methanol and dimethyl carbonate under a reduced pressure to uncap the terminal OH groups.