Abstract: A method for determining weight fractions of a plurality of elements in a subsurface formation penetrated by a wellbore includes determining weight fractions of a first plurality of elements using measurements of capture gamma rays made in the wellbore. The capture gamma rays result from bombardment of the formations with high energy neutrons. A weight fraction of a second plurality of elements is determined using measurements of inelastic gamma rays made in the wellbore resulting from bombardment of the formations with high energy neutrons. The weight fraction for the second plurality is determined by setting a transformation factor for those elements common to both the first and second plurality to result in a statistically equivalent weight fraction for the common elements as determined for the first plurality of elements. Weight fractions of elements in the second plurality not common to the first plurality of elements is determined using the set transformation factor.

Abstract: Methods and systems are described for using pulsed neutron ?-ray spectroscopy to measure formation water salinity from within a borehole. Through generating a cross-plot of database values of ratios of spectroscopically determined yields of hydrogen (H) and chlorine (Cl) from two detectors, deriving apparent salinities therefrom, formation and borehole water salinities can be determined.

Abstract: Methods and related systems are described for gamma-ray detection. A gamma-ray detector is made depending on its properties and how those properties are affected by the data analysis. Desirable properties for a downhole detector include; high temperature operation, reliable/robust packaging, good resolution, high countrate capability, high density, high Z, low radioactive background, low neutron cross-section, high light output, single decay time, efficiency, linearity, size availability, etc. Since no single detector has the optimum of all these properties, a downhole tool design preferably picks the best combination of these in existing detectors, which will optimize the performance of the measurement in the required environment and live with the remaining non-optimum properties.

Abstract: The accurate determination of formation hydrocarbon or water saturation is a useful step in the petrophysical evaluation of petroleum reservoirs. This disclosure presents a new method for estimating hydrocarbon saturation directly from a porosity log and a total organic carbon (TOC) log. The method is enabled by the recent development of a geochemical spectroscopy logging tool that combines inelastic and capture gamma ray measurements to provide a robust and accurate TOC log. The method differs from the prior approach of using carbon-to-oxygen ratios that is most often applied in cased hole evaluation. The main advantages of this method are that it does not use knowledge of formation water resistivity, it does not rely on a resistivity model, it does not use an extensive calibration database, and it is largely independent of clay or other lithology effects.

Abstract: A method and system for analyzing constituent elements in bulk media wherein neutrons are emitted into the bulk media to produce inelastic neutron interaction in the bulk media, and a gamma-ray spectrum resulting from the inelastic neutron interaction in the bulk media is detected. A set of standard spectra are used as part of spectral analysis that processes the standard spectra and the derived gamma-ray spectrum to determine a number of yield coefficients for the constituent elements as part of the bulk media. The standard spectra or the spectral analysis is configured to account for at least one environmental condition that affects detected gamma-rays that result from the inelastic neutron interaction in the bulk media.

Abstract: A method for analyzing a formation includes entering into a computer a number of detected gamma rays resulting from imparting neutrons into the formation. The detected gamma rays are characterized by energy levels thereof. A number of detected gamma rays in each energy level comprises a measured spectrum. In the computer, a non-Gaussian filter is applied to a reference spectrum to match the measured spectrum in shape. The filtered reference spectrum and measured spectrum are used to determine a fractional volume of at least one component of the formation.

Abstract: Methods and related systems are described for gamma-ray detection. A gamma-ray detector is made depending on its properties and how those properties are affected by the data analysis. Desirable properties for a downhole detector include; high temperature operation, reliable/robust packaging, good resolution, high countrate capability, high density, high Z, low radioactive background, low neutron cross-section, high light output, single decay time, efficiency, linearity, size availability, etc. Since no single detector has the optimum of all these properties, a downhole tool design preferably picks the best combination of these in existing detectors, which will optimize the performance of the measurement in the required environment and live with the remaining non-optimum properties.

Abstract: A method and system for analyzing constituent elements in bulk media wherein neutrons are emitted into the bulk media to produce inelastic neutron interaction in the bulk media, and a gamma-ray spectrum resulting from the inelastic neutron interaction in the bulk media is detected. A set of standard spectra are used as part of spectral analysis that processes the standard spectra and the derived gamma-ray spectrum to determine a number of yield coefficients for the constituent elements as part of the bulk media. The standard spectra or the spectral analysis is configured to account for at least one environmental condition that affects detected gamma-rays that result from the inelastic neutron interaction in the bulk media.

Abstract: A method for analyzing a formation includes entering into a computer a number of detected gamma rays resulting from imparting neutrons into the formation. The detected gamma rays are characterized by energy levels thereof. A number of detected gamma rays in each energy level comprises a measured spectrum. In the computer, a non-Gaussian filter is applied to a reference spectrum to match the measured spectrum in shape. The filtered reference spectrum and measured spectrum are used to determine a fractional volume of at least one component of the formation.

Abstract: Methods and related systems are described for gamma-ray detection. A gamma-ray detector is made depending on its properties and how those properties are affected by the data analysis. Desirable properties for a downhole detector include; high temperature operation, reliable/robust packaging, good resolution, high countrate capability, high density, high Z, low radioactive background, low neutron cross-section, high light output, single decay time, efficiency, linearity, size availability, etc. Since no single detector has the optimum of all these properties, a downhole tool design preferably picks the best combination of these in existing detectors, which will optimize the performance of the measurement in the required environment and live with the remaining non-optimum properties.

