Abstract: A multilayer cation exchange membrane for use in a chloralkali process comprising an carboxylate layer comprising a fluorinated ionomer containing carboxylate groups on one side of the membrane, an exterior sulfonate layer comprising a fluorinated ionomer containing sulfonate groups on the side of the membrane opposite the carboxylate layer, and an interior sulfonate layer comprising a fluorinated ionomer containing to sulfonate groups between the carboxylate layer and the exterior sulfonate layer, the exterior sulfonate layer having an ion exchange ratio greater than about 11.3, and the interior sulfonate layer having an ion exchange ratio less than about 11.