Abstract: This invention relates to the application of fluorinated urethane compositions to stone in order to protect the stone from the deleterious effects of water and pollution.

Abstract: This invention relates to the application of fluorinated urethane compositions to stone in order to protect the stone from the deleterious effects of water and pollution.

Abstract: Fluorinated diesters useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae Rf—O—C(O)—(CH2)n—C(O)—O—R1; Rf—O—C(O)—CH2—CH(R2)—C(O)—O—Rf; a mixture of Rf—O—C(O)—(CH2)n—C(O)—O—R1, Rf—O—C(O)—(CH2)n—C(O)—Rf, and R1—O—C(O)—(CH2)n—C(O)—O—R1; and [F(CF2)xCH2CH2—S—CH2]2—C—[CH2—O—C(O)—C17H35]2; wherein Rf is F(CF2)x—(CH2)m wherein x is 4 to 20 and m is 2 to 6, or F(CF2)x—SO2N(R3)—R4 wherein x is 4 to 20; R1 is a saturated aliphatic hydrocarbon with an average carbon chain length of 12 to 66 carbons; R2 is a saturated or unsaturated hydrocarbon with 1-20 carbon atoms; R3 is an alkyl radical having 1 to 4 carbon atoms; R4 is an alkylene radical having 1 to 12 carbon atoms; n is 1 to 20, and x is 4 to 20 are disclose

Abstract: Fluorinated diesters useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulaeR.sub.f --O--C(O)--(CH.sub.2).sub.n --C(O)--O--R.sub.1 ;R.sub.f --O--C(O)--CH.sub.2 --CH(R.sub.2)--C(O)--O--R.sub.f ;a mixture of R.sub.f --O--C(O)--(CH.sub.2).sub.n --C(O)--O--R.sub.1,R.sub.f --O--C(O)--(CH.sub.2).sub.n --C(O)--R.sub.f, and R.sub.1 --O--C(O)--(CH.sub.2).sub.n --C(O)--O--R.sub.1 ;and [F(CF.sub.2).sub.x CH.sub.2 CH.sub.2 --S--CH.sub.2 ].sub.2 --C--[CH.sub.2 --O--C(O)--C.sub.17 H.sub.35 ].sub.2 ;wherein R.sub.f is F(CF.sub.2).sub.x --(CH.sub.2).sub.m wherein x is 4 to 20 and m is 2 to 6, or F(CF.sub.2).sub.x --SO.sub.2 N(R.sub.3)--R.sub.4 wherein x is 4 to 20; R.sub.1 is a saturated aliphatic hydrocarbon with an average carbon chain length of 12 to 66 carbons; R.sub.2 is a saturated or unsaturated hydrocarbon with 1-20 carbon atoms; R.sub.3 is an alkyl radical having 1 to 4 carbon atoms; R.sub.

Abstract: Coating compositions containing an alkyd, urethane or unsaturated polyester resin, and an ester of an unsaturated acid and a fluorinated alcohol wherein the cured coating has an advancing hexadecane contact angle of at least about 40 degrees and durable improved oil and water repellency is disclosed.

Abstract: A coating composition comprising an alkyd or urethane resin and a polyfluorourethane of Formula II(R.sub.f --X--O--CO--NH).sub.m --A--(NH--CO--O--R).sub.(p-m) IIwhereinR.sub.f is a C.sub.2 -C.sub.20 linear or branched fluorocarbon,X is --(CH.sub.2).sub.n --, --(CH.sub.2).sub.g SO.sub.z (CH.sub.2).sub.t --, or --SO.sub.2 N(R.sub.1)CH.sub.2 CH.sub.2 --wherein n is 1 to about 20; g and t are each independently 1 to about 3; z is 0, 1 or 2; and R.sub.1 is an alkyl of 1 to about 4 carbon atoms;A is an aliphatic, cycloaliphatic, aromatic, or heterocyclic radical;R is a C.sub.3 -C.sub.20 linear, branched, or cyclic aliphatic group containing at least one ethylenically unsaturated double bond and optionally at least one phenyl or phenyl substituted with C.sub.1 -C.sub.6 alkyl or halogen;p is 2 to 3; andm is from about 0.8 to about 1.25 when p is 2, and m is from about 1 to about (p-1) when p is greater than 2 is disclosed.

Abstract: Coating compositions containing an alkyd, urethane or unsaturated polyester resin and an ester of an unsaturated alcohol and fluorinated acid wherein the cured coating has an advancing hexadecane contact angle of at least about 40 degrees and improved oil and water repellency is disclosed.