Patents by Inventor James A. Murfree, Jr.

James A. Murfree, Jr. has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4157270
    Abstract: A catalyst bed containing alumina pellets on which an active catalyst metal selected from iridium, nickel, niobium, and molybdenium has been deposited is employed to decompose a compound selected from deuterohydrazine, deuteroammonia, hydrazine, and ammonia to yield ammonia free deuterium and nitrogen or hydrogen and nitrogen at a temperature required for immediate use in a DF or HF laser which uses F atoms as the fuel. The decomposition temperature of the catalyst bed is maintained by a hypergolic reaction produced from reacting a fuel selected from the group consisting of hydrazine, methylhydrazine, 1,2-dimethylhydrazine, and blends of the same with an oxidizer selected from the group consisting of inhibited red fuming nitric acid, dinitrogen tetroxide, chlorine trifluoride, and chlorine pentafluoride. A laser employing ammonia free decomposition products of hydrazine and ammonia produced at a temperature between about 500.degree. C. and 900.degree. C. operates at a higher power output. When NH.sub.
    Type: Grant
    Filed: September 12, 1977
    Date of Patent: June 5, 1979
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Pasquale Martignoni, William M. Chew, Orval E. Ayers, James A. Murfree, Jr.
  • Patent number: 4102988
    Abstract: A cyano compound fuel selected from the group consisting of dicyanoacetylene (DCA), tetracyanoethylene (TCE), and tetracyanoethylene oxide (TCEO) when reacted with an oxidizer compound selected from the group consisting of fluorine (F.sub.2), nitrogen trifluoride (NF.sub.3), chlorine trifluoride (ClF.sub.3), chlorine pentafluoride (ClF.sub.5), and tetrafluorohydrazine (N.sub.2 F.sub.4) produces the F.sup.. atom concentration required for either HF or DF lasers. The reaction is accomplished in the presence of a diluent gas selected from nitrogen and helium. No deactivation species are among the gaseous species produced which include CF.sub.4, F.sup.. atoms, and N.sub.2 ; therefore, deactivation of the excited molecules, either HF or DF, which are responsible for the lasing in a HF or DF laser is prevented. A higher performance of the laser device can be achieved.
    Type: Grant
    Filed: October 3, 1977
    Date of Patent: July 25, 1978
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Pasquale Martignoni, James A. Murfree, Jr., William M. Chew, Orval E. Ayers
  • Patent number: 3953261
    Abstract: The use of methoxylamine hydrochloride (CH.sub.3 ONH.sub.2. HCl) as an adive to exothermally decomposing liquid monopropellants such as hydrazine and hydrazine water mixtures to lower the freezing point of the monopropellants and thereby render the monopropellants usable in gas generators at very low temperatures.
    Type: Grant
    Filed: June 18, 1969
    Date of Patent: April 27, 1976
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: William A. Duncan, John F. Phillips, James A. Murfree, Jr., Walter W. Wharton
  • Patent number: 3953262
    Abstract: The use of methoxylamine nitrate (CH.sub.3 ONH.sub.2.NHO.sub.3) as an addve to exothermally decomposing liquid monopropellants such as hydrazine and hydrazine water mixtures to lower the freezing points of the monopropellants and thereby render the monopropellants usable in gas generators at very low temperatures.
    Type: Grant
    Filed: November 20, 1969
    Date of Patent: April 27, 1976
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: William A. Duncan, James A. Murfree, Jr., Pasquale Martignoni, Walter W. Wharton, John F. Phillips
  • Patent number: 3941626
    Abstract: The use of methoxylamine perchlorate (CH.sub.3 ONH.sub.2.HClO.sub.4) as an dditive to exothermally decomposing liquid monopropellants such as hydrazine and hydrazine water mixtures to maintain energetic monopropellants and at the same time lower the freezing point of the monopropellants, thereby rendering the monopropellants usable in gas generators at very low temperatures.
    Type: Grant
    Filed: June 24, 1970
    Date of Patent: March 2, 1976
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: John F. Phillips, James A. Murfree, Jr., Walter W. Wharton, William A. Duncan