Abstract: The present invention is related to a dental composition comprising: (a) at least one polymerizable monomer having at least one ethylenically unsaturated group; (b) a radical initiator system comprising (i) a photosensitizer having an absorption maximum ranging from 400 nm to 800 nm; (ii) a coinitiator; and (iii) a compound of the following formula (1): wherein R1 and R2, which may be the same or different, independently represent a hydrogen atom, a C1-6 alkyl group, or a C1-6 alkoxy group; R3 and R4, which may be the same or different, independently represent a hydrogen atom, or a C1-6 alkyl group, or R3 and R4 may represent a bond so that the carbon atoms to which R3 and R4 are bonded are linked by a double bond; R5 and R6, which may be the same or different, independently represent a hydrogen atom, or a C1-6 alkyl group, or R5 and R6 may represent a bond so that the carbon atoms to which R5 and R6 are bonded are linked by a double bond; L represents a single bond or a group —CRH—, wherein

Abstract: The present invention is related to a dental composition comprising at least one polymerizable monomer having at least one ethylenically unsaturated group; and a radical initiator system comprising a photosensitizer having an absorption maximum ranging from 400 nm to 800 nm; and at least one thiophenium compound as coinitiator.

Abstract: The present invention relates to compositions (self-thermally) curable on demand under the triggering action of UV-visible to near-infrared irradiation of moderate intensity, method of using same for accelerated photopolyaddition of cyclic ether-amine resins or ultrafast dark curing of cyclic ether-amine resins, and articles obtained by such method. The invention also relates to a resin casting, film or coated substrate, and an adhesive layeror bonding agent, comprising acyclic ether-amine resin obtained by an accelerated curing process according to the invention. The invention additionally relates to the use of a composition of the invention for increasing the delamination strength of laminated composite materials.

Abstract: Radically polymerizable dental material, which includes a catalyst paste and a base paste, wherein the catalyst pastes includes an oxidizing agent, preferably a peroxide or hydroperoxide, a radically polymerizable monomer and/or oligomer with acid group and a polyfunctional radically polymerizable monomer, and the base paste comprises a polyfunctional radically polymerizable monomer without an acid group and a dihydropyridine derivative of Formula (1) The material has good mechanical properties and does not exhibit a bitter taste.

Abstract: A photocurable dental impression material comprising: (a) a mixture of polymerizable silicone compounds each having two or more polymerizable (meth)acrylate groups, said mixture having a dynamic viscosity at 25° C. of from 1 to 100 Pas; (b) a filler; (c) a photo initiator system, wherein the mixture of polymerizable silicone compounds comprises based on the total weight of the mixture of polymerizable silicone compounds (a) 10 to 90 percent by weight of high-molecular polymerizable silicone compounds having a molecular weight in the range of from more than 4000 up to 10.000; and (b) 90 to 10 percent by weight of polymerizable silicone compounds having a molecular weight in the range of from 300 to 4000.

Abstract: The present invention relates to a process for bringing a polymer composition above a threshold temperature on demand, wherein: the polymer composition comprises 0,01 to 0,5% weight of at least one heat-generating organic dye that generates heat above the threshold temperature when exposed to a given range of red to near-infrared irradiation, and the process comprises exposing the polymer composition to red to near-infrared irradiation at a wavelength within the red to near-infrared range where the heat-generating organic dye generates heat above the threshold temperature, the weight % being expressed with respect to the total weight of the polymer composition. The threshold temperature may be the glass transition temperature, the depolymerization temperature, the melting temperature, or the decomposition temperature of the polymer composition.

Abstract: The present invention is related to a dental composition comprising at least one polymerizable monomer having at least one ethylenically unsaturated group; and a radical initiator system comprising a photosensitizer having an absorption maximum ranging from 400 nm to 800 nm; and at least one thiophenium compound as coinitiator.

