Abstract: A process for manufacturing of an alkanesulfonic acid, and an alkanesulfonic acid manufactured by the process. Aspects of the process may involve manufacturing an alkanesulfonic acid by reaction of an initiator composition with an alkane and sulfur trioxide by preparing an initiator composition by reacting aqueous hydrogen peroxide with alkanesulfonic acid and/or H2SO4; and reacting the initiator composition with sulfur trioxide and alkane to form an alkanesulfonic acid, wherein an alkane with a purity of at least 98.0 mol-% is used.

Abstract: The invention relates to a method for operating a linearly concentrating solar power plant (1), in which a heat transfer medium flows through a pipeline loop (47) having at least one receiver, the heat transfer medium having a flow velocity which is such that the flow in the pipeline loop (47) is turbulent, at least part of the heat transfer medium, upon exit from the pipeline loop (47), being extracted and recirculated into the pipeline loop (47). Furthermore, the invention relates to a linearly concentrating solar power plant with at least one pipeline loop (47) having at least one receiver in which a heat transfer medium flowing through the pipeline loop (47) is heated by irradiating solar energy, a mixing device (27) being comprised, in which at least part of the heat transfer medium flowing through the pipeline loop (47) is mixed with heat transfer medium to be delivered.

Abstract: A heat transfer or storage medium containing a nitrate salt composition including at least one alkali metal nitrate and optionally alkaline earth metal nitrate; and, at least one alkali metal nitrite and optionally alkaline earth metal nitrite in an amount of 1.1 to 15.0 mol %. The molar amount of the alkali metal nitrite and optionally alkaline earth metal nitrite for a desired temperature is calculated by x nitrite = K 6 ? ( T ) K 6 ? ( T ) + P O ? ? 2 Xnitrite is the mole fraction of nitrite, K6(T) is the temperature-dependent equilibrium constant of the reaction nitrate ?nitrite+½ oxygen (NO3?? NO2?+½ O2), pO2 is the oxygen partial pressure and T is the temperature of the nitrate salt composition.

Abstract: A process for manufacturing of an alkanesulfonic acid, and an alkanesulfonic acid manufactured by the process. Aspects of the process may involve manufacturing an alkanesulfonic acid by reaction of an initiator composition with an alkane and sulfur trioxide by preparing an initiator composition by reacting aqueous hydrogen peroxide with alkanesulfonic acid and/or H2SO4; and reacting the initiator composition with sulfur trioxide and alkane to form an alkanesulfonic acid, wherein an alkane with a purity of at least 98.0 mol-% is used.

Abstract: The present invention relates to a process for the manufacturing of methane sulfonic acid (MSA) by reaction of a radical initiator composition with methane and sulfur trioxide comprising the steps (a) preparation of the intiator composition by reacting aqueous hydrogen peroxide with the components methane sulfonic acid and methane sulfonic acid anhydride and (b) reaction of the initiator composition from step (a) with sulfur trioxide and methane to form methane sulfonic acid. The invention further relates to the use of methane sulfonic acid anhydride (MSA anhydride) in said process and to methane sulfonic acid manufactured by said process.

Abstract: The present invention deals with a process for the production of alkanesulfonic acids, in particular methanesulfonic acid, and a method of purification of the raw products.

Abstract: A process for purifying alkanesulfonic anhydride that includes feeding a stream containing alkanesulfonic anhydride, sulfuric acid, high boilers and residual low boilers into a melt crystallization to form crystals of the alkanesulfonic anhydride suspended in mother liquor, and solid-liquid separation to remove the crystals from the mother liquor.

Abstract: The present invention relates to a process for the manufacturing of methane sulfonic acid (MSA) by reaction of a radical initiator composition with methane and sulfur trioxide comprising the steps (a) preparation of the intiator composition by reacting aqueous hydrogen peroxide with the components methane sulfonic acid and methane sulfonic acid anhydride and (b) reaction of the initiator composition from step (a) with sulfur trioxide and methane to form methane sulfonic acid. The invention further relates to the use of methane sulfonic acid anhydride (MSA anhydride) in said process and to methane sulfonic acid manufactured by said process.

Abstract: The present invention deals with a process for the production of alkanesulfonic acids, in particular methanesulfonic acid, and a method of purification of the raw products.

Abstract: At least two series-connected storage cells have hot liquid supplied to or removed from a first cell and cold liquid supplied to, or removed from, a final cell. The liquid temperature decreases from the first cell to the final cell. Individual cells are connected from the warmer cell lower region to the colder cell upper region. At least one cell is closed by a cover forming a gas space between the liquid and the cover. A gas line branches off from the gas space entering into the liquid of a colder cell or into the liquid in the connection of two adjacent cells. At least one of the adjacent cells has a lower temperature than that of the cell from the gas space of which the gas line branches off.

Abstract: A process comprising: (a) distilling a melt comprising crude alkanesulfonic acid to completely or partly remove low boilers, wherein the low boilers are drawn off at the top of a distillation column or of a one-stage evaporation apparatus and a material stream comprising alkanesulfonic acid, high boilers and residual low boilers is withdrawn at the bottom of the distillation column or of the one-stage evaporation apparatus, (b) sending the stream comprising alkanesulfonic acid, high boilers and residual low boilers into a melt crystallization as the starting melt to obtain crystals formed from the alkanesulfonic acid, hydrates of the alkanesulfonic acid or a mixture of both suspended in mother liquor, (c) performing a solid-liquid separation to remove the crystals from the mother liquor, and (d) optionally washing the crystals to remove mother liquor adhering to the crystals.

