Abstract: In accordance with the invention a process is provided for achieving a phase-pure BSCCO or lead doped BSCCO powder or precursor of the 2201, 2212 or 2223 phase. In this process a cation solution is intimately mixed with an anion solution and precipitation is caused at a carefully controlled pH in the range from about 10 to about 12.5. The resulting product is filtered and dried or heat-treated at a temperature of from about 400.degree. to about 500.degree. C. for a period of from about 8 to about 12 hours. The heat-treated powder is then subjected to a second heat treatment at a reduced oxygen of from about 3 to about 10 torr and a temperature of from about 700.degree. to about 800.degree. to form a precursor powder. The precursor powder is heat-treated at ambient pressure in CO.sub.2 -free air from about 12 to about 31 hours or more at a temperature of from about 800.degree. to about 850.degree. C.