Abstract: The present invention relates to compositions (self-thermally) curable on demand under the triggering action of UV-visible to near-infrared irradiation of moderate intensity, method of using same for accelerated photopolyaddition of cyclic ether-anhydride resins or dark curing of cyclic ether-anhydride resins, and articles obtained by such method. The invention also relates to a resin casting, film or coated substrate, and an adhesive layer or bonding agent, comprising a cyclic ether-anhydride resin obtained by an accelerated curing process according to the invention. The invention additionally relates to the use of a composition of the invention for increasing the delamination strength of laminated composite materials.

Abstract: The present invention is related to a dental composition comprising: (a) at least one polymerizable monomer having at least one ethylenically unsaturated group; (b) a radical initiator system comprising (i) a photosensitizer having an absorption maximum ranging from 400 nm to 800 nm; (ii) a coinitiator; and (iii) a compound of the following formula (1): wherein R1 and R2, which may be the same or different, independently represent a hydrogen atom, a C1-6 alkyl group, or a C1-6 alkoxy group; R3 and R4, which may be the same or different, independently represent a hydrogen atom, or a C1-6 alkyl group, or R3 and R4 may represent a bond so that the carbon atoms to which R3 and R4 are bonded are linked by a double bond; R5 and R6, which may be the same or different, independently represent a hydrogen atom, or a C1-6 alkyl group, or R5 and R6 may represent a bond so that the carbon atoms to which R5 and R6 are bonded are linked by a double bond; L represents a single bond or a group —CRH—, wherein

Abstract: Disclosed is a curable composition for the manufacture, by stereolithography, of a green part made of a ceramic or metallic material, the curable composition including at least one ceramic and/or metallic powder; at least one polymerizable monomer and/or oligomer; at least one initiator for the polymerization of the polymerizable monomer(s) and/or oligomer(s). The initiator(s) are selected from iodonium, sulphonium and diazonium salts and onium salts in combination with at least one amine and/or at least one phosphine to form a charge transfer complex. The initiator(s) may generate the initiation of a thermal polymerization under the exposure to at least one source of UV, visible or IR irradiation.

Abstract: A redox curing dental composition comprising: a. one or more compounds having a radical polymerizable carbon-carbon double bond; b. a redox initiator system comprising a reducing agent which is a compound of the following formula (I): wherein R1 and R2 which may be the same or different, independently represent a C1-18 hydrocarbyl group, or R1 and R2 form together with the silicon atom to which they are bonded a 3 to 8-membered silicon-containing alicyclic ring, which groups R1 and/or R2 may be substituted with one to three substituents selected from the group consisting of a C1-6 alkoxy group, a halogen atom, or a carboxylic acid group; and (ii) an oxidizing agent adapted to oxidize the reducing agent of formula (I) in the absence of light for generating a radical capable of initiating radical polymerization of the one or more compounds having a radical polymerizable carbon-carbon double bond.

Abstract: The present invention relates to compositions (self-thermally) curable on demand under the triggering action of UV-visible to near-infrared irradiation of moderate intensity, method of using same for accelerated photopolyaddition of cyclic ether-amine resins or ultrafast dark curing of cyclic ether-amine resins, and articles obtained by such method. The invention also relates to a resin casting, film or coated substrate, and an adhesive layer or bonding agent, comprising acyclic ether-amine resin obtained by an accelerated curing process according to the invention. The invention additionally relates to the use of a composition of the invention for increasing the delamination strength of laminated composite materials.

Abstract: A photocurable dental impression material comprising: (a) a mixture of polymerizable silicone compounds each having two or more polymerizable (meth)acrylate groups, said mixture having a dynamic viscosity at 25° C. of from 1 to 100 Pas; (b) a filler; (c) a photo initiator system, wherein the mixture of polymerizable silicone compounds comprises based on the total weight of the mixture of polymerizable silicone compounds (a) 10 to 90 percent by weight of high-molecular polymerizable silicone compounds having a molecular weight in the range of from more than 4000 up to 10.000; and (b) 90 to 10 percent by weight of polymerizable silicone compounds having a molecular weight in the range of from 300 to 4000.

Abstract: The present invention relates to a new method of light induced photopolymerization under mild irradiation conditions, copper initiator complexes to be used in such method and a polymers obtained by such method.