Abstract: A method for estimating an aspect of a formation using a nuclear spectroscopy tool includes placing a nuclear spectroscopy tool into a borehole and emitting neutrons such that some of the neutrons generate gamma rays from a formation adjacent the nuclear spectroscopy tool and some of the neutrons generate gamma rays from elements within the nuclear spectroscopy tool. An energy spectrum of gamma rays induced by the emitted neutrons can be detected. The energy spectrum includes a background having a plurality of measured spectral components. A background ratio between at least one spectral component of the background and another measured spectral component can be determined or estimated in accordance with environmental measurements. The detected gamma ray spectra can be analyzed using a combination of standard spectra and subtracting at least one spectral component of the background in accordance with the background ratio.

Abstract: A method for correcting determined sulfur content in formations penetrated by a wellbore for sulfur in the wellbore includes determining an amount of sulfur from spectral analysis of gamma rays detected by a well logging instrument disposed in the wellbore. The gamma rays result from imparting neutrons into the formations. The method includes determining if strontium is present in fluid disposed in the wellbore. An amount of strontium is determined from the spectral analysis. A corrected sulfur content of the formation is determined based on the determined amount of strontium.

Abstract: The present invention provides systems and methods capable of improving the efficiency and effectiveness of leaching operations. In one embodiment, the present invention may utilize a coiled tubing directional drilling system capable of treating interior portions of the heap/formation. In one embodiment, the present invention may utilize a system and method capable of capturing real time temperature and resistivity data pertaining to pregnant solution characteristics in the heap/formation. In one embodiment, the present invention may utilize one or more wire line deployed X-Ray Fluorescence (XRF) spectrometers capable of quantitatively measuring concentrations of desired metals in the heap/formation during leaching operations. In one embodiment, the present invention utilizes multiple passes of elemental capture spectroscopy logs acquired at regular time intervals to monitor metal concentrations during leaching operations.

Abstract: A method for improving precision of measurement of material composition of formations determined by gamma ray spectral an analysis includes determining an accurate value of an amount of a selected by analyzing a spectrum of gamma rays detected from the formations using a technique that directly relates the gamma ray spectrum to the amount of the material. A precise value of the amount of the material is determined by analyzing the spectrum of detected gamma rays that indirectly relates the gamma ray spectrum to the amount of the material. A function relating the accurate value to the precise value over a selected axial interval along the wellbore is determined. The function is applied to the accurate value at at least one selected axial position along the wellbore to determine an accurate and precise value of the amount of the material.

Abstract: The accurate determination of formation hydrocarbon or water saturation is a useful step in the petrophysical evaluation of petroleum reservoirs. This disclosure presents a new method for estimating hydrocarbon saturation directly from a porosity log and a total organic carbon (TOC) log. The method is enabled by the recent development of a geochemical spectroscopy logging tool that combines inelastic and capture gamma ray measurements to provide a robust and accurate TOC log. The method differs from the prior approach of using carbon-to-oxygen ratios that is most often applied in cased hole evaluation. The main advantages of this method are that it does not use knowledge of formation water resistivity, it does not rely on a resistivity model, it does not use an extensive calibration database, and it is largely independent of clay or other lithology effects.

Abstract: A method of analyzing a geologic formation having a borehole therein may include operating at least one tool within the borehole to collect respective borehole dimensions at different depths in the borehole, and collect respective total values for a given element at the different depths in the borehole. Each total value may be based upon both a value for an adjacent portion of the geologic formation and a value for material within the borehole. The method may also include determining each value of the given element in the adjacent portion of the geologic formation based upon the total value and the corresponding borehole dimensions.

Abstract: Methods and related systems are described for gamma-ray detection. A gamma-ray detector is made depending on its properties and how those properties are affected by the data analysis. Desirable properties for a downhole detector include; high temperature operation, reliable/robust packaging, good resolution, high countrate capability, high density, high Z, low radioactive background, low neutron cross-section, high light output, single decay time, efficiency, linearity, size availability, etc. Since no single detector has the optimum of all these properties, a downhole tool design preferably picks the best combination of these in existing detectors, which will optimize the performance of the measurement in the required environment and live with the remaining non-optimum properties.

Abstract: A method for estimating an aspect of a formation using a nuclear spectroscopy tool includes placing a nuclear spectroscopy tool including a neutron source and a gamma ray detector into a borehole and performing a plurality of environmental measurements. Neutrons are emitted from the nuclear spectroscopy tool such that some of the neutrons generate gamma rays from a formation adjacent the nuclear spectroscopy tool, some of the neutrons generate gamma rays from elements within the nuclear spectroscopy tool and some of the neutrons generate gamma rays from an element in the drilling mud. An energy spectrum of gamma rays induced by the emitted neutrons can be detected with the tool and analyzed using a combination of standard spectra including at least two sub-standards that represent a common element or group of elements and that are differentiated based on location of neutron interaction, such as where the neutrons thermalize.

Abstract: A method for correcting detected gamma ray spectra for the effects of energy analyzer pileup includes assigning detected gamma rays to channels in a multichannel analyzer (MCA). A pileup spectrum is estimated. The pileup spectrum is subtracted from the measured spectrum. The result thereof is compared to the preceding estimated pileup free spectrum and the estimating the pileup spectrum, subtracting the pileup spectrum and comparing is repeated until the difference between successive estimates of the pileup-free spectrum falls below a selected threshold.

Abstract: Methods and related systems are described for gamma-ray detection. A gamma-ray detector is made depending on its properties and how those properties are affected by the data analysis. Desirable properties for a downhole detector include; high temperature operation, reliable/robust packaging, good resolution, high countrate capability, high density, high Z, low radioactive background, low neutron cross-section, high light output, single decay time, efficiency, linearity, size availability, etc. Since no single detector has the optimum of all these properties, a downhole tool design preferably picks the best combination of these in existing detectors, which will optimize the performance of the measurement in the required environment and live with the remaining non-optimum properties.