Abstract: A composite film comprises first and second layers. The first layer comprises a first copolymer of monomers comprising tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride, wherein the first copolymer contains at least 35 mole percent of vinylidene fluoride monomer units. The second layer is disposed on the first layer, and comprises a second copolymer comprising 50 to 83 weight percent of ethylene monomer units and at least 17 weight percent of alkyl (meth)acrylate monomer units represented by the formula (I) wherein R1 is H or methyl, and each R2 is independently an alkyl group having from 1 to 4 carbon atoms. Methods of making the composite film and articles including it are also disclosed.

Abstract: A method of making an adhesive article is described comprising melt extruding a core film layer comprising a composition comprising at least 50% of a polylactic acid polymer. The method further comprises melt extruding an adhesive layer on a major surface of the core film layer such that regions of interdiffusion are present between the core film layer and adhesive layer. The adhesive layer may comprise C1-C10 (meth)acrylic acid or ester thereof, vinyl acetate, ethylene vinyl acetate, hydrolysed polyvinyl alcohol and combinations thereof. The adhesive layer may also be a pressure sensitive adhesive. The method further comprises melt extruding a release film layer on an opposing major surface of the core film layer. The layers are sequentially extruded or co-extruded and can be uniaxially or biaxially oriented.

Abstract: A multilayer fluoropolymer film comprising, in order: a first layer comprising a first polymer, the first polymer comprising at least 35 mol percent tetrafluoroethylene comonomer, at least 15 mole percent vinylidene fluoride comonomer, and at least 5 mol percent hexafluoropropylene comonomer, based on the total mol percent of the first polymer; a second layer comprising a second polymer, the second polymer comprising at least 50 mol percent vinylidene fluoride comonomer, based on the total mol percent of the second polymer; and a third layer comprising a third polymer, the third polymer comprising at least 50 mol percent methylmethacrylate comonomer, based on the total mol percent of the third polymer. The multilayer fluoroplymer films are useful for example, in multi-layer film applications (e.g., traffic sign protection, commercial graphic protection, paint protection, windows, windshields, building exteriors, and photo voltaics).

Abstract: Multilayer films and adhesive tapes that include such films, wherein the multilayer films include plasticized polyvinyl chloride and optionally one or more fillers.

Abstract: Polymeric multilayer material includes an adhesive layer having first and second opposed major surfaces. A first foam layer is joined to the first major surface and includes a first plurality of expandable microspheres. A first skin layer is attached to the first foam layer and is free of the first plurality expandable microspheres. A second foam layer is joined to the second major surface of the internal adhesive layer and includes a second plurality of expandable microspheres dispersed therein. A second skin layer is attached to the second foam layer and is free of the second plurality of expandable microspheres. A portion of the first expandable microspheres of the first foam layer and of the second foam layer is at least partially embedded within the adhesive layer. Embodiments, of polymeric multilayer materials described herein are useful, for example, as wearable medical or athletic support components. The materials can also be used as protective wrappings.

Abstract: Film constructions and articles including the film constructions, wherein a film construction includes: a backing (or an adhesive layer) having a first major surface and a second major surface; and a release layer disposed on the first major surface of the backing (or adhesive layer), wherein the release layer includes polylactic acid.

Abstract: Article comprising first and second continuous polymeric layers having at least one polymeric layer exhibiting a random network of strands and connective regions disposed between the first and second continuous polymeric layers. In some embodiments, the article is a tape and polymeric multilayer film having a slip resistant surface.

Abstract: Polymeric multilayer film comprising a layer comprising a first pressure sensitive adhesive and exhibiting a random network of strands and connective regions. The polymeric multilayer films are useful, for example, for tape and graphic articles.

Abstract: Polymeric multilayer film comprising a layer exhibiting a random network of strands and connective regions that is separable from the remaining polymeric multilayer film. The polymeric multilayer films are useful, for example, for tape and graphic articles.

Abstract: Polymeric multilayer film comprising at least two adjacent layers each exhibiting a random network of strands and connective regions. The polymeric multilayer films are useful, for example, for tape and graphic articles.

Abstract: Adhesive tapes include a plasticized polyvinyl chloride backing, a primer including an ethylene/carbon monoxide-containing terpolymer and a styrene-containing block copolymer and an epoxidized polymer, and an adhesive.

Abstract: The present disclosure provides a core-sheath filament. The core-sheath filament includes an adhesive core and a non-tacky sheath, wherein the sheath exhibits a melt flow index of less than 15 grams per 10 minutes. The present disclosure also provides a method of printing an adhesive. The method includes a) melting a core-sheath filament in a nozzle to form a molten composition, and b) dispensing the molten composition through the nozzle onto a substrate. Steps a) and b) are carried out one or more times to form a printed adhesive. The core-sheath filament includes an adhesive core and a non-tacky sheath. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process using a core-sheath filament, the article including a printed adhesive based on the digital object.

Abstract: Adhesive tapes include a plasticized polyvinyl chloride backing, a primer including an ethylene/carbon monoxide-containing terpolymer and a styrene-containing block copolymer, and an adhesive.

Abstract: Polymeric multilayer film having first and second opposed major surfaces, comprising at least one layer comprising a first release agent and exhibiting a random network of strands and connective regions. The polymeric multilayer films are useful, for example, for tape and graphic articles.

Abstract: Adhesive tapes include a plasticized polyvinyl chloride backing, a primer including an ethylene/carbon monoxide-containing terpolymer and a styrene-containing block copolymer, and an adhesive.

Abstract: Adhesive tapes include a plasticized polyvinyl chloride backing, a primer including an ethylene/carbon monoxide-containing terpolymer, and an adhesive.

Abstract: Polymeric multilayer material includes an adhesive layer having first and second opposed major surfaces. A first foam layer is joined to the first major surface and includes a first plurality of expandable microspheres. A first skin layer is attached to the first foam layer and is free of the first plurality expandable microspheres. A second foam layer is joined to the second major surface of the internal adhesive layer and includes a second plurality of expandable microspheres dispersed therein. A second skin layer is attached to the second foam layer and is free of the second plurality of expandable microspheres. A portion of the first expandable microspheres of the first foam layer and of the second foam layer is at least partially embedded within the adhesive layer. Embodiments, of polymeric multilayer materials described herein are useful, for example, as wearable medical or athletic support components. The materials can also be used as protective wrappings.

Abstract: A method of making an adhesive article is described comprising melt extruding a core film layer comprising a comport comprising at least 50% of a polylactic acid polymer. The method further comprises melt extruding an adhesive layer on a major surface of the core film layer such that regions of interdiffusion are present between the core film layer and adhesive layer. The adhesive layer may comprise C1-C10 (meth)acrylic acid or ester thereof, vinyl acetate, ethylene vinyl acetate, hydrolysed polyvinyl alcohol and combinations thereof. The adhesive layer may also be a pressure sensitive adhesive. The method further comprises melt extruding a release film layer on an opposing major surface of the core film layer. The layers are sequentially extruded or co-extruded and can be uniaxially or biaxially oriented. Articles comprising a core film layer comprising a composition comprising at least 50% of a polylactic acid polymer and an adhesive layer disposed on a major surface of the core layer are also described.

Abstract: Polymeric multilayer film comprising a layer exhibiting a random network of strands and connective regions that is separable from the remaining polymeric multilayer film. The polymeric multilayer films are useful, for example, for tape and graphic articles.

Abstract: Polymeric multilayer film comprising a layer comprising a first pressure sensitive adhesive and exhibiting a random network of strands and connective regions. The polymeric multilayer films are useful, for example, for tape and graphic articles.