Abstract: A process for purifying alkanesulfonic anhydride which includes: (a) feeding a stream containing alkanesulfonic anhydride, sulfuric acid, high boilers and residual low boilers into a melt crystallization to form crystals of the alkanesulfonic anhydride suspended in mother liquor, (b) performing a solid-liquid separation to remove the crystals from the mother liquor, and (c) optionally washing the crystals to remove mother liquor adhering to the crystals.

Abstract: A pipeline system in a linearly concentrating solar power station comprises at least one pipeline which is connected at one end to a converger and at a second end to a distributor. The converger and the distributor are arranged at a different geodetic height. When the converger lies on top pressurized gas can be fed into the converger and the distributor is connected to a drainage container. When the distributor lies on top pressurized gas can be fed into the distributor and the converger is connected to a drainage container. The drainage container is lower than the converter and the distributor.

Abstract: The invention relates to a solar power plant with a first heat transfer medium circuit and with a second heat transfer medium circuit, in which the first heat transfer medium circuit comprises a store (3) for hot heat transfer medium and a store (5) for cold heat transfer medium and also a pipeline system (6) connecting the stores (3, 5) for hot heat transfer medium and for cold heat transfer medium and leading through a solar array (7), and the second heat transfer medium circuit comprises a pipeline system (9) connecting the stores (3, 5) for hot heat transfer medium and for cold heat transfer medium and in which at least one heat exchanger (11) for the evaporation and superheating of water is accommodated, the at least one heat exchanger (11) having a region through which the heat transfer medium flows and a region through which water flows, said regions being separated by a heat-conducting wall, so that heat can be transmitted from the heat transfer medium to the water.

Abstract: Use of a nitrate salt composition Z comprising Z1 at least one alkali metal nitrate and optionally alkaline earth metal nitrate and also Z2 at least one alkali metal nitrite and optionally alkaline earth metal nitrite in an amount of Z2 in the range from 1.1 to 15.0 mol % based on the sum of Z1 plus Z2 as heat transfer or heat storage medium in apparatuses in which these heat transfer or heat storage media are comprised at a temperature in the range from 500 to 620° C. and an oxygen partial pressure over the nitrate salt composition in the range from 0.1 to 1.

Abstract: The invention relates to a method of reprocessing alkanesulfonic acid employed in a chemical process as an agent, catalyst or solvent and comprising the steps of: (a) removing an alkanesulfonic acid-comprising stream from a reaction mixture generated in the chemical process, (b) feeding the alkanesulfonic acid-comprising stream into a melt crystallization as the starting melt to form crystals of the alkanesulfonic acid, of hydrates of the alkanesulfonic acid or of a mixture of both suspended in mother liquor, (c) performing a solid-liquid separation to remove the crystals from the mother liquor, (d) optionally washing the crystals to remove mother liquor adhering to the crystals, (e) recycling the washed or unwashed crystals removed from the mother liquor into the chemical process.

Abstract: The invention relates to a device for storing heat, comprising a heat storage medium which absorbs heat in order to store heat and releases heat in order to use the stored heat, and a container for holding the heat storage medium, the container being closed by a gastight cover, and the device comprising volume compensation means in order to compensate for a volume increase of the heat storage medium (3) due to a temperature rise and a volume decrease due to a temperature reduction.

Abstract: The invention relates to a method of reprocessing alkanesulfonic acid employed in a chemical process as an agent, catalyst or solvent and comprising the steps of: (a) removing an alkanesulfonic acid-comprising stream from a reaction mixture generated in the chemical process, (b) feeding the alkanesulfonic acid-comprising stream into a melt crystallization as the starting melt to form crystals of the alkanesulfonic acid, of hydrates of the alkanesulfonic acid or of a mixture of both suspended in mother liquor, (c) performing a solid-liquid separation to remove the crystals from the mother liquor, (d) optionally washing the crystals to remove mother liquor adhering to the crystals, (e) recycling the washed or unwashed crystals removed from the mother liquor into the chemical process.

Abstract: The invention relates to a device for heat transfer, comprising a low temperature heat exchanger (3) and a high temperature heat exchanger (5), the heat exchangers (3, 5) being connected to one another by means of a connecting line such that a heat transfer medium flows through the high temperature heat exchanger (5) and through the low temperature heat exchanger (3) in succession, at least one dwell time tank (19) being arranged in the connecting line.

Abstract: The invention relates to a process for purifying alkanesulfonic acids which comprises the steps of: (a) distilling a melt comprising crude alkanesulfonic acid (1) to completely or partly remove low boilers, wherein the low boilers are drawn off at the top of a distillation column (3) or of a one-stage evaporation apparatus and a material stream (7) comprising alkanesulfonic acid, high boilers and residual low boilers is withdrawn at the bottom of the distillation column (3) or of the one-stage evaporation apparatus, (b) sending the stream (7) comprising alkanesulfonic acid, high boilers and residual low boilers into a melt crystallization (9) as the starting melt to form crystals of the alkanesulfonic acid, of hydrates of the alkanesulfonic acid or of a mixture of both suspended in mother liquor, (c) performing a solid-liquid separation to remove the crystals from the mother liquor, (d) optionally washing the crystals to remove mother liquor adhering to the crystals.