Abstract: Cement compositions including ordinary Portland cement, a secondary cementitious material (SCM) including one or more of pozzolan, metakaolin, limestone, or gypsum in an amount of up to approximately 70% of a replacement level of ordinary Portland cement, and between approximately 0.05% by weight of cement (bwoc) and 2% bwoc of aggregates of mesoporous carbon nanoparticles (3DG) carbons. The cement compositions regulate nucleation and time-lapsed growth of calcium silica hydrates during initial hydration. The 3DG carbons include aggregates of mesoporous carbon nanoparticles, which include one or more interconnected bundles of electrically conductive graphene layers. The 3DG carbons include oxygen containing functional groups disposed on one or more of the surfaces of the 3DG carbons or within the 3DG carbons.

Abstract: A system for post-processing carbon powders includes a fluidized-bed reactor having an interior containing a fluidized-bed region. The system may include a gas feed source, a gas inlet value, a gas-solid separator, and an energy source coupled to the fluidized-bed reactor. Carbon nano-particulates may be loaded, in powder form, into the fluidized-bed region prior to operation. The gas feed source may output a gas-phase mixture into the interior of the fluidized-bed reactor, and the energy source may electromagnetically excite the gas-phase mixture and generate a plasma-phase mixture formed in a plasma region positioned adjacent to or within the interior of the fluidized-bed reactor. The energy source may be positioned at one or more positions relative to the gas inlet valve.

Abstract: A greenhouse gas negative emissions system. Embodiments use a dissociating reactor to produce fuel as well as carbonaceous materials, both of which are used in environmentally-clean fuel cells. A high-power reactor harmlessly dissociates methane into solid carbon and hydrogen. The methane is dissociated rather than being burned, thus permanently abating greenhouse gas emissions that would result from combustion of methane thus, the reactor operates as a negative emissions system. The dissociated hydrogen is distributed as hydrogen gas (H2). The hydrogen gas is stored for use in a clean fuel consuming apparatus that converts H2 to water (H2O) and electric energy. A first portion of the dissociated carbon is used to produce a fuel cell array that is used in environmentally-clean vehicles. A second portion of the dissociated carbon is used in other carbon-containing applications, such as lightweight carbon fiber components, carbon fiber reinforced plastics, carbon-containing building materials, and so on.

Abstract: A fuel cell assembly includes multiple fuel cells that are electrically coupled. Each fuel cell includes an electrolyte, an anode, and a cathode that can be fabricated from decorated or non-decorated carbon particles. The carbon particles can be produced by a methane dissociating reactor that converts methane into solid carbon and hydrogen. The electrolyte particles form an electrolyte structure that has a pattern of grooves on the anode and cathode facing surfaces. The electrolyte structure is sintered with microwave energy to fuse the adjacent electrolyte particles at contact points. The anode and cathode layers are deposited on opposite sides of the electrolyte and sintered. The anode and cathode layers are then processed to form multiple electrically fuel cells. The anode layers of the fuel cells are electrically coupled with interconnects to cathode layers of the adjacent fuel cells.

Abstract: A system for post-processing carbon powders includes a fluidized-bed reactor having an interior containing a fluidized-bed region. The system may include a gas feed source, a gas inlet value, a gas-solid separator, and an energy source coupled to the fluidized-bed reactor. Carbon nano-particulates may be loaded, in powder form, into the fluidized-bed region prior to operation. The gas feed source may output a gas-phase mixture into the interior of the fluidized-bed reactor, and the energy source may electromagnetically excite the gas-phase mixture and generate a plasma-phase mixture formed in a plasma region positioned adjacent to or within the interior of the fluidized-bed reactor. The energy source may be positioned at one or more positions relative to the gas inlet valve.

Abstract: A process for removing hydrocarbons from a feed stream containing hydrocarbons includes introducing ozone to the feed stream to produce an ozone doped stream containing ozone and hydrocarbons, and contacting the ozone doped stream with a supported metal catalyst at a temperature of from 100° C. to 300° C. to produce a treated stream, wherein the supported metal catalyst comprises iron supported on a support selected from aluminosilicates, silica-aluminas, silicates and aluminas. A process for removing NOx from a feed stream containing NOx, and an apparatus for removing hydrocarbons and/or NOx from a feed stream containing hydrocarbons and/or NOx are also provided.

Abstract: A process for removing hydrocarbons from a feed stream containing hydrocarbons includes introducing ozone to the feed stream to produce an ozone doped stream containing ozone and hydrocarbons, and contacting the ozone doped stream with a supported metal catalyst at a temperature of from 100° C. to 300° C. to produce a treated stream, wherein the supported metal catalyst comprises iron supported on a support selected from aluminosilicates, silica-aluminas, silicates and aluminas. A process for removing NOx from a feed stream containing NOx, and an apparatus for removing hydrocarbons and/or NOx from a feed stream containing hydrocarbons and/or NOx are also provided.

Abstract: A process for removing hydrocarbons from a feed stream containing hydrocarbons includes introducing ozone to the feed stream to produce an ozone doped stream containing ozone and hydrocarbons, and contacting the ozone doped stream with a supported metal catalyst at a temperature of from 100° C. to 300° C. to produce a treated stream, wherein the supported metal catalyst comprises iron supported on a support selected from aluminosilicates, silica-aluminas, silicates and aluminas. A process for removing NOx from a feed stream containing NOx, and an apparatus for removing hydrocarbons and/or NOx from a feed stream containing hydrocarbons and/or NOx are also provided.

Abstract: A process for removing hydrocarbons from a feed stream containing hydrocarbons includes introducing ozone to the feed stream to produce an ozone doped stream containing ozone and hydrocarbons, and contacting the ozone doped stream with a supported metal catalyst at a temperature of from 100° C. to 300° C. to produce a treated stream, wherein the supported metal catalyst comprises iron supported on a support selected from aluminosilicates, silica-aluminas, silicates and aluminas. A process for removing NOx from a feed stream containing NOx, and an apparatus for removing hydrocarbons and/or NOx from a feed stream containing hydrocarbons and/or NOx are also provided.

Abstract: A soot resistant and efficient diesel fuel reformer for a diesel exhaust aftertreatment system has serially arranged first and second catalyst supports. The first support is nearer the inlet and has a monolith structure that is uniform in the direction of flow. The second support has a modified monolith structure that is non-uniform in the direction of flow. Preferably, the first support has straight channels. Preferably, the second support has internal leading edges spaced periodically through its length to break up the flow. The first support has a catalyst coating comprising at least an oxidation catalyst. The second support has a catalyst coating comprising at least a steam reforming catalyst.

Abstract: A soot resistant and efficient diesel fuel reformer for a diesel exhaust aftertreatment system has serially arranged first and second catalyst supports. The first support is nearer the inlet and has a monolith structure that is uniform in the direction of flow. The second support has a modified monolith structure that is non-uniform in the direction of flow. Preferably, the first support has straight channels. Preferably, the second support has internal leading edges spaced periodically through its length to break up the flow. The first support has a catalyst coating comprising at least an oxidation catalyst. The second support has a catalyst coating comprising at least a steam reforming catalyst.

Abstract: The invention provides methods and systems for catalytic reforming of a hydrocarbon fuel to produce hydrogen, which may be used as a power source for a fuel cell. In some embodiments, hydrogen is produced by partial oxidation or autothermal reforming of fuel in an oxygen containing gas stream that is rich the majority of the time, with periodic conversion to a lean gas stream for short periods of time to maintain catalytic activity. In one embodiment, hydrogen peroxide is used as the oxidant in an autothermal reforming process. In some embodiments, hydrogen is produced by steam reforming at a low steam to carbon ratio, with a periodic increase in the steam to carbon ratio for short periods of time to maintain catalytic activity.